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Analytical Instruments
Sievers InnovOx
On-Line TOC Analyzer
F
V
3.02
L
IRMWARE
ERSION
OR
ATER
DLM 68100-06 EN Rev. A

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   Summary of Contents for GE Sievers InnovOx

  • Page 1

    Analytical Instruments Sievers InnovOx On-Line TOC Analyzer 3.02 IRMWARE ERSION ATER DLM 68100-06 EN Rev. A...

  • Page 2

    T +1 800 255 6964 United Kingdom Shanghai China 201203 T +1 303 444 2009 T +44 (0) 161 864 6800 T +(8621) 38777735 F +1 303 444 9543 F +44 (0) 161 864 6829 F +(8621) 38777469 www.geinstruments.com geai.europe@ge.com geai.asia@ge.com techsupport@geinstruments.com...

  • Page 3: Identification Records

    Analyzer serial number: _______________________ (This is located on the side of the Analyzer.) Date of receipt and installation of the Analyzer: _______________________ (This is the warranty start date.) GE Analytical Instruments ©2013 3 of 238 DLM 68100-06 EN Rev. A...

  • Page 4: Table Of Contents

    IP56 ....................58 GE Analytical Instruments ©2013 4 of 238 DLM 68100-06 EN Rev.

  • Page 5

    Handling Standards ..................90 GE Analytical Instruments ©2013 5 of 238 DLM 68100-06 EN Rev.

  • Page 6

    Acid ................... . 128 GE Analytical Instruments ©2013 6 of 238 DLM 68100-06 EN Rev.

  • Page 7

    Recommended Spare Parts ................154 GE Analytical Instruments ©2013 7 of 238 DLM 68100-06 EN Rev.

  • Page 8

    Pneumatic Valves ................. . 206 GE Analytical Instruments ©2013 8 of 238 DLM 68100-06 EN Rev.

  • Page 9

    Returning the Analyzer to GE Analytical Instruments ........

  • Page 10: List Of Tables

    Consumables Replacement Schedule ............153 Table 12 2-Year Maintenance Worksheet — Sievers InnovOx Online TOC Analyzer ..... . . 170 Table 13 Other Software Errors .

  • Page 11: List Of Figures

    Check Standard (Setup) Screen ............. 121 GE Analytical Instruments ©2013 11 of 238 DLM 68100-07 EN Rev.

  • Page 12

    The Temperatures Display on the NDIR Screen ..........192 GE Analytical Instruments ©2013 12 of 238 DLM 68100-07 EN Rev.

  • Page 13

    Microsoft Excel Spreadsheet Program — Text Import Wizard - Step 3 ......226 GE Analytical Instruments ©2013 13 of 238 DLM 68100-07 EN Rev.

  • Page 14: Revision History

    DLM 68100-04 EN Rev. A Firmware 3.01 April 2012 DLM 68100-05 EN Rev. A Firmware 3.02 January 2013 DLM 68100-06 EN Rev. A Firmware 3.02 (Consumables Replacement May 2013 Schedule Update) GE Analytical Instruments ©2012 14 of 238 DLM 68100-06 EN Rev. A...

  • Page 15: Confidentiality

    Confidentiality The information contained in this manual may be confidential and proprietary and is the property of GE Analytical Instruments. Information disclosed herein shall not be used to manufacture, construct, or otherwise reproduce the goods disclosed herein. The information disclosed herein shall not be disclosed to others or made public in any manner without the express written consent of GE Analytical Instruments.

  • Page 16: Declaration Of Conformity

    Warranty Term The GE Analytical Instruments warranty term is thirteen (13) months ex-works, or twelve (12) months from installation or start up by GE Ana- lytical Instruments certified service personnel. In no event shall the standard limited warranty coverage extend beyond thirteen (13) months from original shipment date.

  • Page 17: Limitation Of Remedies And Liability

    Operation and Maintenance Manual. Usage of non-recommended maintenance materials may void a warranty claim. The remedies provided herein are the customer's sole and exclusive remedies. In no event shall GE Analytical Instruments be liable for direct, indirect, special, incidental or consequential damages (including loss of profits) whether based on contract, tort, or any other legal theory.

  • Page 18: Limitazione Di Rimedi E Responsabilità

    Gli unici rimedi spettanti all’utente sono quelli qui inclusi. In nessun caso GE Analytical Instruments sarà responsabile per danni diretti, indiretti, speciali, accidentali o consequenziali (inclusa la perdita di profitti) risultanti dall’applicazione del contratto, atto illecito o altra teoria legale. Il manuale d’uso e manutenzione è...

  • Page 19: Warnings

    This symbol indicates that to comply with European Union Directive 2002/96/EC for waste electrical and electronic equipment (WEEE), the Analyzer should be disposed of separately from standard waste. GE Analytical Instruments ©2013 19 of 238 DLM 68100-06 EN Rev. A...

  • Page 20

    100 psig (689 kPa). The pressure of compressed gas at the blowback gas inlet on the Filter Panel accessory must not exceed 40 psig (276 kPa). Use only dry, oil-free air or nitrogen. GE Analytical Instruments ©2013 20 of 238 DLM 68100-06 EN Rev. A...

  • Page 21

    Warning If this instrument is used in a manner not specified by GE Analytical Instruments, the protection provided by the instrument may be impaired. Warning Consult the MSDS that accompanies each standards set and the reagents to identify proper disposal techniques.

  • Page 22

    Warning If you experience an issue with the printed circuit assembly (PCA) that contains a lithium battery, please contact GE Analytical instruments for return instructions. Whenever changing the lithium battery, observe the correct polarity. Dispose of used batteries according to the manufacturer’s instructions and local disposal requirements.

  • Page 23

    Advertencia Para garantizar el funcionamiento adecuado y protegerlo contra lesiones, no haga funcionar el Analyzer sin las cubiertas colocadas o con la puerta abierta. GE Analytical Instruments ©2013 23 of 238 DLM 68100-06 EN Rev. A...

  • Page 24

    La pantalla puede contener mercurio y, por ende, ser considerada un material peligroso en su área local. Deseche estos productos de conformidad con las leyes locales, estatales y federales de su país. GE Analytical Instruments ©2013 24 of 238 DLM 68100-06 EN Rev. A...

  • Page 25

    Advertencia La utilización de este instrumento de un modo no especificado por GE Analytical Instruments puede afectar la protección que brinda el instrumento. Advertencia Para conocer las técnicas apropiadas de desecho, consulte la hoja de datos de...

  • Page 26

    Este símbolo indica que, para estar de acordo com a European Union Directive 2002/96/EC para resíduos de equipamentos elétricos e eletrônicos (REEE), o Analisador deve ser descartado separadamente do lixo padrão. GE Analytical Instruments ©2013 26 of 238 DLM 68100-06 EN Rev. A...

  • Page 27

    Use apenas ar seco e sem óleos ou nitrogênio. Advertência Se o acessório IP56 for usado com o Analisador, não o opere sem o filtro instalado na saída de ar refrigerante do reator. GE Analytical Instruments ©2013 27 of 238 DLM 68100-06 EN Rev. A...

  • Page 28

    Nesse caso, pode ser necessário que o usuário tenha que tomar medidas para corrigir a interferência. Advertência Se o instrumento for usado de forma não especificada pela GE Analytical Instruments, a proteção fornecida pelo instrumento poderá ser prejudicada. Advertência Consulte as Especificações de segurança do material que acompanha cada...

  • Page 29

    Se você se deparar com um problema com as placas de circuitos impressos que contenha bateria de lítio, entre em contato com a GE Analytical Instruments para obter instruções para a devolução. Sempre que trocar a bateria de lítio, observe a polaridade correta.

  • Page 30

    Warnung Alle Arbeiten im Inneren des Analysators, einschließlich der Anbringung von Verschleißteilen, können zu Verletzungen führen. Um elektrische Schläge oder Verbrennungen zu vermeiden, schalten Sie den Analysator aus und ziehen Sie den Netzstecker, bevor Sie ihn öffnen. Seien Sie vorsichtig, wenn Sie elektrische Komponenten berühren.

  • Page 31

    Der Bildschirm kann Quecksilber enthalten und in Ihrem Land als gefährliches Material eingestuft werden. Entsorgen Sie diese Teile gemäß Ihrer staatlichen und lokalen Vorschriften. Warnung Stoppen Sie die Analyse immer bevor Sie den Analysator ausschalten. GE Analytical Instruments ©2013 31 of 238 DLM 68100-06 EN Rev. A...

  • Page 32

    Beeinflussung verursachen. In diesem Fall kann es sein, dass der Benutzer entsprechende Maßnahmen treffen muss, um diese Störung zu beheben. Warnung Wenn dieses Instrument auf eine nicht von GE Analytical Instruments festgelegte Weise verwendet wird, kann der durch das Instrument gewährleistete Schutz beeinträchtigt werden. Warnung Lesen Sie bitte die Anweisung zur richtigen Entsorgung in den Sicherheitsdatenblättern, die jedem Standardset und den Reagenzien beiliegen,...

  • Page 33

    Ce symbole indique qu'aux fins de conformité avec la directive 2002/ 96/CE de l'Union Européenne concernant les matériels électroniques et électriques mis au rebut, l'analyseur doit être jeté séparément des déchets standard. GE Analytical Instruments ©2013 33 of 238 DLM 68100-06 EN Rev. A...

