Shimadzu IRAffinity-1 Instruction Manual
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Shimadzu IRAffinity-1 Instruction Manual

Infrared spectrophotometer
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SHIMADZU FOURIER TRANSFORM
INFRARED SPECTROPHOTOMETER
Read the instruction manual thoroughly before you use the product.
Keep this instruction manual for future reference.
INSTRUCTION MANUAL
USER SYSTEM GUIDE
IRAffinity-1
206-97090B
Jan. 2009

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Summary of Contents for Shimadzu IRAffinity-1

  • Page 1 206-97090B Jan. 2009 INSTRUCTION MANUAL USER SYSTEM GUIDE IRAffinity-1 SHIMADZU FOURIER TRANSFORM INFRARED SPECTROPHOTOMETER Read the instruction manual thoroughly before you use the product. Keep this instruction manual for future reference.
  • Page 2 This page is intentionally left blank.
  • Page 3 (after the product is moved). COPYRIGHT AND TRADEMARK • © 2007-2009 Shimadzu Corporation. All rights reserved. This publication may not be reproduced in whole or in part without written permission from Shimadzu Corporation. Since Shimadzu products are frequently upgraded and improved, information in this publication is subject to change without notice. Any errors or omissions which may have occurred in this publication will be corrected as soon as possible.
  • Page 4 An electrical file (pdf) of the Validation program manual is stored in the IRsolution Installation CD. The IRAffinity-1 Instruction Manual: User System Guide primarily describes the IRAffinity-1 hardware, including its unit description, installation and maintenance. Refer to the Instruction Manual: Operation Guide for operation procedures such as data acquisition and processing, and to the "Help"...

  • Page 5: Safety Instructions

    • When organic solvents are used for FTIR applications, provide protective equipment near the instrument. If solvent gets into the eyes or on the skin, it must be flushed away immediately. Provide equipment, such as eye wash stations and safety showers, as close to the instrument as possible. IRAffinity-1...
  • Page 6 Installation Precautions WARNING • To ensure safe operation, contact your Shimadzu representative if product installation, adjustment, or re-installation (after the product is moved) is required. • Take measures to prevent the instrument from falling in the event of an earthquake or other disaster.
  • Page 7 • Do not use flammable sprays (hair sprays, insecticide sprays, etc.) near the instrument. They could ignite and cause a fire. CAUTION • Wipe the FTIR and/or inside of its sample compartment immediately, when they are wet by any liquid samples such as water, organic solvents, etc. The instrument could be damaged. IRAffinity-1...
  • Page 8 Use tubing with an inner diameter of at least 2 mm for a drain line with high flow rates. • Air bubbles in liquid can multiply the electro-static charge by a factor of 20, 30 or more. Periodically check the tubing connections for leaks. IRAffinity-1...
  • Page 9 • Ventilate the room by opening windows or using ventilation fans during purging or after purging. • Avoid purging in a sealed room. • For safety reasons, Shimadzu recommends the use of the oxygen indicator along with the product introduced in this manual. The following is the recommended portable oxygen indicator.
  • Page 10 In an Emergency WARNING Unplug the power cord of IRAffinity-1 instead of turning off the power switch on the front panel, if IRAffinity-1 must be completely turned off in case of rising smoke, etc. During a Power Outage NOTE When AC power cannot be supplied because of the periodic inspection of utilities etc., the Dry unit...

  • Page 11: Unit Warning Labels

    Unit Warning Labels For safety operation, warning labels are affixed to where special attention is required. Should any of these labels peel off or be damaged, obtain replacements from Shimadzu Corporation. WARNING RISK OF ELECTRIC SHOCK DO NOT remove cover. Contact your Shimadzu representative for service.
  • Page 12 NOTE When orange lamp is lighting, interferometer is kept in low humid. If this orange lamp is not lighting, refer to Instruction manual: User's System Guide - Troubleshooting immediately. Notice label (Part No. 206-73588) IRAffinity-1...
  • Page 13 U.S. FDA 21CFR Part 1040.10/1040.11 except for deviations pursuant to Laser Notice No.50 dated June 24, 2007. And the IRAffinity-1 uses a Class 2 helium neon laser with an output of 0.5 mW, maximum in it. When the IRAffinity-1 is on, the laser is emitted continuously. It has two purposes in the system: sampling signal generation and optical axis adjustment.

  • Page 14: Symbols Found On The Iraffinity-1

    Symbols Found on the IRAffinity-1 Symbol Definition Current (AC). IRAffinity-1...

  • Page 15: Warranty And After-Sales Service

    After-Sales Service If any problem occurs with this instrument, inspect it and take appropriate corrective action as described in this manual. If the problem persists, or symptoms not covered in this manual occur, contact your Shimadzu representative. Replacement Parts Availability Replacement parts for this instrument will be available for a period of seven (7) years after the discontinuation of the product.

