Opel 1900 1973 Service Manual page 539

refrigerant penetrates to every nook and cranny of
the unit.
Among the many desirable properties of R-12, is its
stability under operating conditions. However, while
more stable than the other refrigerants under the
same conditions, it, too, can be caused to form harm-
ful acids which will eventually fail the system.
O i l
Oil is the most complex of all of the organic chemi-
cals. Its stability in a refrigerating system is depend-
ent upon the source of crude oil and its method of
refining. A good refrigerating oil must be free of
sludge and gum-forming substances and free of
harmful impurities, such as sulphur. It must also be
stabilized to resist oxidation and must have a high
degree of resistance to carbonization.
The chemical properties of the lubricating oil form
another very important consideration in the chemi-
cal stability within the system. Like the refrigerant,
it travels to every nook and cranny of the unit.
The factory obtains the finest oils which have been
refined from the most desirable crudes.
essed at the factory before it is charged into a system
or poured into a container for resale. Its voscosity
and flash point are checked and it is forced through
many sheets of filtering paper.
Even the containers in which it is poured for resale
are processed. As you recive it for field service it is
the cleanest, dry&, and purest oil that is humanly
possible to make. Leaving the container uncapped
even for a few minutes allows the oil to absorb mois-
ture from the air. Many system failures have been
caused by chemical reactions which were started by
servicemen adding contaminated oil.
Desiccants (Dehydrating Agent)
Over the years the industry has spent hundreds of
thousands of dollars in finding and developing
chemical substances which are suitable for use in
refrigerating systems. An ideal desiccant must have
the following characteristics:
I. High capacity.
2. High eficiency.
3. Low tendency to powder.
4. Absorb moisture without reacting chemically with
it.
5. Allow refrigerant to flow through it with mini-
mum restriction.
6. Retain moisture at high temperature.
This has been a difficult combination to find. While
some desiccants excel in several of the desirable char-
acteristics, they are unsatisfactor:y in others.
Activated Silica Alumina, used in current receiver-
dehydrators, is a most satisfactory desiccant. How-
ever, its ability to retain moisture is affected by its
temperature. As the temperature increases, its ability
decreases. This means that moisture which is re-
tained at a lower temperature may be put back into
the system at a higher temperature.
MAINTAINING CHEMICAL STABILITY IN THE
REFRIGERATION
The metal internal parts of the refrigeration system
and the refrigerant and oil contained in the system
are designed to remain in a state of chemical stability
as long as pure R-12 plus refrigeration oil is used in
the system. However, when abnormal amounts of
foreign materials, such as dirt, air or moisture are
allowed to enter the system, the chemical stability
may be upset (Fig. 9B-24).
It is reproc-
When accelerated by heat, these contaminants may
form acids and sludge and eventually cause the
breakdown of components within the system. In ad-
dition, contaminants may affect the temperature
pressure relationship of R-12, resulting in improper
operating temperature and pressures and decreased
efficiency OF the system.
The following general practices
to maintain chemical stability in the system:
Whenever it becomes necessary to disconnect a re-
frigerant or gauge line, it should be immediately
capped. Capping the tubing will also prevent dirt and
foreign matter from entering.
Tools should be kept clean and dry. This also in-
cludes the gauge set and replacement parts.
SYSTEM
Figure System Contaminants
should
be observed