  • Page 34

    100 psig (689 kPa). La pression du gaz comprimé à l'admission du gaz de retour sur le panneau filtrant ne doit pas dépasser 40 psig (276 kPa). Utiliser uniquement de l'air sans huile, sec ou de l'azote. GE Analytical Instruments ©2013 34 of 238 DLM 68100-06 EN Rev. A...

  • Page 35

    électromagnétiques, auquel cas l'utilisateur peut être contraint de prendre les mesures adéquates pour y remédier. Avertissement Si cet instrument est utilisé d'une manière non spécifiée par GE Analytical Instruments, la protection offerte par l'instrument peut s'en trouver affaiblie. Avertissement Consulter les fiches techniques des substances dangereuses fournies avec chaque jeu de standards et avec les réactifs afin d'identifier les bonnes techniques de mise...

  • Page 36

    Avertissement Si un problème se présente avec l'ensemble du circuit imprimé (PCA) qui contient une batterie de lithium, contactez GE Analytical Instrument pour les instructions de renvoi. Lors du changement de batterie de lithium, observez la polarité correcte. Jetez les batteries usées selon les instructions du fabricant et les exigences locales de mise au rebut.

  • Page 37

    Avvertenza Al fine di garantire che tutte le operazioni vengano svolte correttamente ed evitare infortuni, vi consigliamo di azionare l'analizzatore utilizzando le adeguate protezioni e chiudendo la porta. GE Analytical Instruments ©2013 37 of 238 DLM 68100-06 EN Rev. A...

  • Page 38

    Avvertenza Il display può contenere mercurio e nella propria area può essere considerato materiale pericoloso. Smaltire l'articolo secondo le norme locali, regionali e statali. GE Analytical Instruments ©2013 38 of 238 DLM 68100-06 EN Rev. A...

  • Page 39

    Avvertenza Se lo strumento viene utilizzato in modo diverso da quello specificato dalla GE Analytical Instruments, potrebbe essere compromessa la protezione prevista per l'apparecchiatura.

  • Page 40

    必要があることを示します。 警告 バイアル ポートには、サンプル バイアルの隔壁を貫通するため に設計された鋭い針が含まれています。バイアル ポートには指 や不適切な素材を入れないようにしてください。 警告 サンプルの配合によっては、塩素や臭素などのハロゲン、または フッ化物、シアン化合物、その他の有毒塩分から出る毒性ガスが 分析機器から廃棄コンテナに排出される可能性があります。有毒 ガスを吸いこまないようにするため、炭酸ソーダ ( ソーダ灰 ) を 廃棄コンテナに入れて中性化する必要があります。 警告 有毒ガスを吸い込まないようにするため、必ず分析機器を通気の 良い場所に取り付けてください。 警告 この記号は、EU の廃電気電子機器指令 (WEEE) に準拠しており、 分析機器を標準の廃棄物とは別に廃棄すべきであることを示し ます。 GE Analytical Instruments ©2013 40 of 238 DLM 68100-06 EN Rev. A...

  • Page 41

    これは、安全等級 I 製品です。接地電源に接続する必要があります。分析機 器の破損と人体傷害を回避するため、分析機器を正しい電圧の電力線に接続 するようにしてください。 警告 正しく機能させ、人体傷害を防ぐため、カバーが外れているときには分析機 器を操作しないでください。 警告 保守管理用の品目の取り付けを含む、分析機器内部に接近する操作は、人身 傷害につながる可能性があります。感電や火傷の危険性を回避するため、分 析機器を開く前に電源を切り、コンセントから抜いてください。電気部品に 触れる場合は細心の注意を払ってください。 警告 サンプル、標準、廃液または試薬が含まれる部品を取り扱う際は、目の保護 具と手袋を着用してください。 警告 ディスプレイ画面には、水銀が含まれ、お住まいの地域では有害物質に指定 されている可能性があります。この品目は、国、州、および地方自治体の政 府規制に従って廃棄してください。 警告 分析は、必ず分析機器の電源を切る前に停止してください。 警告 これは、等級 A 製品です。屋内環境においては、この製品は電磁干渉を 発生することがあり、その場合はユーザーが適切な是正措置を取る必要が あります。 GE Analytical Instruments ©2013 41 of 238 DLM 68100-06 EN Rev. A...

  • Page 42

    警告 この機器が GE Analytical Instruments によって指定された方法で使用され なかった場合、機器に組み込まれた保護機能は損なわれます。 警告 適切な廃棄方法については、各標準セットや試薬についている製品安全デー タシートをご覧ください。 警告 分析機器が破損しないよう、分析機器のファンに異物を近づけないようにし てください。反応装置の冷却空気入り口は分析機器の下にあります。紙など の異物が入り口を塞いだり入り込んだりしないようにしてください。 警告 分析器に取付ス タ ン ド ア ク セサ リ ーを使用する場合は、 分析器を取 り 付け る 前に取付ス タ ン ド を壁または床にボル ト で固定 し てお く 必要があ り ます...

  • Page 43

    警告 この機器は、その地域の規定や条例に従って、また地域の規定がない 場合には、米国電気規則、ANSI/NFPA、規格番号 70 に従って、電気的 に接地する必要があります。 警告 警告: 仪器上的此符号表示用户应参阅操作说明手册。 警告: 瓶口含有锐利的针,设计用于刺穿样本瓶的隔片。请勿将手指或不 当物体放入瓶口中。 警告: 根据样本组成的不同,诸如氯或溴等卤素,或氟化物、氰化物或其 它有毒盐的有毒火焰等可能会排放到分析仪的废物中。为防止吸入 有害火焰,向废物箱中添加碳酸钠 (苏打灰)以中和废物中的酸。 警告: 为防止吸入有毒火焰,要确保分析仪安装在通风良好的区域。 GE Analytical Instruments ©2013 43 of 238 DLM 68100-06 EN Rev. A...

  • Page 44

    警告: 在分析仪中使用有害试剂 (过硫酸钠、盐酸以及磷酸) 。仪器中排出的废物流 属酸性,必须妥善处理。请查询联邦、州和当地政府的法规。 警告: 这是安全等级 I 级产品。它必须连接到接地的电源上。为避免对分析仪造成损 坏,并避免受伤,要确保分析仪连接到电压正确的电源线上。 警告: 为确保正常工作并防止受伤,在分析仪护盖拆掉时不得操作分析仪。 警告: 需要进入分析仪内部的任何操作,包括安装维护物品,都可能会导致伤害。为 避免潜在的危险电击或灼伤,在打开分析仪之前请关闭电源并拔下电源线。在 接触任何电子器件时务必小心。 警告: 在搬运含有样本、标准、废物溶液或试剂的部件时,请佩戴眼睛保护和手套。 警告: 显示屏幕可能含有汞,而汞在您的所在地可能被认为是有害物质。根据联邦、 州或当地政府法规处置此物品。 警告: 一定要在关闭分析仪之前先停止分析。 警告: 这是 A 级产品。在室内环境中,该产品可能会造成电磁干扰,此时用户需要采 取适当措施消除干扰。 GE Analytical Instruments ©2013 44 of 238 DLM 68100-06 EN Rev. A...

  • Page 45

    警告: 如果该仪器以通用电气分析仪未规定的方式使用,该仪器所提供的保护可能会 受到损害。 警告 查阅随每个标准组和试剂配备的物质安全数据表 (MSDS) ,以确定正确的处置 技术。 警告 分析仪风扇附近避免置放异物,以避免将有害物吹入分析仪。用于反应器的冷 却空气进口在分析仪的底部,严禁纸张或其它物体堵塞或进入该入口。 警告 警告 警告 警告 GE Analytical Instruments ©2013 45 of 238 DLM 68100-06 EN Rev. A...

  • Page 46

    警告 警告 此设备必须按照地方法规和条例接地。在没有地方法规的情况下,必须 按照美国电工法 ANSI/NFPA 第 70 号的规定接地 . GE Analytical Instruments ©2013 46 of 238 DLM 68100-06 EN Rev. A...

  • Page 47: Chapter 1: Introduction

    Chapter 1. Introduction The Sievers* InnovOx On-Line TOC Analyzer from GE Analytical Instruments is a high-sensitivity Analyzer used to measure the concentration of total organic carbon (TOC), non-purgeable organic carbon (NPOC), total carbon (TC), and inorganic carbon (IC) in water samples. The Analyzer uses supercritical water oxidation (SCWO) to measure a wide range of carbon concentrations in complex sample matrices, including those containing high concentrations of total dissolved solids (TDS) and particulates.

  • Page 48

    Chapter 1: Introduction GE Analytical Instruments ©2013 48 of 238 DLM 68100-06 EN Rev. A...

  • Page 49: Chapter 2: System Description

    125 psig maximum with provided control valve 0.5 psig minimum without optional sample pump Stated analytical performance is achievable under controlled laboratory conditions that minimize operator and standards errors. GE Analytical Instruments ©2013 49 of 238 DLM 68100-06 EN Rev. A...

  • Page 50

    Delivery Pressure of 30-100 psi required when using the air purifier option; Delivery pressure must be regulated to 10-20 psi when using a cylinder of purified gas; Unit will consume up to 200 cc/min in NPOC mode. GE Analytical Instruments ©2013 50 of 238 DLM 68100-06 EN Rev. A...

