Summary of Contents for Endress+Hauser Liquiline System CA80PH
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Products Solutions Services BA01435C/07/EN/05.21 71525548 2021-01-31 Valid as of version 01.09.00 Operating Instructions Liquiline System CA80PH Colorimetric analyzer for orthophosphate (molybdate- vanadate method)
Liquiline System CA80PH About this document About this document Warnings Structure of information Meaning This symbol alerts you to a dangerous situation. DANGER Failure to avoid the dangerous situation will result in a fatal or serious Causes (/consequences) injury. If necessary, Consequences of non-compliance (if applicable) ‣...
Documentation The following instructions complement these Operating Instructions and are available on the product pages on the Internet: • Brief Operating Instructions Liquiline System CA80PH, KA01186C • Operating Instructions Memosens, BA01245C • Software description for Memosens inputs • Calibration of Memosens sensors •...
Designated use The Liquiline System CA80PH is a wet-chemical analyzer for the almost continuous determination of the concentration of orthophosphate in liquid media. The analyzer is designed for use in the following applications: •...
Basic safety instructions Liquiline System CA80PH During operation: 1. If faults cannot be rectified: products must be taken out of service and protected against unintentional operation. 2. Keep the door closed when not carrying out service and maintenance work. CAUTION...
Photometer Controller Measuring system A complete measuring system comprises: • Analyzer Liquiline System CA80PH with the configuration ordered • Reagent, reagents and standard solution (to be ordered separately) • Sample conditioning Liquiline System CAT8x0 (optional) Microfiltration (Liquiline System CAT810) • Function: pressure pipe sampling and filtration •...
Product description Liquiline System CA80PH Membrane filtration (Liquiline System CAT860) • Function: sampling and filtration • Ceramic membrane filter candle; pore size 0.1 µm or 0.4 µm • Communication via Memosens protocol, control via CA80 • Automatic backflush function with cleaning solution and compressed air •...
Liquiline System CA80PH Product description A0044810 A0044809 5 Measuring system with Liquiline System 6 Measuring system with Liquiline System CAT820 CAT860 Pump Pump Liquiline System CA80 Valve Sample collecting vessel Liquiline System CA80 Sample collecting vessel overflow Sample...
Product description Liquiline System CA80PH A0044808 8 Measuring system with Liquiline System CA80, Liquiline System CAT820 and second analyzer Backflushing with compressed air (optional) Second analyzer Valve (optional) Sample to second analyzer Pump Filter (ceramic) Liquiline System CA80 Medium...
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Liquiline System CA80PH Product description 3.3.2 Terminal diagram The unique terminal name is derived from: Slot no. : Port no. : Terminal Example, NO contact of a relay Device with 4 inputs for digital sensors, 4 current outputs and 4 relays •...
Incoming acceptance and product identification Liquiline System CA80PH Incoming acceptance and product identification Incoming acceptance 1. Verify that the packaging is undamaged. Notify the supplier of any damage to the packaging. Keep the damaged packaging until the issue has been resolved.
Liquiline System CA80PH Incoming acceptance and product identification Interpreting the order code The order code and serial number of your product can be found in the following locations: • On the nameplate • In the delivery papers Obtaining information on the product 1.
Installation Liquiline System CA80PH Installation CAUTION Incorrect transportation can cause injury and damage the device ‣ Always use a lifting truck or a fork-lift to transport the analyzer. Two people are needed for the installation. ‣ Lift the device by the recessed grips.
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Liquiline System CA80PH Installation 654 (25.74) A0028821 15 Liquiline System CA80 with base, dimensions in mm (in) 1800 (70.9) 8 (0.31) A0041592 16 Post (accessory) for "Outdoor" version, dimensions in mm (inch) 5.1.2 Mounting location Note the following when erecting the device: ‣...
Installation Liquiline System CA80PH ‣ Ensure that the unit can drain freely, without any siphoning effects. ‣ Make sure air can circulate freely at the front of the housing. ‣ Open analyzers (i.e. analyzers that are supplied without a door) may only be erected in closed areas or in a protective cabinet or similar facility.
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Liquiline System CA80PH Installation The mounting materials required to secure the device to the wall are not supplied. 1. Provide the mounting materials to secure the device to the wall (screws, wall plugs) onsite. 2. Mount the wall holder unit (2 parts) on the wall.
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Installation Liquiline System CA80PH 624 (24.57) 530 (20.87) A0036783 20 Foundation plan Fasteners (4 x M10) Dimensions of Liquiline System CA80 A0036785 21 Securing the base 1. Screw the base to the ground. 2. With 2 people, lift the analyzer and fit it on the base. Use the recessed grips.
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Liquiline System CA80PH Installation 5.2.3 "Outdoor" version: mounting on a post Erecting the post 4 x 12 (0.47) 250 (9.84) A0041437 22 Foundation plan, dimensions in mm (in) When installing outdoors, consideration must be given to providing correct protection against lightning.