  • Page 16: Software License Agreement

    Software License Agreement PLEASE READ THIS AGREEMENT CAREFULLY BEFORE USING THE SOFTWARE. SHIMADZU Corporation ("SMZ") is willing to license the SMZ software provided herein, together with accompanying documentation (collectively "SOFTWARE") to you only upon the condition that you accept all of the terms and condition contained in this License Agreement. By using the SOFTWARE, you agree to be bound by the terms of this Agreement.
  • Page 17 The exclusive jurisdiction for any disputes arising out of or in connection with this Agreement shall be Kyoto District Court of Japan. d. The invalidity or unenforceability of any provision of this Agreement shall not affect the validity or enforceability of any other provision. IRAffinity-1...

  • Page 18: Regulatory Information

    Product Name Fourier Transform Infrared Spectrophotometer Model Name IRAffinity-1 Manufacturer SHIMADZU CORPORATION ANALYTICAL & MEASURING INSTRUMENTS DIVISION Address 1 NISHINOKYO-KUWABARA CHO NAKAGYO-KU KYOTO 604-8511 JAPAN Authorized Shimadzu Europa GmbH Representative in EU Address Albert-Hahn-Strasse 6-10, 47269 Duisburg, F.R. Germany IRAffinity-1...

  • Page 19: Action For Environment (Weee)

    WEEE Mark With your co-operation we are aiming to reduce contamination from waste electronic and electrical equipment and preserve natural resource through re-use and recycling. Do not hesitate to ask Shimadzu service representative, if you require further information. IRAffinity-1 xvii...

  • Page 20: Table Of Contents

    3.2 Installation Environment for Equipment ................. 3-3 3.3 Wiring the Cables........................3-5 3.4 Installing the Software......................3-6 3.4.1 Installation of the Driver Program for the IRAffinity-1..........3-6 3.4.2 Installation of IRsolution ..................... 3-7 3.4.3 Installation of Supplemental Disk ................3-12 3.4.4...
  • Page 21 Dry Indicator Check ..................5-6 5.1.2.2 Silica Gel Check..................5-6 5.2 When Not Using IRAffinity-1 for a Long Term (Over a Month) ..........5-7 5.3 For Brownout ......................... 5-8 5.4 Procedure to Replace Silica Gel .................... 5-9 5.5 Dry Indicator ........................5-10 5.6 Self Diagnostics ........................
  • Page 22 6.4 Confirming the Power Selector Switch and Fuse..............6-9 Chapter 7 Materials for Infrared Analysis 7.1 Materials for Infrared Analysis ....................7-2 7.2 Characteristics of Materials....................7-3 7.3 Optical Materials in IRAffinity-1....................7-5 7.4 Material Safety Data Sheet ....................7-6 7.4.1 KRS-5......................... 7-6 7.4.1.1 Thallium Bromide (TlBr) ................
  • Page 23 IRAffinity-1 CONTENTS 1.1 Principle and Construction......................1-2 1.2 Resolution and Apodization ......................1-5 1.3 The FTIR Advantage ........................1-7 1.4 System Configuration of IRAffinity-1....................1-8 1.5 Interferometer ..........................1-9 1.6 Electrical System ......................... 1-15 1.7 S/N Ratio ............................. 1-16 IRAffinity-1...

  • Page 24: Principles, Description, And Functions Of The Iraffinity-1

    The Fourier Transform InfraRed spectrophotometer measures an infrared spectrum by Fourier-transform of an interferogram. The Physics of Fourier Transform Spectrophotometry An FTIR uses one of several optical systems; the IRAffinity-1 relies on a Michelson interferometer (Fig. 1.1). After passing through the aperture, light is turned into a parallel beam by the collimator mirror and enters the beam splitter.
  • Page 25 The signal I(χ) observed by the detector is called an interferogram, and 4RT is labeled beam splitter efficiency. If polychromatic light is emitted instead of monochromatic light, I(χ) is given by the integration of 1.2 with respect to wavenumber. ∞ ∫ I χ ( ) B σ ( ) 2πσχ σ δ ........................(1.3) IRAffinity-1...
  • Page 26 Chapter 1 Principles, Description, and Functions of the IRAffinity-1 Equation 1.3 demonstrates that I(χ) is a Fourier cosine transform of spectrum B(σ). Thus, an inverse Fourier cosine transform of I(χ) recovers the original spectrum B(σ). +∞ ∫ B σ ( ) I χ...

  • Page 27: Resolution And Apodization

    (b) illustrates that the instrument function defined by 1.10 has worse separation, but smaller submaxima, than that defined by 1.8. Using A(χ) to reduce the instrument function submaxima called apodization; A(χ) is called the apodization function. (a) "Rectangular" function (b) "Triangular" function Fig. 1.3 Apodization with "Rectangular" and "Triangular" Functions IRAffinity-1...
  • Page 28 Chapter 1 Principles, Description, and Functions of the IRAffinity-1 Table 1.1 lists the IRAffinity-1 apodization parameters and their characteristics. Table 1.1 Apodization Function Half-width Submaxima Parameter Apodization Function Instrument Function value residue None, 0.605/L -21% A χ ( ) c 2πσL...