  • Page 51

    Chapter 2: System Description GE Analytical Instruments ©2013 51 of 238 DLM 68100-06 EN Rev. A...

  • Page 52: System Overview

    Chapter 2: System Description System Overview The Sievers InnovOx On-Line TOC Analyzer consists of eleven major modules (see Figure 1): Multistream module, which accommodates two or five sample streams, depending on the Analyzer configuration. It also includes a vial port, which is used to calibrate the Analyzer. The multistream module also includes a port through which a check standard can be measured.

  • Page 53: Figure 1: Analyzer Schematic

    This schematic is a flattened image of the Analyzer’s components. For a spatial representation of the fluidics layout inside the instrument, refer to Figure 58 on page 183. GE Analytical Instruments ©2013 53 of 238 DLM 68100-06 EN Rev. A...

  • Page 54: Sample Flow Path

    The solution is not sparged when TC, IC, or TOC (TC-IC) is measured. However, IC is lost from the solution while it is in the sparging chamber because the solution is acidic, and the IC is converted into volatile CO . The instrument GE Analytical Instruments ©2013 54 of 238 DLM 68100-06 EN Rev. A...

  • Page 55

    When IC is to be measured, organics do not have to be oxidized. Therefore, the reactor is filled with the acidified sample as described above, but the reactor is not heated and no oxidizer is added. GE Analytical Instruments ©2013 55 of 238...

  • Page 56: Additional System Components

    • Input/Output board for processing digital input signals and analog and digital outputs • Terminator board, which terminates the M-LVDS bus and provides Ethernet and USB interfaces • Power Entry/Supply GE Analytical Instruments ©2013 56 of 238 DLM 68100-06 EN Rev. A...

  • Page 57: Data Outputs

    The Analyzer will export to the first inserted USB flash storage device. While this USB flash storage device is inserted, the Analyzer will not recognize any additional USB storage devices inserted in other USB ports. GE Analytical Instruments ©2013 57 of 238...

  • Page 58: 5-stream Configuration

    NEMA 4X Cabinet The optional NEMA 4x cabinet protects the Analyzer from water jets and the ingress of dust and corrosive gases that would interfere with operation of the Analyzer. GE Analytical Instruments ©2013 58 of 238 DLM 68100-06 EN Rev. A...

  • Page 59: Sample Filter Panel

    Some sample streams are not pressurized, or are not sufficiently pressurized to provide the necessary flow to the Analyzer. For that reason, the sample pump peristaltic accessory is available for those applications that require a pump to get the sample to the Analyzer. GE Analytical Instruments ©2013 59 of 238 DLM 68100-06 EN Rev. A...

  • Page 60

    Chapter 2: System Description GE Analytical Instruments ©2013 60 of 238 DLM 68100-06 EN Rev. A...

  • Page 61: Chapter 3: Interferences

    Compounds such as hydrazine and hydrogen peroxide may generate excessive volumes of gas during the oxidation. However, the InnovOx Analyzer can handle the additional pressure in the reactor associated with gas-producing samples. GE Analytical Instruments ©2013 61 of 238 DLM 68100-06 EN Rev. A...

  • Page 62: Reliability

    InnovOx TOC Analyzer uses supercritical water oxidation (SCWO). Salts tend to precipitate in the Reactor when supercritical conditions are reached. This makes those species less reactive during the oxidation, while the organic compounds are more soluble and, therefore, more reactive. GE Analytical Instruments ©2013 62 of 238 DLM 68100-06 EN Rev. A...

  • Page 63

    NPOC, TC, or TOC readings. Contact GE Analytical Instruments at 303.444.2009 or 1 (888) 245.2595 for questions about specific applications. Technical support in the United Kingdom is available at 44 (0) 161 864 6800.

  • Page 64

    Chapter 3: Interferences GE Analytical Instruments ©2013 64 of 238 DLM 68100-06 EN Rev. A...

  • Page 65: Chapter 4: Installation

    Chapter 4. Installation Overview This chapter provides installation instructions for the Sievers InnovOx On-Line TOC Analyzer and also includes information on the Analyzer design and function. An interior overview diagram is available in Chapter 8, "Maintenance." If you need additional assistance, contact GE Analytical Instruments Technical Support at 303.444-2009 or 888.245.2595, or in the United Kingdom at 44 (0) 161 866 9337.

  • Page 66: Additional Installation Equipment

    To install the InnovOx On-Line TOC Analyzer, you will also need to provide the following equipment: • Mounting hardware to support the Analyzer (see “Step 3: Select a Location for the Analyzer” on page 67.) GE Analytical Instruments ©2012 66 of 238 DLM 68100-06 EN Rev. A...

  • Page 67: Step 2: Complete The Identification Records

    The InnovOx On-Line TOC Analyzer is designed to be mounted on a Mounting Stand or on a wall. For an illustration of the required clearances for the Mounting Stand accessory, see Figure 2. GE Analytical Instruments ©2012 67 of 238...

  • Page 68: Figure 2 Mounting Stand - Clearances

    To mount a Filter Panel on the Mounting Stand, attach the two Filter Panel brackets 30.5 cm apart, as shown in Figure 2. Further instructions for installation of the Filter Panel are provided in the GE InnovOx Filter Panel Operation and Maintenance Manual.

  • Page 69: Figure 3 Attaching Mounting Brackets On The Analyzer

    We recommend when lifting the instrument that you use a two-person lift. OSHA standards require protecting employees from injury. This instrument weighs over 40 lbs. It is the policy of GE to require a two-person lift for items weighing over 40 lbs. GE Analytical Instruments ©2012 69 of 238 DLM 68100-06 EN Rev.

  • Page 70: Figure 4 Mounting The Analyzer To The Stand

    Chapter 4: Installation Figure 4: Mounting the Analyzer to the Stand GE Analytical Instruments ©2012 70 of 238 DLM 68100-06 EN Rev. A...

  • Page 71: Wall Mount Installation

    Connect the waste line, as follows: Connect one end of the waste tube to the elbow barb labeled “Waste to Drain,” as shown in Figure 5. Figure 5: Connecting the Waste Lines GE Analytical Instruments ©2012 71 of 238 DLM 68100-06 EN Rev. A...

  • Page 72

    (lye) or sodium carbonate (soda ash) to the waste container to neutralize acid in the waste. Locate the Analyzer in a well-ventilated area. Avoid stratification of the waste within the container by occasionally agitating the container. GE Analytical Instruments ©2012 72 of 238 DLM 68100-06 EN Rev. A...

  • Page 73: Step 5: Fill The Gas-liquid Separator

    Use the squeeze bottle to fill the gas-liquid separator through the center top barb until the water level is (as shown in Figure 6). Reconnect the tube to the barb. Figure 6: The Gas-Liquid Separator GE Analytical Instruments ©2012 73 of 238 DLM 68100-06 EN Rev. A...

  • Page 74: Step 6: Install Input/output, Cables, And Accessories

    — The maximum load for these ports is 30 VDC at 1.0 A or 125 VAC at 0.5 A. • TB4 Alarm Outputs (Alarms 1 and 2) — The maximum load for these ports is 30 VDC at 1.0 A or 125 VAC at 0.5 A. GE Analytical Instruments ©2012 74 of 238 DLM 68100-06 EN Rev. A...

  • Page 75: Table 1 Analog Outputs (tb1)

    4-20 mA outputs may be configured by the user to output NPOC, IC, TC, or TOC ppm levels. Table 2: Binary Input (TB2) Signal Function BININ1+ Start/ Stop BININ1- BININ2+ RESERVED BININ2- BININ3+ RESERVED BININ3- GE Analytical Instruments ©2012 75 of 238 DLM 68100-06 EN Rev. A...

  • Page 76: Alarm Outputs (tb3)

    Signal Function BINOUT3_NO BINOUT3_COM User Assigned Alarm #3 BINOUT3_NC BINOUT4_NO BINOUT4_COM User Assigned Alarm #4 BINOUT4_NC BINOUT5_NO BINOUT5_COM Analysis Complete Output BINOUT5_NC BINOUT6_NO BINOUT6_COM System Fault Alarm BINOUT6_NC GE Analytical Instruments ©2012 76 of 238 DLM 68100-06 EN Rev. A...

  • Page 77: Alarm Outputs (tb4)

    @ 1 AMP. +24 volts and system ground are provided for local use only and are not intended for connections more than 15 feet away from the Analyzer. GE Analytical Instruments ©2012 77 of 238 DLM 68100-06 EN Rev. A...

  • Page 78: Installing The 4-20 Ma Connection

    Binary Input using Analyzer’s Internal Supply shows how the internal 24 VDC of the Analyzer (on TB4) may be used to power the binary input. No menu configuration is necessary. For more information on using the binary input, see “Binary Input” on page 208. GE Analytical Instruments ©2012 78 of 238 DLM 68100-06 EN Rev. A...

  • Page 79: Installing The Analysis Complete Output Connection

    Once the binary output is wired properly, the Analyzer will automatically provide a one-second contact closure at the end of every sample analysis. No menu configuration is necessary. The binary output is active in the Online, Check Standard, and Grab modes. GE Analytical Instruments ©2012 79 of 238 DLM 68100-06 EN Rev. A...