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Installation Liquiline System CA80PH Mounting analyzer on the post A0041425 A0041426 23 Analyzer mounted on post (from front) 24 Analyzer mounted on post (from behind) Fit the clamp of the post retainer on the retaining rods and post using the nuts.
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Liquiline System CA80PH Installation Mount the wall holder unit (included in the delivery with the analyzer) on the post retainer. Insert the spacer. Screw the suspension bracket of the wall holder unit (included in the delivery with the analyzer) onto the analyzer.
Installation Liquiline System CA80PH Hook in the analyzer. Fix the upper wall holder unit in place with the screw provided. Post-installation check After mounting, check all the connections to ensure they are secure. Endress+Hauser...
Liquiline System CA80PH Electrical connection Electrical connection WARNING Device is live! Incorrect connection may result in injury or death! ‣ The electrical connection may be performed only by an electrical technician. ‣ The electrical technician must have read and understood these Operating Instructions and must follow the instructions contained therein.
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Electrical connection Liquiline System CA80PH Connection of analog inputs and outputs, Memosens sensors or digital fieldbuses Remove the bottle tray: Lift up the recessed grip slightly and pull it towards the front. Remove the cover that is hooked into place.
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Liquiline System CA80PH Electrical connection 6 x Ph2 Release the 6 screws on the electronics compartment cover using a Phillips-head screwdriver and fold out the cover towards the front. 8. Only for order versions with G or NPT glands: Replace the pre-installed M-thread cable glands with the G or NPT cable glands that are enclosed.
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Electrical connection Liquiline System CA80PH After connecting: 1. Secure the electronics compartment cover with the 6 screws. 2. Fold up the carrier board and use the 6 screws to secure it after connecting. 3. Tighten the cable glands on the bottom of the device to secure the cables.
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Liquiline System CA80PH Electrical connection 6.2.3 "Outdoor" version: connecting the power supply and hose heater The power supply cable is not included with the delivery and must be provided by the customer. 1. Guide the power supply cable and the cable of the hose heater from below through the cable gland on the inner rear panel of the device and feed them up into the electronics compartment (→...
Electrical connection Liquiline System CA80PH Connecting sample preparation 6.3.1 Connecting the optional cleaning valve of Liquiline System CAT810 1. Disconnect the mains plug. 2. To fold out the carrier board towards the front, proceed as described in the "Routing the cables" section .
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Liquiline System CA80PH Electrical connection Cable sample (does not necessarily correspond to the original cable supplied) A0044089 A0044090 A0044091 28 Terminated cable 29 Inserting the cable 30 Tightening the screw (2 Nm) Outer shield (exposed) Cable clamp for hose heating...
Electrical connection Liquiline System CA80PH 10. Connect the cable or cables (depending on the version) to the following plug-in terminals: GN/YE A0028924 31 Connection scheme for Liquiline System CAT820 / 860 Hose heater 100 to 120 V/200 to 240 V AC (optional)
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Liquiline System CA80PH Electrical connection BASE2-E A0044867 32 Connection compartment in the controller housing Base module Base2-E Analyzer interface Dummy cover Module cover Base module E A0042273 33 BASE2-E Power supply for digital fixed cable sensors with Memosens protocol...
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Electrical connection Liquiline System CA80PH Com B Com A – A0024019 34 Example of a Memosens CYK10 data cable Connecting the ferrules of the sensor cable to the base module E 1. To access the electronics compartment, proceed as described in the "Routing the cables"...
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Liquiline System CA80PH Electrical connection Digital inputs and outputs DIO module – – – – – – 37 Wiring 36 Module diagram Current inputs Module 2AI – – 38 Module 39 Wiring diagram Endress+Hauser...
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Liquiline System CA80PH Electrical connection Example: Connecting the cleaning unit 71072583 for CAS40D NOTICE Power consumption too high for the Liquiline alarm relay! Can cause irreparable damage to the base module ‣ Connect the cleaning unit only to terminals of an additional module (AOR, 2R or 4R), not to the alarm relay of the base module.
Electrical connection Liquiline System CA80PH Terminal PROFIBUS DP Modbus RS485 Not connected DGND DGND LEDs on front of module Identifier Color Description RJ45 LNK/ACT RJ45 is disabled. Ethernet communication is via the BASE2 module RJ45 10/100 Power Supply voltage is applied and module is initialized...
Liquiline System CA80PH Electrical connection ‣ Using a suitable tool such as a tweezer, move all four DIP switches to the "ON" position. The internal termination is used. DGND B/B' A/A' 52 Structure of internal termination 2. External termination Leave the DIP switches on the module board in the "OFF"...
Electrical connection Liquiline System CA80PH Individual types of protection permitted for this product (impermeability (IP), electrical safety, EMC interference immunity, Ex protection) can no longer be guaranteed if, for example : • Covers are left off • Different power units to the ones supplied are used •...
Liquiline System CA80PH System integration System integration Overview of device description files 7.1.1 Device identification → 168, protocol-specific data 7.1.2 Source for device description and device master files Downloading device drivers 1. Go to the website: www.endress.com/downloads. A dropdown list is displayed.