  • Page 29: The Ftir Advantage

    When a large aperture is used, more of the light source is available to maintain a high-throughput optical system, giving the spectrum a high S/N ratio. The wavenumber precision, or Cones, advantage is the result of the IRAffinity-1 He-Ne laser. The laser emits extremely stable monochromatic light, creating a spectrum with high wavenumber accuracy.

  • Page 30: System Configuration Of Iraffinity-1

    Chapter 1 Principles, Description, and Functions of the IRAffinity-1 System Configuration of IRAffinity-1 This section briefly describes the system configuration of the IRAffinity-1. The IRAffinity-1 consists of the interferometer and a personal computer. The USB 2.0 interface is used for communication between the interferometer and the personal computer.

  • Page 31: Interferometer

    ] side to turn on the power to the laser, light source and electronic boards. Unplug the power cord of IRAffinity-1 instead of turning off the power switch, if IRAffinity-1 must be completely turned off in case of rising smoke, etc.

  • Page 32: Inside Of Sample Compartment

    Chapter 1 Principles, Description, and Functions of the IRAffinity-1 Fig. 1.6 Appearance of Interferometer (Rear View) (1) AC inlet (with fuse holder) : Connect the power cable here. Two fuses are accommodated here. (2) Optional connector mounting holes : Connect the connector here to use an optional MCT detector such as infrared microscope.

  • Page 33: Optical System

    Wipe the FTIR and/or inside of its sample compartment immediately, when they are wet by any liquid samples such as water, organic solvents, etc. The instrument could be damaged. 1.5.3 Optical System The figure below shows the optical system of the IRAffinity-1. (16) (18) (17) (19)

  • Page 34: Light Source

    (3) position. The beam which has passed through the aperture is reflected by the collimator (4), made into parallel beam, then introduced into the interferometer (5). The IRAffinity-1 has the Michelson interferometer whose incident angle is 30 degrees.

  • Page 35: Beam Splitter

    To cope with this, moisture resistant coating is applied on these beam splitters used in the IRAffinity-1, and the dry unit is built in the main unit. Usually, no problem is expected while the IRAffinity-1 is operating. Refer to Chapter 5 "Maintenance and Inspection"...
  • Page 36 ® Fig. 1.9 Principle of ROSAHL The dry unit is located the inside of the cover on the back side of IRAffinity-1. The following attentions should be paid when use. • Please avoid using this product in poor ventilation space.

  • Page 37: Electrical System

    USB 2.0 interface to the PC where IRsolution transforms the interferogram into a spectrum. Interferometer unit HIGH Sample GAIN Interferogram Spectrum DETECTOR PASS PASS and Hold Converter cable GAIN setting signal He-Ne laser fringe signal Fig. 1.10 Signal Processing System in the IRAffinity-1 IRAffinity-1 1-15...

  • Page 38: S/N Ratio

    ), the noise in the unaffected range near 2200 cm is used (2250 - 2050 cm The S/N ratio is therefore measured and calculated by the following method with IRAffinity-1 series. 1. BKG scan and Sample scan is sequentially measured at 4 cm resolution, and 2.8 mm/s mirror speed...
  • Page 39 Chapter 2 Specifications CONTENTS 2.1 IRAffinity-1 Specifications ......................2-2 IRAffinity-1...

  • Page 40: Chapter 2 Specifications

    NOTE 1. Resolution and wavenumber accuracy of the FTIR are determined by the wavenumber interval of −1 spectral data. Since the maximum data interval of IRAffinity-1 is 0.25 cm , the peak position can be −1 read at an accuracy of ±0.125 cm .

  • Page 41: Software

    2.1 IRAffinity-1 Specifications 2.1.2 Software Windows XP Professional SP2 , Windows Vista Business Interface USB2.0 compatible Monitor of hardware Self-diagnosis function, Status monitor Validation program based on Japanese Pharmacopoeia/European Pharmacopoeia/ASTM Measurement Spectrum scanning, Continuous scanning, Atmosphere correction scanning, Automatic scanning with Auto-sampler, Easy scanning, Evaluation scanning Data processing Addition, Subtraction, Multiplication, Division, %T ↔...

  • Page 42: Other

    Installation site Must be controlled with an Air conditioner Humidity : 70% or less, No dewing condensation Utility AC 100/120/220/230/240 V, 50/60 Hz, 150 VA (at used), 4 VA (at standby) * Power for the computer is required separately. IRAffinity-1...
  • Page 43 3.2 Installation Environment for Equipment ..................3-3 3.3 Wiring the Cables .......................... 3-5 3.4 Installing the Software ........................3-6 3.5 User Management ........................3-14 3.6 Uninstallation of the IRsolution ....................3-15 3.7 Trial Run ............................3-16 3.8 Electromagnetic Compatibility ..................... 3-17 IRAffinity-1...

  • Page 44: Chapter 3 Installation

    NOTE If the cold IRAffinity-1 is brought into a warm room, leave the IRAffinity-1 for approximately 2 hours to prevent dew condensation in the interferometer, then unpack the interferometer (especially in winter).

