Waters 2998 Operator's Manual page 104

Photodiode array detector
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Solvent miscibility (Continued)
Polarity
Solvent
Index
2.2
Isopropyl ether
2.3
Toluene
2.4
P-xylene
3.0
Benzene
3.3
Benzyl ether
3.4
Methylene chloride
3.7
Ethylene chloride
3.9
Butyl alcohol
3.9
Butanol
4.2
Tetrahydrofuran
4.3
Ethyl acetate
4.3
1-propanol
4.3
2-propanol
4.4
Methyl acetate
4.5
Methyl ethyl ketone 0.43
4.5
Cyclohexanone
4.5
Nitrobenzene
4.6
Benzonitrile
4.8
Dioxane
5.2
Ethanol
5.3
Pyridine
5.3
Nitroethane
5.4
Acetone
5.5
Benzyl alcohol
5.7
Methoxyethanol
6.2
Acetonitrile
6.2
Acetic acid
6.4
Dimethylformamide 0.90
C-4
Solvent Considerations
Boiling
Viscosity
Point °C
CP, 20 °C
(1 atm)
0.33
68.3
0.59
100.6
0.70
138.0
0.65
80.1
5.33
288.3
0.44
39.8
0.79
83.5
3.00
117.7
3.01
177.7
0.55
66.0
0.47
77.1
2.30
97.2
2.35
117.7
0.45
56.3
80.0
2.24
155.7
2.03
210.8
1.22
191.1
1.54
101.3
1.20
78.3
0.94
115.3
0.68
114.0
0.32
56.3
5.80
205.5
1.72
124.6
0.37
81.6
1.26
117.9
153.0
Miscibility
λ Cutoff
Number
(nm)
(M)
––
220
23
285
24
290
21
280
––
––
20
245
20
––
––-
––
15
––
17
220
19
260
15
210
15
––-
15, 17
260
17
330
28
210
14, 20
––
15, 19
––
17
220
14
210
16
305
––
––
15, 17
330
13
––
13
––
11, 17
190
14
––
12
––

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