Freundlich Isotherm - Micromeritics ASAP 2460 Operator's Manual

Accelerated surface area and porosimetry system
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Appendix C
Quantity of the Monolayer (cm
1
-- -
Q
=
m
S
Langmuir b Value:
b
=
Y
V
int
Error of the Langmuir Surface Area (m
LAN
=
err

Freundlich Isotherm

The Freundlich isotherm has the form
Q
------- -
=
CP
Q
m
where
C
=
m
=
P
=
Q
=
Q
=
m
The pressure is absolute; typically, m > 1. In terms of quantity adsorbed,
Q
=
Q
CP
m
Taking the log of both sides yields
log
Q
=
log
C-10
3
/g STP):
m
2
/g):
SA
S
Lan
err
-----------------------
S
1
--- -
m
temperature-dependent constant
temperature-dependent constant
equilibrated collected pressure measured by gauge at temp T
quantity of gas adsorbed
quantity of gas in a monolayer
1
--- -
m
1
--- -
Q
C
+
log
P
m
m
ASAP 2460 Operator's Manual
amb
246-42800-01 - Aug 2013

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