  • Page 45: Installation Environment For Equipment

    1 instead of turning off the main switch on the front panel, if IRAffinity-1 must be completely turned off in case of rising smoke, etc. 10. Make sure to install it in a room equipped with a ventilation device to use the IRAffinity-1 after purge with gas. Usually, use N gas for industrial use (whose purity is 99.99%) though the requirement of the purity...
  • Page 46 • Ventilate the room by opening windows or using ventilation fans during purging or after purging. • Avoid purging in a sealed room. • For safety reasons, Shimadzu recommends the use of the oxygen indicator along with the product introduced in this manual. The following is the recommended portable oxygen indicator.

  • Page 47: Wiring The Cables

    NOTE The dry unit is built in the IRAffinity-1. This dry unit is driven to keep the humidity in the interferometer while the equipment being stopped. Connect the AC cable even if the equipment is not used. Do not turn off the power supply.

  • Page 48: Installing The Software

    Chapter 3 Installation Installing the Software When your computer controls the IRAffinity-1, an instrument driver program must be installed. When the PC is used for data manipulation and/or printing, and not for FTIR control, installation of instrument driver is not needed.

  • Page 49: Installation Of Irsolution

    • The English version of IRsolution install program is activated on another version of Windows other than Japanese. 4. [Preparing Setup] dialog box and then [Welcome to the InstallShield Wizard for IRsolution] dialog box are displayed. Click the [Next] button. Fig. 3.3 [Welcome] Dialog Box IRAffinity-1...
  • Page 50 9. Input the CD Key written on the CD-ROM package into the [Serial Number CD Key]. If the input CD Key is not correct, you cannot proceed to the next step. After inputting the information, click the [OK] button. IRAffinity-1...
  • Page 51 Fig. 3.6 [Chose Destination Location] Dialog Box 11. Click the [Next] button to proceed to the next step, then the [Backup Replaced Files] dialog box opens. Click the [Next] button with the default setting. Fig. 3.7 [Backup Replaced Files] Dialog Box IRAffinity-1...
  • Page 52 DataExtractor support Is checked, when used with the CLASS-Agent/IRsolution Agent. Support for Sadtler Installs the hardlock driver to use Sadtler libraries. hardlock Fig. 3.8 [Select Components] Dialog Box 13. Check the necessary components. Click the [Next] button after setting. IRAffinity-1 3-10...
  • Page 53 18. When a check mark is on the "View Readme", the Readme file is opened. 19. Install the Supplemental Disk in the next step. The latest information for IRsolution software is described in "ReadmeE.htm" in both the Installation CD-ROM and Supplemental Disk. Please refer to both of them before using IRsolution software. IRAffinity-1 3-11...

  • Page 54: Installation Of Supplemental Disk

    As it may not be possible to create folders or files, if they are created at the location other than "C:\Program Files\Shimadzu\IRsolution\data" and its sub folders, it is necessary to modify folder securities using the tools provided by Windows.

  • Page 55: Selecting An Instrument

    [IRsolution] menu on the [Start] menu. 2. Set up the model of instrument to connect with the IRsolution. Select the [Environment]- [Instrument Preferences]-[Instruments] menu before initializing the FTIR. Select [IRAffinity-1] as the Scanning FTIR Module. Fig. 3.11 [Instrument Preferences] Dialog Box FTIR 8000 series Connects to the FTIR-8000 series.

  • Page 56: User Management

    IRsolution is run again. Select "Administrator" as "User name" and nothing is input on the "Password" section, then click the [OK] button. Fig. 3.13 [Login] Dialog Box Change the "password" for the "Administrator" by the [Admin]-[Security] command. Then manage the User and his/her rights of operations. IRAffinity-1 3-14...

  • Page 57: Uninstallation Of The Irsolution

    Fig. 3.15 Select Uninstall Method 6. Finally, select [IRsolution] then click the [Modify / Remove] button. Select [Remove] on the window then follow the prompts on the screen. 7. After uninstallation, close the [Add / Remove Programs] window and the [Control Panel]. IRAffinity-1 3-15...

  • Page 58: Trial Run

    After completing the installation work described so far, start up the IRAffinity-1 in conformance to Chapter 1 of the Instruction Manual (Operation Guide). Execute [Auto Adjust] from the IRsolution window, measure the...

  • Page 59: Electromagnetic Compatibility

    A greater interference than specified may cause instrument malfunction. To avoid electromagnetic disturbance, follow these two recommended precautions: 1. Before handling the instrument, discharge any electrostatic charge to a grounded object. 2. Do not install the FTIR near strong electromagnetic fields. IRAffinity-1 3-17...
  • Page 60 Chapter 3 Installation This page is intentionally left blank. IRAffinity-1 3-18...
  • Page 61 Chapter 4 Operations This section describes the outline of IRAffinity-1 operation. Because actual scanning of samples or data manipulation are done by IRsolution software, refer to Instruction manual - Operation guide for detail operation. CONTENTS 4.1 Activation and Shutdown of IRAffinity-1 and PC................4-2 4.2 Initialization of IRAffinity-1 and Self Diagnostics................