  • Page 80: Installing The Alarms And System Fault Output Connection

    Analyzer to a Computer). Or, as shown in see Figure 11, a straight-through Ethernet cable is used to connect to a network. Figure 10: Connecting the Analyzer to a Computer GE Analytical Instruments ©2012 80 of 238 DLM 68100-06 EN Rev. A...

  • Page 81: Installing The Usb Connection

    USB port to transfer exported data for import into a spreadsheet or database program. The Analyzer cannot be directly connected to a computer via the USB port. GE Analytical Instruments ©2012 81 of 238...

  • Page 82: Step 7: Connecting To A Power Supply

    Step 7: Connecting to a Power Supply Installation of the Sievers InnovOx On-Line TOC Analyzer requires an external source of AC power connected to the enclosure using a watertight, grounded conductive conduit connector. A qualified electrician should make the electrical connections according to local Electrical Code.

  • Page 83: Step 8: Connect The Sample Inlet System

    Connect the other end to the barbed Luer-Lok adapter fitting provided with the Sample Peristaltic Pump. Attach the fitting to the pump inlet on the top of the pump head. GE Analytical Instruments ©2012 83 of 238...

  • Page 84: Installing The Check Standard System

    Insert the other end of the tube assembly into the opening of the carboy. Fill the “Dilution Water” carboy with deionized water or the best-quality water available to you. GE Analytical Instruments ©2012 84 of 238 DLM 68100-06 EN Rev. A...

  • Page 85: Step 10: Connect The Compressed Gas

    Air Purifier is installed. The Air Purifier removes CO and moisture from compressed air that is pressurized from 30 to 100 psig (207 to 689 kPa). GE Analytical Instruments ©2012 85 of 238 DLM 68100-06 EN Rev. A...

  • Page 86: Installing The Gas Supply For The Ip56 Accessory

    The System Info screen appears with a reminder to attach the waste lines. If the waste lines were not attached already, do that now (see Installation Step 4). When ready, press the Main button on the display. GE Analytical Instruments ©2012 86 of 238 DLM 68100-06 EN Rev. A...

  • Page 87: Setting The Clock

    Press 3, then press Enter to set the Analyzer to 3 replicate measurements. Ensure that the other settings in the Protocol Setup screen are: • Measure: NPOC • Acid: • Oxid: • Rej: • Flush: GE Analytical Instruments ©2012 87 of 238 DLM 68100-06 EN Rev. A...

  • Page 88: Step 13: Calibrate The Analyzer

    Before placing the Analyzer into normal operation, calibrate the Analyzer in a manner suited to your application. Consult Chapter 5, "Calibration and Verification" for details on calibration options. GE Analytical Instruments ©2012 88 of 238 DLM 68100-06 EN Rev. A...

  • Page 89: Chapter 5: Calibration And Verification

    Chapter 5. Calibration and Verification Overview Calibration of the Sievers InnovOx On-Line TOC Analyzer for NPOC, IC, TC and TOC (TC- IC) measurements is accomplished using standards that contain known concentrations of the form of carbon of interest. It is required that the InnovOx be calibrated for the specific mode that you will be running samples.

  • Page 90: Handling Standards

    Calibration Group. Handling Standards GE Analytical Instruments recommends special handling of all standards to ensure proper preparation and analysis. Most standards are provided in 250 mL bottles. Before performing calibration or verification, standards solutions should be transferred into 40 mL vials for use with the Analyzer’s vial port. Additionally, observe the following practices: •...

  • Page 91: Calibration And Verification Options

    The concentration of samples is calculated from a calibration equation of the form: C = b*R where, R = Mass Response, μg b = Calibration constant (slope) C = mg/L Carbon, ppm GE Analytical Instruments ©2013 91 of 238 DLM 68100-06 EN Rev. A...

  • Page 92: Two-point Calibration

    TC and IC regardless of the variability of the individual concentrations. Figure 15 depicts a two-point calibration in which point 1 is not reagent water. The concentrations of both points are entered into the calibration protocol. GE Analytical Instruments ©2013 92 of 238 DLM 68100-06 EN Rev. A...

  • Page 93: Two-point Calibration (point 1 Is Standard)

    For the case in which point 1 is reagent water, the calibration of the Analyzer is depicted graphically in Figure 16. The operator designates point 1 as reagent water in the protocol by setting its concentration to 0 ppm. The Analyzer interprets “0 ppm” as “reagent water.” GE Analytical Instruments ©2013 93 of 238 DLM 68100-06 EN Rev. A...

  • Page 94: Two-point Calibration (point 1 Is Reagent Water)

    = Response of Analyzer to point 2 = Response of Analyzer to reagent water = TOC concentration of point 1 (= 0 for RW) = TOC concentration of point 2 (mg/L) GE Analytical Instruments ©2013 94 of 238 DLM 68100-06 EN Rev. A...

  • Page 95: Calibration With More Than Two Points

    C = a + b*R A correlation coefficient, R , is also calculated. The correlation coefficient is a statistical measure of agreement between the measured values (R) and standard concentration (C). GE Analytical Instruments ©2013 95 of 238 DLM 68100-06 EN Rev. A...

  • Page 96: Point-to-point Multi-point Calibration

    When this calibration is later applied to a sample, the Analyzer applies the appropriate intercept and slope, based on the magnitude of its mass response for that sample. GE Analytical Instruments ©2013 96 of 238 DLM 68100-06 EN Rev. A...

  • Page 97: Auto Dilution

    40 ppm via Auto Dilution, you must start with a standard less than 1000 ppm TOC. Generally, best performance is found when the dilution ratio does not exceed 10:1 (e.g., a 1000 ppm standard diluted to 100 ppm). GE Analytical Instruments ©2013 97 of 238 DLM 68100-06 EN Rev. A...

  • Page 98: Blank Correction

    Analyzer which calibration to use in each range. The Analyzer can store up to 20 calibration groups. To set up a calibration group From the Menu screen, select Cal/Ver. Select Calibration Groups. Press the New button. GE Analytical Instruments ©2013 98 of 238 DLM 68100-06 EN Rev. A...

  • Page 99: Preparing For Calibration

    While this USB flash storage device is inserted, the Analyzer will not recognize any additional USB storage devices inserted in other USB ports. The Analyzer can take up to 15 seconds to recognize the flash storage device. GE Analytical Instruments ©2013 99 of 238 DLM 68100-06 EN Rev. A...

  • Page 100: Perform Maintenance Tasks

    TOC (so called because both TC and TOC are calibrated simultaneously). Select the appropriate default to modify. Certain protocol variables will be enabled or disabled depending on the type of calibration you are creating. GE Analytical Instruments ©2013 100 of 238 DLM 68100-06 EN Rev. A...

  • Page 101

    The box in the lower-left corner of the screen will tell you what type of sample is expected (e.g., NPOC Standard, IC Standard, Rinse or TOC Standard). GE Analytical Instruments ©2013 101 of 238 DLM 68100-06 EN Rev. A...

  • Page 102: Calibrating The Analyzer

    • RSD: Indicates the percent relative standard deviation of the non-rejected measurements of the standard. • Adjusted: Indicates the calculated concentration of the standard, using the new calibration constants from the calibration just completed. GE Analytical Instruments ©2013 102 of 238 DLM 68100-06 EN Rev. A...

  • Page 103

    USB flash memory drives are connected to more than one USB port, the Analyzer will only export to the first USB flash memory drive inserted. The Analyzer can take up to 15 seconds to recognize the flash storage device. GE Analytical Instruments ©2013 103 of 238 DLM 68100-06 EN Rev. A...

  • Page 104: Editing A Calibration

    When the Back button is pressed, the Calibration Summary screen is shown again, with the new slope, intercept, measured and % RSD. Remember to press the Apply button to save the edited calibration. GE Analytical Instruments ©2013 104 of 238...

  • Page 105: Performing A Calibration Verification

    If Auto Dilution is employed, more repetitions are possible than are shown in Table 7, but the maximum number of repetitions that can be selected is 20. GE Analytical Instruments ©2013 105 of 238 DLM 68100-06 EN Rev. A...

  • Page 106: Reviewing Calibration And Verification History

    10802 to access the exported file, and capture the file under file name you select. Then, press the Cal. CSV to Ethernet button or the Ver. CSV to Ethernet button. Printing of the Cal/Ver history is also available if the printer is set up. GE Analytical Instruments ©2013 106 of 238 DLM 68100-06 EN Rev. A...

  • Page 107: Chapter 6: Analyzer Operation

    Analyzer. When the Analyzer is first powered on, a startup screen appears with basic GE Analytical Instruments contact information and the firmware version number. The Analyzer then begins initialization to check the status of consumables and prepare for making measurements.

  • Page 108: The Main Screen

    S2, S3, S4, and S5 tabs — When making Online measurements, select (press) any of these tabs (located along the top of the screen) to display peaks or data from each enabled stream. GE Analytical Instruments ©2013 108 of 238 DLM 68100-06 EN Rev. A...

  • Page 109: The Menu Screen

    “Viewing and Exporting Data” on page 133.) • I/O — Configure the Analyzer’s input and output interfaces. (Information for using this tab is included in “Setting Up Input and Output (I/O)” on page 137.) GE Analytical Instruments ©2013 109 of 238 DLM 68100-06 EN Rev. A...

