Waters ACQUITY UPLC Operator's, Overview And Maintenance Manual page 113

Photodiode array and egphotodiode array detector
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Solvent miscibility (Continued)
Polarity
Solvent
index
3.9
Butanol
4.2
Tetrahydrofuran
4.3
Ethyl acetate
4.3
1-propanol
4.3
2-propanol
4.4
Methyl acetate
4.5
Methyl ethyl ketone 0.43
4.5
Cyclohexanone
4.5
Nitrobenzene
4.6
Benzonitrile
4.8
Dioxane
5.2
Ethanol
5.3
Pyridine
5.3
Nitroethane
5.4
Acetone
5.5
Benzyl alcohol
5.7
Methoxyethanol
6.2
Acetonitrile
6.2
Acetic acid
6.4
Dimethylformamide 0.90
6.5
Dimethylsulfoxide
6.6
Methanol
7.3
Formamide
9.0
Water
Boiling
Viscosity
point °C
CP, 20 °C
(1 atm)
3.01
177.7
0.55
66.0
0.47
77.1
2.30
97.2
2.35
117.7
0.45
56.3
80.0
2.24
155.7
2.03
210.8
1.22
191.1
1.54
101.3
1.20
78.3
0.94
115.3
0.68
114.0
0.32
56.3
5.80
205.5
1.72
124.6
0.37
81.6
1.26
117.9
153.0
2.24
189.0
0.60
64.7
3.76
210.5
1.00
100.0
Solvent considerations
Miscibility
λ Cutoff
number
(nm)
(M)
15
––
17
220
19
260
15
210
15
––-
15, 17
260
17
330
28
210
14, 20
––
15, 19
––
17
220
14
210
16
305
––
––
15, 17
330
13
––
13
––
11, 17
190
14
––
12
––
9
––
12
210
3
––
––
––
101

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