  • Page 62: Chapter 4 Operations

    4. Verify that there is no remaining disk activity by checking the access indicator on the front panel of the PC, and turn off the PC. 5. Turn off the power switch at the front right side of the IRAffinity-1. The power indicator (green) should turn off.

  • Page 63: Initialization Of Iraffinity-1 And Self Diagnostics

    Initialize the IRAffinity-1 by IRsolution software. 1. Confirm that there is nothing interrupting the IR beam in the compartment of the IRAffinity-1. If there is a sample or an accessory which interrupts the IR beam, "Infrared power spectrum shape" and another tests in Self diagnostics fails.

  • Page 64: Scan Parameters

    To cope with this, execute background measurement by using the same option (without sample) used in sample measurement. Use 3.0, 2.1 or 1.5 as Aperture to scan background and sample spectra. IRAffinity-1...

  • Page 65: Measurement Modes

    4.4 Measurement Modes Measurement Modes IRAffinity-1 has the following measurement modes and they can be selected according to your applications. Scan mode Description Spectrum Scan Typical scanning mode. Background spectrum and sample spectrum are scanned separately using [BKG] and [Sample] buttons.

  • Page 66: Setting For Accessory Recognition

    When an accessory with an Automatic Recognition Function is installed in the sample compartment, IRAffinity-1 can automatically recognize the type of the accessory, and then load a suitable scan parameter or execute the method (macro program) (as far as the accessory has the recognition function).
  • Page 67 6. After this setting, when an accessory with an Automatic Recognition Function is installed, the following dialog box is displayed. Fig. 4.6 QuickStart Accessories (Recognized) 7. Clicking [OK] button sets the specified scan parameter or executed the specified macro program. IRAffinity-1...

  • Page 68: Auto Sampler

    5. Turn on the PC, and then activate the IRsolution software. 6. Select [Measurement]-[Initialize]. NOTE Energy (power spectrum) check is performed during initialization of IRAffinity-1. When an accessory interrupts IR beam, the check may be faulty. 7. Select [Measurement]-[Auto Sampler]. The [Sampler] dialog box is displayed.

  • Page 69: Measurement

    7. When you want to execute Kubelka-Munk conversion of the obtained spectra automatically, put a check mark on "Kubelka-Munk" and input a name. 8. Then, click the [Start Scan] button. 9. Automatic scan starts and obtained spectra are displayed on the IRsolution screen. IRAffinity-1...

  • Page 70: The Way To Move Sample Position

    Input the sample position number at the [Control] part, and then click the [Move to] button. • If input number exceeds the "Maximum" of the ASC setting, an Error message is displayed. Current Position Position movement control Fig. 4.9 [Sampler] Dialog Box IRAffinity-1 4-10...

  • Page 71: Precautions For Using Accessories

    BKG and sample with smaller aperture setting such as 3.0, 2.1 and 1.5. CAUTION Wipe the FTIR and/or inside of its sample compartment immediately, when they are wet by any liquid samples such as water, organic solvents, etc. The instrument could be damaged. IRAffinity-1 4-11...

  • Page 72: In Case Of Emergency

    Chapter 4 Operations In Case of Emergency Unplug the power cord of IRAffinity-1 instead of turning off the power switch on the front panel, if IRAffinity-1 must be completely turned off in case of rising smoke, etc. IRAffinity-1 4-12...
  • Page 73 Inspection CONTENTS 5.1 Start-Up Inspection and Periodic Inspection.................. 5-2 5.2 When Not Using IRAffinity-1 for a Long Term (Over a Month) ............5-7 5.3 For Brownout ..........................5-8 5.4 Procedure to Replace Silica Gel....................5-9 5.5 Dry Indicator ..........................5-10 5.6 Self Diagnostics ...........................

  • Page 74: Maintenance And Inspection 5.1 Start-Up Inspection And Periodic Inspection

    KBr beam splitter deliquesces and performance of the FTIR becomes low. In worst case, FTIR does not work. In such case, a SHIMADZU service engineer must replace the beam splitter and align the FTIR condition. Repairing costs are high.

  • Page 75: 5.1.1.2 Silica Gel Check

    Put the top cover on the FTIR after checking. NOTE IRAffinity-1 includes a Dry unit to desiccate in the interferometer. It also includes Silica gel to provide for cutting AC power supply. Because the humidity inside of the interferometer is usually lower than 20% RH and Silica gel stops moisture absorption, replacement of Silica gel is not needed while the dry unit is working.

  • Page 76: 5.1.1.3 Power Spectrum Check

    In [Data] tab: "Measuring mode": "Power" −1 "Resolution": "2 cm " −1 "Range": "4700-340 cm " "N scans": "45" scans "Apodization": "HAPP-GENZEL" "Detector": "standard" "Beam": "internal" In [More] tab: "Detector speed": "2.8 mm/sec" IRAffinity-1...
  • Page 77 [Auto adjustment] on the [Instrument] Menu, and reanalyze the spectrum. If the power spectrum does not improve after the "auto adjustment", the system may be damaged; contact your SHIMADZU representative. If the intensity remains zero, the light source may be disconnected or damaged; light source replacement or repair should be performed by a SHIMADZU service engineer.