  • Page 110: Setting Up Measurements (the Setup Tab)

    When operating in Rinse mode, the measurements are not stored in the Analyzer’s Data History in order to ensure that this data is not confused with measurements of real samples. GE Analytical Instruments ©2013 110 of 238 DLM 68100-06 EN Rev. A...

  • Page 111: Online Measurements

    (the Check Standard Frequency). Since two Repetitions have been selected, the check standard is measured twice every three hours. The first measurement is ignored because it has been designated as a Reject. GE Analytical Instruments ©2013 111 of 238 DLM 68100-06 EN Rev. A...

  • Page 112: Operation With Multiple Streams

    Minimize the concentration difference between adjacent streams. It takes more time to get an accurate measurement because more Sample Flushes are required, when one stream is a much higher concentration than the following stream. GE Analytical Instruments ©2013 112 of 238 DLM 68100-06 EN Rev. A...

  • Page 113: Cycle Frequency

    • The number of Dilution Water and Sample Flushes selected • The type of measurement selected (NPOC, TOC, and so on) • Whether or not AutoRange is selected GE Analytical Instruments ©2013 113 of 238 DLM 68100-06 EN Rev. A...

  • Page 114: Figure 26 Calculating The Run Time

    Auto Range measurements require more time than when a particular Range is selected. Possibly one or more measurements can be made with fewer or no Sample Flushes. GE Analytical Instruments ©2013 114 of 238 DLM 68100-06 EN Rev. A...

  • Page 115: Configuring Online Measurements

    The Fail Safe button, previously located on this screen, has been moved to the Advanced screen (Maintenance Tab > Advanced). For information on this feature, refer to “Setting the Fail Safe Option” on page 145. GE Analytical Instruments ©2013 115 of 238 DLM 68100-06 EN Rev. A...

  • Page 116: Operation With Multiple Streams

    Figure 28: Stream 1 Screen If the stream button is disabled, press the Enabled button that appears to the right. At least one stream must always be enabled in Online mode. GE Analytical Instruments ©2013 116 of 238 DLM 68100-06 EN Rev. A...

  • Page 117

    Use Sample Flushes to quickly reach steady-state response when the Analyzer will be switching from one stream to another and the two streams have very different concentrations. • If you have a GE InnovOx Filter Panel installed (ONLY), press the Blowback Pulses button to set the number of pulses.

  • Page 118: Check Standards

    “Check Standards” on page 118. Any changes made to the Check Standard Measurement (Manual Start) are also applied to the Check Standard Measurement (Scheduled). See page 118. GE Analytical Instruments ©2013 118 of 238 DLM 68100-06 EN Rev. A...

  • Page 119: Figure 29: Check Standard Setup Screen

    20% above the Concentration value. Press the Check Std. Setup button. The following buttons appear on the Check Standard screen. Figure 30: Check Standard (with Setup Buttons) Screen GE Analytical Instruments ©2013 119 of 238 DLM 68100-06 EN Rev. A...

  • Page 120

    On the Setup tab, press the Check Standard button. The Check Standard Setup button appears to the right. Press the Check Standard Setup button. The Check Standard (Setup) screen appears. GE Analytical Instruments ©2013 120 of 238 DLM 68100-06 EN Rev. A...

  • Page 121: Check Standard (setup) Screen

    111. Use this feature to exclude initial measurements when the concentration of the check standard is different from the previously measured sample, so that the average of the check standard measurements is accurate. GE Analytical Instruments ©2013 121 of 238 DLM 68100-06 EN Rev. A...

  • Page 122: Clean Inlet

    On the Configure Online screen, press the Daily Flush button. An On button and an Off button appear to the right. Press either the On or Off button, as needed. Proceed to the next instruction to set the Daily Flush start time. GE Analytical Instruments ©2013 122 of 238 DLM 68100-06 EN Rev. A...

  • Page 123: Summary

    On the Setup tab, press the Grab button. The Analysis Protocol button appears on the right. Press the Analysis Protocol button. The Protocol screen appears with a listing of protocols. Figure 32: The Protocol Screen GE Analytical Instruments ©2013 123 of 238 DLM 68100-06 EN Rev. A...

  • Page 124

    RSD criteria. If you enter 7 Max Reps and 2 Min Reps, the Analyzer will run at least two repetitions and compare the calculated RSD to the RSD criteria entered. If the calculated RSD is GE Analytical Instruments ©2013 124 of 238...

  • Page 125

    As an example,, the following table lists the approximate number of repetitions possible when using 40-mL vials. The possible number of repetitions varies according to the size of the vials used in the protocol. GE Analytical Instruments ©2013 125 of 238 DLM 68100-06 EN Rev. A...

  • Page 126: Table 8 Vial Port - Repetitions Possible

    Completely Filled 40-mL Vials Flushes Dilution None 1 Sample 2 Sample 3 Sample Mode Water Auto Range NPOC 1,000-ppm Range NPOC 5,000-ppm Range NPOC 20,000-ppm Range NPOC 50,000-ppm Range NPOC GE Analytical Instruments ©2013 126 of 238 DLM 68100-06 EN Rev. A...

  • Page 127: Rinse

    (TOC = TC - IC). In order for the TOC measurement to be as accurate as possible, the solution is introduced into the Sparger prior to loading the Reactor. GE Analytical Instruments ©2013 127 of 238 DLM 68100-06 EN Rev. A...

  • Page 128: Range

    To determine the correct setting for those kinds of samples, increase the acid percentage until further increases do not result in higher measured values. GE Analytical Instruments ©2013 128 of 238 DLM 68100-06 EN Rev. A...

  • Page 129: Oxidizer

    NPOC mode. However, the composition of the sample can affect this. The frit in the Sparging Chamber also may become contaminated during use, requiring longer sparge times. Therefore, the sparge can be set up to a maximum of 30 min. GE Analytical Instruments ©2013 129 of 238 DLM 68100-06 EN Rev. A...

  • Page 130: Flush

    Press the Factor 1 Units button to edit the final result units. This may be an alphanumeric string. Press the Save button. Repeat steps 3 to 6 to edit Factor 2. GE Analytical Instruments ©2013 130 of 238 DLM 68100-06 EN Rev. A...

  • Page 131: User Management

    Write down your passwords and store them in a safe place for future reference. If you have forgotten your password, you will need to contact GE to help unlock your Analyzer with the keycode that appears on the Login screen.

  • Page 132: Measuring The Blank

    When the analysis is complete, the Analyzer displays a results screen that lists the measured TC, IC and TOC concentrations of dilution water, acid, and oxidizer. To save the measured blank values, press the Apply button. GE Analytical Instruments ©2013 132 of 238 DLM 68100-06 EN Rev. A...

  • Page 133: Viewing And Exporting Data

    Touch the screen or use the Page Up/Page Down buttons to move through the list of sampling data that appears. To view data starting at a specific date, press the Go To button and use the date buttons to specify the starting date. GE Analytical Instruments ©2013 133 of 238 DLM 68100-06 EN Rev. A...

  • Page 134: Exporting Data

    Press the Range button to select the time frame for the data to export. The following buttons appear on the right: • 1 Day • 1 Week • All • Custom (Enter a specific date and time range.) GE Analytical Instruments ©2013 134 of 238 DLM 68100-06 EN Rev. A...

  • Page 135: Figure 36: Export Data Screen

    • CSV to Ethernet — Exports a comma-separated text file via the Ethernet port. • Export PDF to USB — Exports a PDF file to a USB flash memory drive. Press the Back button to return to the Data tab. GE Analytical Instruments ©2013 135 of 238 DLM 68100-06 EN Rev. A...

  • Page 136: Reviewing Exported Data

    Manual Dilution Numeric Value Calibration Name Alphanumeric characters Calibration Date MM/DD/YYYY HH:MM Error/Warning Error/Warning Number (mg) Mass of CO measured (mg). Rejects are not reported. Mass Response (µg) Equation GE Analytical Instruments ©2013 136 of 238 DLM 68100-06 EN Rev. A...

  • Page 137: Setting Up Input And Output (i/o)

    • Off (default) — Indicates that the Analyzer is not communicating with a network or other computer. • Automatic — The Analyzer is connected to your network with a standard ethernet cable, and your network uses a DHCP server to dynamically assign IP addresses. GE Analytical Instruments ©2013 137 of 238 DLM 68100-06 EN Rev. A...

  • Page 138: Configuring A Personal Computer

    However, there are instances in which autonegotiation may fail or be disabled. In such cases, the Ethernet interface will need to be configured manually to the "10BASE-T half duplex" setting on the remote device. Contact your IT professional for help with this configuration. GE Analytical Instruments ©2013 138 of 238 DLM 68100-06 EN Rev. A...

  • Page 139

    192.168.1.11. Enter a subnet mask address. This should be the same numbers as those used on the Analyzer. 10. Click the OK button. 11. Click the OK button. GE Analytical Instruments ©2013 139 of 238 DLM 68100-06 EN Rev. A...

  • Page 140: Collecting Real-time Data

    To set the alarms Select the I/O tab. Press one of the alarm output buttons (such as the Alarm 1 button). The Alarm Output screen appears. Figure 38: Alarm Output Screen GE Analytical Instruments ©2013 140 of 238 DLM 68100-06 EN Rev. A...

  • Page 141: Resetting Alarms

    (not supplied with Analyzer). Select the I/O menu and select "Printer Setup" option. Select the Printer Disabled button to change it to Printer Enabled. Select the Search button to have the InnovOx search for a connected approved HP Printer. GE Analytical Instruments ©2013 141 of 238 DLM 68100-06 EN Rev. A...

  • Page 142: Figure 39 Print Data Screen

    Chapter 6: Analyzer Operation To print data Select the Data tab. Click the Print button. Select the desired result file and then click the Print option. Figure 39: Print Data Screen GE Analytical Instruments ©2013 142 of 238 DLM 68100-06 EN Rev. A...

  • Page 143: Configuring Advanced Setup

    Press the Location button, and use the keyboard that appears to specify the location of the Analyzer. Press Set Location. The Advanced screen appears again. Press the Back button to return to the Maintenance tab. GE Analytical Instruments ©2013 143 of 238 DLM 68100-06 EN Rev. A...

  • Page 144: Setting System Properties

    Set the Analyzer clock to ensure that all TOC measurements reflect the correct date and time. To set the clock Select the Maintenance tab. Press the Advanced button. The Advanced screen appears. GE Analytical Instruments ©2013 144 of 238 DLM 68100-06 EN Rev. A...

  • Page 145: Upgrade Option

    USB key. If you downloaded the upgrade files from the GE website, make sure that the files are saved in the proper folders on your USB key (:\InnovOx\Upgrade). After you install your USB key in the USB port, wait 15 seconds and then select the Upgrade button.

  • Page 146: Setting The Keyboard Options

    Insert a USB flash drive into the USB port, and wait 15 seconds. Select the Maintenance tab. Press the Advanced button. The Advanced screen appears. Press the Archive Data button. GE Analytical Instruments ©2013 146 of 238 DLM 68100-06 EN Rev. A...

  • Page 147: Shutting Down The Analyzer

    When you are ready to resume operation after shutting down the Analyzer, follow these steps: Ensure that AC power is connected and the power switch is in the On position. Press the touchscreen to start the Analyzer. GE Analytical Instruments ©2013 147 of 238 DLM 68100-06 EN Rev. A...

  • Page 148

    Chapter 6: Analyzer Operation GE Analytical Instruments ©2013 148 of 238 DLM 68100-06 EN Rev. A...

  • Page 149: Chapter 7: Operation With The Filter Panel

    200 m. The InnovOx On-Line TOC Analyzer is designed to control up to five Filter Panels. Refer to the GE Filter Panel Operation and Maintenance Manual for instructions on the installation and setup of the Filter Panel.

  • Page 150: Figure 42: Blowback Pulses And Delay

    Air to Filter Panel port 1. Confirm that compressed air is connected to the Blowback Air port on the Filter Panel. If the Analyzer is making measurements, stop the analysis. GE Analytical Instruments ©2013 150 of 238 DLM 68100-06 EN Rev. A...

  • Page 151: Flush/blowback Screen

    Enter. Press the Blowback Delay button. Enter the delay time in seconds (0 through 300) on the keypad that appears to the right, and then press Enter. GE Analytical Instruments ©2013 151 of 238 DLM 68100-06 EN Rev. A...

  • Page 152

    Chapter 7: Operation with the Filter Panel GE Analytical Instruments ©2013 152 of 238 DLM 68100-06 EN Rev. A...

  • Page 153: Chapter 8: Maintenance

    Refer to Table 11 for the recommended consumables replacement schedule. Maintenance items MUST be purchased from GE Analytical Instruments. If you need additional assistance, contact GE Analytical Instruments Technical Support at 303. 444.2009 or 888.245.2595. Training is also available. Technical support in the United Kingdom is available at 44 (0) 161 866 9337.

  • Page 154: Recommended Spare Parts

    This inspection is automatically performed by the Analyzer if the Fail Safe accessory is installed and activated. The Analyzer can be set to automatically perform the Check Standard measurements. GE Analytical Instruments ©2013 154 of 238 DLM 68100-06 EN Rev. A...

  • Page 155: Figure 45 Aging Of 30% (w/v) Na

    Seal the container with the bottle cover that does not have a hole, and shake the bottle to dissolve the oxidizer. d. Transfer the solution to the 5-gallon oxidizer carboy. Repeat steps 1a-1d until the 5-gallon oxidizer carboy is filled with the desired volume of solution. GE Analytical Instruments ©2013 155 of 238 DLM 68100-06 EN Rev. A...

  • Page 156: Preparing The Acid

    The Check Standard must be the Enabled state. • Flush All: Flushes the Acid, Oxidizer, Check Standard, and Dilution Water. The Check Standard must be the Enabled state. GE Analytical Instruments ©2013 156 of 238 DLM 68100-06 EN Rev. A...

  • Page 157: Cleaning The Analyzer

    Fill the gas-liquid separator with DI water from the center port on top. 10. Secure the gas-liquid separator to the bracket by tightening the screw. Do not over-tighten. GE Analytical Instruments ©2013 157 of 238 DLM 68100-06 EN Rev. A...

  • Page 158: Cleaning The Sparger

    Wait for the display to turn off, and then turn off power to the Analyzer using the main power switch on the side of the Analyzer. Open the door of the Analyzer. GE Analytical Instruments ©2013 158 of 238 DLM 68100-06 EN Rev. A...

  • Page 159: Figure 47 The Sparger

    13. Reattach the tubing to the four barbs. 14. Perform other maintenance tasks, or close the Analyzer door and return the Analyzer to normal operation. Figure 47: The Sparger GE Analytical Instruments ©2013 159 of 238 DLM 68100-06 EN Rev. A...

  • Page 160: Lubricating The Syringe

    Washers* *If these washers are NOT installed with your Analyzer. ignore this Figure 48: Locating the Syringe Screw and Washers GE Analytical Instruments ©2013 160 of 238 DLM 68100-06 EN Rev. A...

  • Page 161: Figure 49 Unscrewing The Syringe Base

    The washer should remain in the valve. If the washer comes free of the valve when you remove the syringe, be sure to capture the washer for reinstallation. You must place the washer back on the plunger tip when reinstalling. Figure 50: Removing the Syringe GE Analytical Instruments ©2013 161 of 238 DLM 68100-06 EN Rev. A...

  • Page 162: Figure 51 Pulling Out The Plunger

    11. Swirl the syringe tip once in the slightly moistened wipe and reinstall it into the syringe barrel. Cycle two or three strokes to ensure adequate distribution of the lubricant. Figure 53: Distributing the Lubricant GE Analytical Instruments ©2013 162 of 238 DLM 68100-06 EN Rev. A...

  • Page 163: Consumables Replacement

    Analyzer’s Main screen and on the Consumables screen. For this procedure, the Analyzer should be powered on. Contact GE Analytical Instruments at 303. 444.2009 or 800.255.2595 for a replacement kit. Technical support in the United Kingdom is available at 44 (0) 161 864 6800.

  • Page 164

    Perform other maintenance tasks, or close the Analyzer door and return the Analyzer to normal operation. 10. Before resuming analysis, enter the installation date for the new sample tubing. See “Entering Consumables Installation Information” on page 168. GE Analytical Instruments ©2013 164 of 238 DLM 68100-06 EN Rev. A...

  • Page 165: Figure 54 Valve Locations - Innovox On-line Toc Analyzer

    Chapter 8: Maintenance Figure 54: Valve Locations - InnovOx On-Line TOC Analyzer GE Analytical Instruments ©2013 165 of 238 DLM 68100-06 EN Rev. A...

  • Page 166: Replacing The Peristaltic Pumps

    The NDIR Filter (Figure 55) should be replaced if the Filter has become plugged with aerosols, if liquid has gotten into the NDIR from the Gas-Liquid Separator, or after 12 months of operation. Replacement of the NDIR Filter is GE Analytical Instruments ©2013 166 of 238...

  • Page 167: Figure 55: Replacing The Ndir Filter

    Attach the new filter to the tubing. Perform other maintenance tasks, or close the Analyzer door and return the Analyzer to normal operation. Figure 55: Replacing the NDIR Filter GE Analytical Instruments ©2013 167 of 238 DLM 68100-06 EN Rev. A...

  • Page 168: Entering Consumables Installation Information

    Wear eye protection and gloves when performing this task. The Sievers InnovOx Online TOC Analyzer has two high pressure valves (V4-R and V5-R). These valves are identified in Figure 54. Each valve contains a seal that wears over time. The seals should be replaced after one month of operation.

  • Page 169: Figure 56: The High Pressure Valve Seal - Before Removal

    20 measurements before the Analyzer will achieve its maximum precision. Figure 56: The High Pressure Valve Seal — Before Removal Figure 57: The High Pressure Valve Seal — After Removal GE Analytical Instruments ©2013 169 of 238 DLM 68100-06 EN Rev. A...

  • Page 170: Table 12 2-year Maintenance Worksheet - Sievers Innovox Online Toc Analyzer

    Chapter 8: Maintenance Table 12: 2-Year Maintenance Worksheet — Sievers InnovOx Online TOC Analyzer Item Operating Time Installation Date Notes Acid reagent Initial Install Oxidizer reagent Initial Install Dilution water Initial Install High pressure valve seals 1 month High pressure valve seals...