  • Page 78: 5.1.1.4 Validation Program

    Validation program for ASTM The IRAffinity-1 can automatically execute the inspection in conformance to the ASTM E1421-94 ("Level Zero"). Use a polystyrene film in conformance to the Japanese Pharmacopoeia with thickness of approximately 40 μm. When traceability is required in the inspection result, separately purchase the standard sample supplied by NIST or its secondary standard, and use it in the inspection.

  • Page 79: When Not Using Iraffinity-1 For A Long Term (Over A Month)

    When Not Using IRAffinity-1 for a Long Term (Over a Month) Even if the IRAffinity-1 is not used for long term, AC power must still be supplied. The Dry unit works, desiccating the inside of the interferometer and protecting the optical elements against humidity.

  • Page 80: For Brownout

    Chapter 5 Maintenance and Inspection For Brownout When AC power cannot be supplied because of periodic inspection of utilities etc., the Dry unit does not desiccate. Replace Silica gel packages in the FTIR once a week during brownout. IRAffinity-1...

  • Page 81: Procedure To Replace Silica Gel

    5. Insert the tip of the Top cover into the hole ((4) in Fig. 5.6), and then put it on the FTIR after replacement. Lift up to remove the Top cover. Fig. 5.5 Remove the Top Cover Fig. 5.6 Silica Gel Case IRAffinity-1...

  • Page 82: Dry Indicator

    IRAffinity-1 is not used. Accordingly, always let the power plug of the IRAffinity-1 be connected to the AC power supply to keep the power supply. Confirm that the orange Dry indicator is lit.

  • Page 83: Self Diagnostics

    Self Diagnostics The IRAffinity-1 has a self-diagnosis function. The IRAffinity-1 automatically checks its own status during operation or startup. When all items are judged OK, the IRAffinity-1 can be used normally. The contents of the self-diagnosis are described below. Items checked when the IRAffinity-1 starts up or when [Measurement]-[Diagnostics] is executed: 1.

  • Page 84: Describing The Diagnostic Screen

    If the "Humidity level inside of the interferometer" failed, the humidity in the interferometer has become too high and the optical elements may be damaged. 1. Disconnect the power cord immediately and do not use your IRAffinity-1. 2. Remove the Top cover and replace silica gel packages.
  • Page 85 If the "Humidity level inside of the interferometer" failed, the humidity in the interferometer has become too high and the optical elements may be damaged. 1. Disconnect the power cord immediately and do not use your IRAffinity-1. 2. Remove the Top cover and replace silica gel packages.

  • Page 86: Status Monitor

    1. Disconnect the power cord immediately and do not use your IRAffinity-1. 2. Remove the Top cover and replace silica gel packages. 3. Please contact your SHIMADZU representative. Indicates presence and setting of the Beam switching kit. None The beam switching kit is not installed.
  • Page 87 Green Auto-sampler was initialized and is ready to be used. Accessory Indicates presence and information of the installed accessory. None Accessory is not installed. Green Accessory is installed and ready to be used. Its serial number is shown. IRAffinity-1 5-15...

  • Page 88: Cleaning The System

    Do not use organic solvents, such as thinner or benzene, and avoid contact with mirrors and other internal components. NOTE Do not spill water or solvents on the system; spills may result in system damage, fire or electric shock. IRAffinity-1 5-16...

  • Page 89: Transporting The System

    5.8 Transporting the System Transporting the System WARNING To ensure safe operation, contact your SHIMADZU representative for installation, adjustment, or re-installation after moving the instrument to a different site. IRAffinity-1 5-17...

  • Page 90: Maintenance Parts And Consumable Parts

    • He-Ne laser assy is a consumable part. Replacement may be required every year. This however depends on condition. • Dry unit assy is a consumable part. Replacement may be required periodically year. This however depends on condition. IRAffinity-1 5-18...
  • Page 91 Chapter 6 Troubleshooting CONTENTS 6.1 Error Message Table ........................6-2 6.2 Error Message Shown in the "Status Window"................6-3 6.3 What's Happening? ........................6-6 6.4 Confirming the Power Selector Switch and Fuse ................6-9 IRAffinity-1...

  • Page 92: Chapter 6 Troubleshooting

    Please choose a different file name! Change file name and save again. XXX to XXXX wavenumber should Wavenumber range value in measurement parameter is out of the be inputted. range which is set to the beam splitter used. Input correct value. IRAffinity-1...

  • Page 93: Error Message Shown In The "Status Window

    This table shows error message meanings and how to operate. Please read the message and refer to operate. If no improvement is obtained in spite of this operation, your instrument may be damaged. Please contact Shimadzu branch. Error Message Meanings and Operation...
  • Page 94 System fails initialization of ASC motor. Check the connection of ASC cable. Failure in initializing of Beam setting motor System fails initialization of Beam switching motor. Please contact your SHIMADZU representative. Lamp offline Light source inoperative. Please contact your SHIMADZU representative. IRAffinity-1...
  • Page 95 The light at the detector was too weak. There are more error messages, but in normal use they seldom appear. If undefined errors in the table above frequently occur, the instrument may have a software or hardware problem. Please contact the Shimadzu branch.