  • Page 171

    Chapter 8: Maintenance Table 12: 2-Year Maintenance Worksheet — Sievers InnovOx Online TOC Analyzer Item Operating Time Installation Date Notes Syringe lubrication 12 months Sample/Reagent peristaltic pump heads 12 months Waste tubing (black) 12 months High pressure valve seals 13 months...

  • Page 172

    Chapter 8: Maintenance Table 12: 2-Year Maintenance Worksheet — Sievers InnovOx Online TOC Analyzer Item Operating Time Installation Date Notes Syringe lubrication 24 months Waste tubing (black) 24 months Analyzer Serial number ______________Date placed into operation __________ Dates of operation encompassed by this worksheet: from __________to __________ GE Analytical Instruments ©2013...

  • Page 173: Chapter 9: Troubleshooting

    303.444.2009. Technical support in the United Kingdom is available at 44 (0) 161 866 9337. In other parts of the world, contact your local GE Analytical instruments representative. You can also visit the support tab on our website at www.geinstruments.com.

  • Page 174: Analyzer Warnings And Error Messages

    50 - Power Error on System/Controller Board Message: "Power error on System/Controller Board. Please power cycle the Analyzer. If the problem persists, export errors and contact GE Analytical Instruments for further instructions and analysis." Explanation: Replace the System/Controller Board. 150 - Software Control Error Message: "Software control error.

  • Page 175

    Explanation: Based on the history of usage, the Analyzer estimates that only two weeks of pinch valve tubing remains. The tubing must be replaced to protect the operation of the pinch valves. Order tubing from GE now to avoid down time and more costly failures of pinch valves.

  • Page 176

    Explanation: This is a failure to read information from the iButton. This information includes the serial number, family, and model. Possible reasons for failure include corrosion on iButton contacts, a gap between the iButton and system board contacts, or a component failure. Consult GE Analytical Instruments for further instructions on determining the root cause.

  • Page 177

    Explanation: Check that water is flowing in the sample cup and the inlet valve (if installed) is properly adjusted. If the problem persists, please export the errors and contact GE Analytical Instruments for further instructions. 6417 – Stream 2 Flow Error Message: “Stream 2 flow stopped.”...

  • Page 178

    Explanation: This error is associated with the creation of a .pdf file. If you are creating a .pdf from the Analyzer, shut down the Analyzer, power cycle and repeat. If the problem persists, contact GE Analytical Instruments for further instructions.‘...

  • Page 179

    Then, check the cable connections. You may be able to regain control of the unit by plugging a mouse into any of the USB port. If the problem persists please export the errors and contact GE Analytical Instruments for further instructions.”...

  • Page 180

    Explanation: An error has been found during writing to the data history portion of the flash memory card on the Analyzer’s System Controller Board. Archiving the Datastore manually may alleviate the issue. See “Archiving the Data History” on page 146 for instructions. If this error persists, please contact GE Analytical Instruments. 6433 – Sparger Gas Flow Error Message: “Go to the Diagnostics screen and run the Gas Valves test (V7-SH).

  • Page 181

    Message: “System either failed to detect an HP printer, or the printer is not currently supported. Please export the errors and diagnostics, and contact GE Analytical Instruments for further instructions.” Explanation: Please refer to Chapter 7 for a list of supported printers.

  • Page 182: Other Software Errors

    If possible, perform the inspection with the Analyzer in analysis mode so you can verify that relevant modules are performing as usual (described below). GE Analytical Instruments ©2013 182 of 238 DLM 68100-06 EN Rev. A...

  • Page 183: Figure 58 The Fluidics Side Of The Analyzer

    Chapter 9: Troubleshooting Figure 58: The Fluidics Side of the Analyzer GE Analytical Instruments ©2013 183 of 238 DLM 68100-06 EN Rev. A...

  • Page 184: Figure 59 The Electronics Side Of The Analyzer

    Power Supply Terminator Board NDIR Board Multistream Module Board Gas Control Module Board Reactor Sample Handling Module Board Module Board Figure 59: The Electronics Side of the Analyzer GE Analytical Instruments ©2013 184 of 238 DLM 68100-06 EN Rev. A...

  • Page 185: Figure 60 Electronics In The Top Of The Analyzer

    Chapter 9: Troubleshooting System Controller Power Supply Board Analog I/O Board Front of Analyzer Multi-stream Module Board Figure 60: Electronics in the Top of the Analyzer GE Analytical Instruments ©2013 185 of 238 DLM 68100-06 EN Rev. A...

  • Page 186: Figure 61: Analyzer Schematic

    Chapter 9: Troubleshooting Figure 61: Analyzer Schematic GE Analytical Instruments ©2013 186 of 238 DLM 68100-06 EN Rev. A...

  • Page 187: External Inspection

    If excessive bubbles are present, a flush should be performed. Look to see if air flows into the reagent lines during flushing. GE Analytical Instruments ©2013 187 of 238 DLM 68100-06 EN Rev. A...

  • Page 188: Figure 62 Connections To The Gas-liquid Separator

    • If maintenance work has recently been performed on the Analyzer, confirm that electronics cables are securely attached. Figure 62: Connections to the Gas-Liquid Separator GE Analytical Instruments ©2013 188 of 238 DLM 68100-06 EN Rev. A...

  • Page 189: Reviewing Solutions For Basic Problems

    If you press the Cancel or Back button, the activated components are immediately turned off again. As a result, several of the GE Analytical Instruments ©2013 189 of 238...

  • Page 190: Pinch Valves

    V1-MS through V5-MS refer to the pinch valves in streams 1-5, respectively. Values V3-MS through V5-MS are not installed in 2-stream Analyzers. V6-MS is for the Check Standard port and V7-MS is for the Vial port. GE Analytical Instruments ©2013 190 of 238...

  • Page 191: Gas Valves

    • Valve V2-R is closed • Proportional valve, V2-GS, is set to its normal set point for the carrier gas flow • Carrier Gas Valve, V1-R, is opened. GE Analytical Instruments ©2013 191 of 238 DLM 68100-06 EN Rev. A...

  • Page 192: Ndir

    This screen provides temperature information to facilitate troubleshooting: • The Source Temperature is maintained at 65 °C + 2 • The Detector Temperature is maintained at 55 °C + 2 GE Analytical Instruments ©2013 192 of 238 DLM 68100-06 EN Rev. A...

  • Page 193: Heater

    To stop the heater diagnostic, press the Back button. The heater may be hot if this is done before the cycle is allowed to complete, however. To quickly cool the heater, press the Heater button from the Diagnostics menu to activate the fan. GE Analytical Instruments ©2013 193 of 238 DLM 68100-06 EN Rev. A...

  • Page 194: Liquid Flow

    If the liquid level in the sparger does not drop, it indicates that the tube is plugged. GE Analytical Instruments ©2013 194 of 238...

  • Page 195: Gas Leak Checks

    The Gas Control Module pressurizes the lines using the optional air pump P1-GS or the pressurized gas source for 10 sec., then valve V2-GS closes to trap that pressure in the area being tested. During this 10-sec. pressurization period, the timer remains at 00:00. GE Analytical Instruments ©2013 195 of 238 DLM 68100-06 EN Rev. A...

  • Page 196

    V1-R, V2-R, and V7-SH. Ensure the brass fittings on the gas manifold in the Gas Control Manifold are not leaking. Check gas connections leading to the NDIR end caps. If all of those items are correct, then contact GE Analytical Instruments for further information. •...

  • Page 197: Figure 70: Gas Manifold Leak Check

    Chapter 9: Troubleshooting Figure 70: Gas Manifold Leak Check GE Analytical Instruments ©2013 197 of 238 DLM 68100-06 EN Rev. A...

  • Page 198: Reactor Inlet Valve Leak Check

    Remove the plug on the NDIR end cap outlet gas line if this is the last leak test to be performed. Otherwise, leave the plug in place and proceed to the next leak test. GE Analytical Instruments ©2013 198 of 238...

  • Page 199: Figure 71: Reactor Inlet Valve Leak Check

    Chapter 9: Troubleshooting Figure 71: Reactor Inlet Valve Leak Check GE Analytical Instruments ©2013 199 of 238 DLM 68100-06 EN Rev. A...

  • Page 200: Reactor Bypass Leak Check

    Remove the plug on the NDIR end cap outlet gas line if this is the last leak test to be performed. Otherwise, leave the plug in place and proceed to the next leak test. GE Analytical Instruments ©2013 200 of 238...

  • Page 201: Figure 72: Reactor Bypass Leak Check

    Chapter 9: Troubleshooting Figure 72: Reactor Bypass Leak Check GE Analytical Instruments ©2013 201 of 238 DLM 68100-06 EN Rev. A...

  • Page 202: Reactor Leak Check

    Remove the plug on the NDIR end cap outlet gas line if this is the last leak test to be performed. Otherwise, leave the plug in place and proceed to the next leak test. GE Analytical Instruments ©2013 202 of 238...

  • Page 203: Figure 73: Reactor Leak Check

    Chapter 9: Troubleshooting Figure 73: Reactor Leak Check GE Analytical Instruments ©2013 203 of 238 DLM 68100-06 EN Rev. A...

  • Page 204: Reactor Outlet Valve Leak Check

    V5-R may need to be replaced. • Remove the plug on the NDIR end cap outlet gas line. GE Analytical Instruments ©2013 204 of 238 DLM 68100-06 EN Rev. A...