  • Page 96: What's Happening

    What's Happening? This section lists troubles that you may have during the operating of the IRAffinity-1 and describes their reasons and solutions. Refer to Chapter 5 and 6 to solve these troubles. If the trouble cannot be solved, please contact your SHIMADZU representative.

  • Page 97: A Part Of The Mirror Is A Little White

    Please prevent the entry of organic halide vapors into the interferometer by installing a local ventilation system at the FTIR sample compartment, or purging the interferometer with dried air or N gas, when you run samples that include volatile organic halide compounds. IRAffinity-1...

  • Page 98: Power Spectrum Becomes Too Small, Or Fluctuates

    6.3.4 Power Spectrum Becomes too Small, or Fluctuates. Phenomena 1. Power spectrum becomes smaller than ones when IRAffinity-1 was installed. 2. Power spectrum becomes small in short term (a day to a week). Power spectrum fluctuates. Reason 1. Deterioration because of long term use 2.

  • Page 99: Confirming The Power Selector Switch And Fuse

    Confirming the Power Selector Switch and Fuse 1. The setting of the input power for the interferometer unit of IRAffinity-1 is normally adjusted to the supply voltage in the area where the equipment is used. By using the voltage selector switch and by changing the fuse and AC cable of the AC inlet, the voltage of 100 V, 120 V, 220 V, or 230 V AC can be used.
  • Page 100 Chapter 6 Troubleshooting 5. Close the lid of the AC inlet. Place the interferometer so that the front face is placed toward you after the works above are completed. Fig. 6.1 (e) IRAffinity-1 6-10...
  • Page 101 Chapter 7 Materials for Infrared Analysis CONTENTS 7.1 Materials for Infrared Analysis ....................... 7-2 7.2 Characteristics of Materials ......................7-3 7.3 Optical Materials in IRAffinity-1...................... 7-5 7.4 Material Safety Data Sheet......................7-6 IRAffinity-1...

  • Page 102: Chapter 7 Materials For Infrared Analysis

    Chapter 7 Materials for Infrared Analysis Materials for Infrared Analysis Listed materials are used in IRAffinity-1 and their accessories. Used materials are depended on the equipment. They are usually used as windows or ATR prisms. Selection of materials are based on wavenumber range and physical/chemical characteristics of samples.

  • Page 103: Characteristics Of Materials

    EDTA a solution of a compound that reacts with thallium to form complex Insoluble in water. acetone acidic solution Zinc sulfide Resistant against mechanical and thermal alcohol shocks. High refractive index. Effectively used for evaporation depositing. IRAffinity-1...
  • Page 104 Recommended for the window of high- pressure cell. (Fused Silica) Effective for analysis in the UV and visible ethanol regions. acetone Though useful up to 4 nm in the IR region, this is material ensures high stability and is easy to process. IRAffinity-1...

  • Page 105: Optical Materials In Iraffinity-1

    7.3 Optical Materials in IRAffinity-1 Optical Materials in IRAffinity-1 Fig. 7.1 shows optical materials in the IRAffinity-1. Beam splitter (Ge on KBr window) Compensator Window (KBr window) (KRS-5 window) Detector (KRS-5 windows) Fig. 7.1 Optical Materials in IRAffinity-1 IRAffinity-1...

  • Page 106: Material Safety Data Sheet

    Use fire fighting measures that suit the environment. Special hazards caused by the material, its products of combustion or flue gases: Can be released in case of fire: Toxic metal oxide smoke Hydrogen bromide (HBr) Protective equipment: Wear self-contained breathing apparatus. Wear full protective suit. IRAffinity-1...
  • Page 107 Protect from humidity and keep away from water. This product is hygroscopic. Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Store in a locked cabinet or with access restricted to technical experts or their assistants. IRAffinity-1...
  • Page 108 Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Store protective clothing separately. Breathing equipment: Use breathing protection with high concentrations. Eye protection: Safety glasses Body protection: Protective work clothing. IRAffinity-1...
  • Page 109 Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known. No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH. IRAffinity-1...
  • Page 110 (thallium (I) bromide) Maritime transport IMDG/GGVSea: IMDG/GGVSea Class: UN Number: 1707 Label Packaging group: Correct technical name: THALLIUM COMPOUNDS, N.O.S. Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: UN/ID Number: 1707 Label Packaging group: Correct technical name: THALLIUM COMPOUNDS, N.O.S. IRAffinity-1 7-10...
  • Page 111 This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user. IRAffinity-1 7-11...

  • Page 112: Thallium Iodide (Tli)

    Use fire fighting measures that suit the environment. Special hazards caused by the material, its products of combustion or flue gases: Can be released in case of fire: Toxic metal oxide smoke Hydrogen iodide (HI) Protective equipment: Wear self-contained breathing apparatus. Wear full protective suit. IRAffinity-1 7-12...
  • Page 113 Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Protect from the effects of light. Store in a locked cabinet or with access restricted to technical experts or their assistants. IRAffinity-1 7-13...
  • Page 114 Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Store protective clothing separately. Breathing equipment: Use breathing protection with high concentrations. Eye protection: Safety glasses Body protection: Protective work clothing. IRAffinity-1 7-14...
  • Page 115 Danger to drinking water if even extremely small quantities leak into soil. Also poisonous for fish and plankton in water bodies. Do not allow material to be released to the environment without proper governmental permits. Toxic for aquatic organisms IRAffinity-1 7-15...
  • Page 116 (thallium (I) bromide) Maritime transport IMDG/GGVSea: IMDG/GGVSea Class: UN Number: 1707 Label Packaging group: Correct technical name: THALLIUM COMPOUNDS, N.O.S. Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: UN/ID Number: 1707 Label Packaging group: Correct technical name: THALLIUM COMPOUNDS, N.O.S. IRAffinity-1 7-16...
  • Page 117 This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user. IRAffinity-1 7-17...

  • Page 118: Potassium Bromide (Kbr)

    Do not allow material to be released to the environment without proper governmental permits. Measures for cleaning/collecting: Collect mechanically. Additional information: See item for information on safe handling. See item for information on personal protection equipment. See item for information on disposal. IRAffinity-1 7-18...
  • Page 119 Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Breathing equipment: Not required. Protection of hands: Use breathing protection with high concentrations. Eye protection: Safety glasses Body protection: Protective work clothing. IRAffinity-1 7-19...
  • Page 120 Water hazard class 1 (Self-assessment): slightly hazardous information for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. Do not allow material to be released to the environment without proper governmental permits. IRAffinity-1 7-20...
  • Page 121 This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user. IRAffinity-1 7-21...

  • Page 122: Silica Gel (Desiccant)

    Measures for cleaning/collecting: Dispose of contaminated material as waste according to item Ensure adequate ventilation. Additional information: See item for information on safe handling. See item for information on personal protection equipment. See item for information on disposal. IRAffinity-1 7-22...
  • Page 123 Korea TLV Netherlands MAC-TGG 0.075 Norway TWA 0.3 (total dust) 0.1 (resp. dust) Russia 14-STEL Sweden NGV 0.1 (resp. dust) Switzerland MAK-W 0.15 United Kingdom TWA 0.3 (respirable) USA PEL 10/(% resp. SiO2+2) 30/(% SiO +2) (total dust) IRAffinity-1 7-23...
  • Page 124 ACGIH TLV 0.1 (respirable particulate) Finland TWA Germany TWA (respirable fraction of the aerosol) Ireland TWA 0.1 (respirable) United Kingdom TWA 0.3 (respirable dust) Silica, amorphous-fume mg/m ACGIH TLV 2 (respirable particulate) Germany TWA (respirable fraction of the aerosol) IRAffinity-1 7-24...
  • Page 125 Thermal decomposition / conditions to be avoided: reactivity No decomposition if used and stored according to specifications. Materials to be avoided: Interhalogens Halogens Oxidizing agents Dangerous reactions: Reacts violently with interhalogens. Dangerous products of decomposition: No dangerous decomposition products known IRAffinity-1 7-25...
  • Page 126 Disposal must be made according to official regulations. 14. Transport Land transport ADR/RID and GGVS/GGVE (cross-border/domestic) information ADR/RID-GGVS/E Class: None Maritime transport IMDG/GGVSea: ADR/RID-GGVS/E Class: None Air transport ICAO-TI and IATA-DGR: ADR/RID-GGVS/E Class: None Transport/Additional information: Not dangerous according to the above specifications. IRAffinity-1 7-26...
  • Page 127 This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user. IRAffinity-1 7-27...
  • Page 128 Chapter 7 Materials for Infrared Analysis This page is intentionally left blank. IRAffinity-1 7-28...
  • Page 129 Continuous Scan ..........4-5 interferogram ......1-2 1-12 interferometer ............ 1-12 IRsolution ............5-18 detector ........1-12 5-18 DLATGS detector ..........1-13 DRS-8010ASC ............ 4-8 Japanese Pharmacopoeia ........5-6 dry indicator ......1-9 1-13 5-10 dry unit ............. 1-13 5-18 DuraSamplIR IIA ..........4-11 IRAffinity-1...
  • Page 130 ........6-9 phase ..............1-3 Polystyrene ............5-18 power indicator .......... 1-9 5-10 Warning Labels ............ix Power spectrum ........... 5-2 wavenumber range ........... 1-13 power switch ........1-9 4-12 WEEE ..............xvii purge ............1-10 Weight ..............2-2 Window ............... 7-5 IRAffinity-1...
  • Page 131 ZnSe ............7-2 IRAffinity-1...
  • Page 132 This page is intentionally left blank. IRAffinity-1...
  • Page 133 Record of Revision Date Revision Changed Page Description 2009-01 Windows Vista Business was added on Specification. P/N of IRsolution and Supplemental Disk were changed. Note) A ...Added Page No. D ..Deleted Page No. IRPrestige-21...
  • Page 134 This page is intentionally left blank. IRPrestige-21...

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