  • Page 205: Figure 74 Reactor Valve Outlet Check

    Chapter 9: Troubleshooting Figure 74: Reactor Valve Outlet Check GE Analytical Instruments ©2013 205 of 238 DLM 68100-06 EN Rev. A...

  • Page 206: Gas Liquid Separator, Ndir Filter, Ndir Sample Path And Sparger Leak Check

    PV1-MS refers to the pneumatic valve in position 1, PV2-MS in position 2, etc. When the button is pressed, you should hear compressed air exit the selected valve, which is mounted on the left side of the Analyzer. GE Analytical Instruments ©2013 206 of 238 DLM 68100-06 EN Rev. A...

  • Page 207: Analog Output

    When the Binary Output screen first appears, it will show the current state of the outputs. When you exit the Binary Output screen, the outputs return to their original states. GE Analytical Instruments ©2013 207 of 238 DLM 68100-06 EN Rev. A...

  • Page 208: Binary Input

    Analysis Start/Stop binary input is activated when the Binary Input screen appears, the Analysis Start/Stop button will change from Off to On. However, the Analyzer will not start or stop analysis. GE Analytical Instruments ©2013 208 of 238 DLM 68100-06 EN Rev. A...

  • Page 209: Sample Pumps

    GE Analytical Instruments ©2013 209 of 238 DLM 68100-06 EN Rev. A...

  • Page 210: Export Diagnostic Data

    Returning the Analyzer to GE Analytical Instruments In some instances, after consulting with GE Analytical Instruments Technical Support, it may be necessary to return the Analyzer to the factory for repairs. Only return the Analyzer if Technical Support has issued you a Return Authorization (RA) number.

  • Page 211

    To prepare the Analyzer for shipping Before repackaging the Analyzer, prepare it for shipping. Warning If the Analyzer is returned in anything other than an GE Analytical Instruments shipping container, you will be charged for any damage that occurs during shipping.

  • Page 212

    Chapter 9: Troubleshooting GE Analytical Instruments ©2013 212 of 238 DLM 68100-06 EN Rev. A...

  • Page 213: Appendix A: Analyzer Dimension Diagrams

    Appendix A: Analyzer Dimension Diagrams Diagrams show Analyzer dimensions and required clearances. Figure 80: Analyzer Dimensions (Front View) GE Analytical Instruments ©2013 213 of 238 DLM 68100-05 EN Rev. A...

  • Page 214: Analyzer Dimensions (right Side View)

    Figure 81: Analyzer Dimensions (Right Side View) GE Analytical Instruments ©2013 214 of 238 DLM 68100-05 EN Rev. A...

  • Page 215: Analyzer Dimensions (left Side View)

    Figure 82: Analyzer Dimensions (Left Side View) GE Analytical Instruments ©2013 215 of 238 DLM 68100-05 EN Rev. A...

  • Page 216

    GE Analytical Instruments ©2013 216 of 238 DLM 68100-05 EN Rev. A...

  • Page 217: Appendix B: Acronyms And Definitions

    Range, or changes in Acid or Oxidizer percentages. The Blank Correction feature should be performed when reagents or dilution water are changed. GE Analytical Instruments ©2013 217 of 238 DLM 68100-05 EN Rev. A...

  • Page 218

    Check Standard carboy should be refilled. It also automatically skips analysis of sample streams when flow stops. Flush The Sievers InnovOx Online TOC Analyzer can perform two types of flushes: Sample Flushes and Dilution Water Flushes. These are defined below. Sample Flush Sample Flushes should be performed only when there is a very large concentration difference between one sample and the next.

  • Page 219

    Analyzer, including the calibration that is used. Protocols can be named and saved in the Analyzer’s memory for later use. Protocol Date Date that the protocol was created and saved on the Analyzer. Protocol Name Name used to identify a saved protocol. GE Analytical Instruments ©2013 219 of 238 DLM 68100-05 EN Rev. A...

  • Page 220

    100 ppm if the 1,000 ppm range is selected. Reagent Water Reagent-grade water, having a TOC concentration less than 0.1 ppm. Sievers Reagent Water is available in 40 mL vials with a concentration of less than 0.05 ppm from GE Analytical Instruments. Rejects The number of initial measurements for a sample in the Grab, Check Standard, Calibration, or Verification mode that will be omitted from the Analyzer’s calculations.

  • Page 221: Appendix C: Transferring Data To A Pc

    Then, in the Host Address field, enter the IP address of your Analyzer. The IP address appears on the System Info screen (Menu  Maintenance  System Info). GE Analytical Instruments ©2013 221 of 238 DLM 68100-06 EN Rev. A...

  • Page 222: Figure 84 Entering Connection Information

    To save the data from the Analyzer, select Transfer  Capture Text... (see Figure 85). When prompted, specify the file name and location for saving the data file (see Figure 86). Press Start to start saving the data. GE Analytical Instruments ©2013 222 of 238 DLM 68100-06 EN Rev. A...

  • Page 223: Figure 85 Saving Data On Hyperterminal

    12. Exit out of HyperTerminal. You will be prompted to save the connection information. Saving the information makes it easier to connect to the Analyzer the next time you want to capture data. GE Analytical Instruments ©2013 223 of 238...

  • Page 224: Importing Data Into A Spreadsheet Program

    “Text Import Wizard” to help you create a spreadsheet from the data in the file. If the “Text Import Wizard” dialog box appears (see Figure 87), make sure Delimited is selected and click the Next button. GE Analytical Instruments ©2013 224 of 238 DLM 68100-06 EN Rev. A...

  • Page 225: Figure 87 Microsoft Excel Spreadsheet Screen — Text Import Wizard - Step 1

    Make sure the Comma check box is selected, to identify the file as being comma-delimited (see Figure 88). Figure 88: Microsoft Excel Spreadsheet Program — Text Import Wizard - Step 2 GE Analytical Instruments ©2013 225 of 238 DLM 68100-06 EN Rev. A...

  • Page 226: Figure 89 Microsoft Excel Spreadsheet Program — Text Import Wizard - Step 3

    Figure 89: Microsoft Excel Spreadsheet Program — Text Import Wizard - Step 3 A new spreadsheet containing you exported data opens. You can now modify the document as you would modify any other Microsoft Excel spreadsheet program file. GE Analytical Instruments ©2013 226 of 238 DLM 68100-06 EN Rev. A...

  • Page 227: Appendix D: Modbus Map

    2004 Stream 3 Enabled 2005 Stream 4 Enabled 2006 Stream 5 Enabled 2007 Reject Measurement 2008 2000 See Footnote 3 Coils (write) Stop 2001 Check Standard Enabled 2002 GE Analytical Instruments ©2013 227 of 238 DLM 68100-06 EN Rev. A...

  • Page 228

    3201 16 bit unsigned Error Time - Month 3202 16 bit unsigned Error Time - Day 3203 16 bit unsigned Error Time - Hour 3204 16 bit unsigned GE Analytical Instruments ©2013 228 of 238 DLM 68100-06 EN Rev. A...

  • Page 229

    Supply 1 to Start Check Standard analysis at address 2008. Supply 1 to Stop Check Standard analysis at address 2009. Refer to “Analyzer Warnings and Error Messages” on page 174. GE Analytical Instruments ©2013 229 of 238 DLM 68100-06 EN Rev. A...

  • Page 230

    TOC, TC, IC, and NPOC units are: Units Value Stream Value Stream 1 Stream 2 Stream 3 Stream 4 Stream 5 Vial Port Check Standard Value NPOC GE Analytical Instruments ©2013 230 of 238 DLM 68100-06 EN Rev. A...

  • Page 231

    Current Mode Value Continuous Grab Autosampler Blank Calibration Verification IC Calibration Mock Online Check Standard Rinse Instrument Model Value Laboratory Online GE Analytical Instruments ©2013 231 of 238 DLM 68100-06 EN Rev. A...

  • Page 232

    GE Analytical Instruments ©2013 232 of 238 DLM 68100-06 EN Rev. A...

  • Page 233: Index

    117 dimensions, Analyzer 213 bromide 61 Display Option 146 drain 50 draining the Analyzer 145 calc run time 114 dynamic TOC range 49 calibration 89 calibration groups 98 GE Analytical Instruments ©2013 233 of 238 DLM 68100-06 EN Rev. A...

  • Page 234

    195 mounting installation 66 gas-liquid separator 73 mounting stand 67 gas-liquid separator, cleaning 157 multiple streams 112 GE InnovOx Filter Panel 149 multi-point calibration 95 Grab measurements 123 Grab mode 110 Grab Sample system 84 name of Analyzer 143...

  • Page 235

    136 shut down 147 signal air tube 150 single-point calibration 91 wall mount installation 71 soda ash 72 warnings and errors 173 sodium carbonate 61 waste 66 GE Analytical Instruments ©2013 235 of 238 DLM 68100-06 EN Rev. A...

  • Page 236

    Index waste neutralization 72 water tubes 154 weight 50 wet chemical analyzers 62 Windows Vista 139 Windows XP 139 GE Analytical Instruments ©2013 236 of 238 DLM 68100-06 EN Rev. A...

  • Page 237

    Notes GE Analytical Instruments ©2013 237 of 238 DLM 68100-06 EN Rev. A...

  • Page 238

    Notes GE Analytical Instruments ©2013 238 of 238 DLM 68100-06 EN Rev. A...

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