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192.168.1.212/logbooks_csv.fhtml (for logbooks in CSV format) 192.168.1.212/logbooks_fdm.fhtml (for logbooks in FDM format) Downloads in FDM format can be securely transmitted, saved and visualized with Endress+Hauser' s "Field Data Manager Software". (→ www.endress.com/ms20) Operation The menu structure of the web server corresponds to the onsite operation.
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Liquiline System CA80PH System integration A0026780 57 Example of web server (menu/language=English) • Clicking a menu name or a function corresponds to pressing the navigator. • You can make your settings conveniently via the computer keyboard. Instead of using an Internet browser, you can also use FieldCare for configuration via Ethernet.
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System integration Liquiline System CA80PH Online configuration competes with onsite operation, i.e. each of the two options blocks the other one. On both sides it is possible to take away access from the other side. Operation • In the DTM the menu structure corresponds to the onsite operation. The functions of the Liquiline soft keys are found in the main window on the left.
Liquiline System CA80PH Operation options Operation options Structure and function of the operating menu Menu/Language English Č eština Nederlands Français Deutsch Italiano Polski A0040682 A0036773 60 Display (example) 59 Display (example) Menu path and/or device designation Soft key (press function)
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Operation options Liquiline System CA80PH 8.2.2 Configuration options Display only • You can only read the values but cannot change them. • Typical read-only values are: analyzer data, sensor data and system information • Example: Menu/Setup/Analyzer/../Measuring parameter Picklists • You receive a list of options. In a few cases, these also appear in the form of multiple choice boxes.
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Liquiline System CA80PH Operation options User-defined text • You are assigning an individual designation. • Enter a text. You can use the characters in the editor for this purpose (upper-case and lower-case letters, numbers and special characters). • Using the soft keys, you can: •...
Commissioning Liquiline System CA80PH Commissioning Before the supply voltage is applied On account of the device design, high switch-on currents occur when the device is commissioned at low temperatures. The power value indicated on the nameplate refers to the power consumption after one minute of operation when the device is commissioned at 5 °C (41 °F).
Liquiline System CA80PH Commissioning Visual inspection of the liquid-bearing lines ‣ Check the hose connections using the hose connection diagram. ‣ Is the suction line connected to the sample collector (if present)? ‣ Are the dispensers inserted correctly? ‣ Can the dispensers move up and down freely? ‣...
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Commissioning Liquiline System CA80PH If you want to already configure additional input and output parameters in the Basic setup analyzer: ‣ Configure the current outputs, relays, limit switches and device diagnostics with the following submenus. Endress+Hauser...
Liquiline System CA80PH Operation Operation 10.1 Display 10.1.1 Soft keys in the measuring mode On the bottom row of the display you can find four soft keys in the measuring screens: • With MENU and DIAG take you directly to the specific software menu.
Operation Liquiline System CA80PH Icon Location Description At measured value The measured value is influenced by a simulated value At measured value The displayed measured value is simulated (for sensors) Header bar Controller is active Only pH or ORP measurement...
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Liquiline System CA80PH Operation 10.2.2 Date and time Menu/Setup/General settings/Date/Time Function Options Info Set date Depends on the format Editing mode: Day (two-digit): 01 to 31 Month (two-digit): 01 to 12 Year (four-digit): 1970 to 2106 Set time Depends on the format...
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Operation Liquiline System CA80PH Menu/Setup/General settings/Hold settings Function Options Info ‣ Setup menu Selection Decide whether the device outputs should • Disabled switch to the defined hold state when the Diagnostics menu • Enabled particular menu is opened. Factory setting...
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Liquiline System CA80PH Operation Menu/Setup/General settings/Logbooks Function Options Info Analyzer event logbook Selection All diagnostic messages are recorded • Ring buffer Ring buffer • Fill up buffer If the memory is full, the most recent entry Factory setting automatically overwrites the oldest entry.
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Operation Liquiline System CA80PH Menu/Setup/General settings/Logbooks Function Options Info Data logbooks For connected Memosens sensors (optional) You can create a maximum of 8 data logbooks. Logbook name Customized text, 20 characters ‣ Source of data Selection Select a data source for the logbook entries.
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Liquiline System CA80PH Operation Menu/Setup/General settings/Logbooks Function Options Info Source of data Read only This is for information purposes only. If you want to record another value, delete this logbook Measured value and create a new data logbook. Log time left...
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Operation Liquiline System CA80PH • Logbook name Assign a name. Example: "01". • Source of data Select a data source. Example: Signal of binary input 1. • Measured value Select the measured value to be recorded. Example: pH value. • Scan time Specify the time interval between two logbook entries.
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Liquiline System CA80PH Operation Menu/Setup/(General settings or Inputs<sensor channel>)/Extended setup/Diagnostics settings/Diag. behavior Function Options Info Diag. output Selection Before being able to assign the message to an • None output you must first configure a relay output to • Alarm relay Diagnostics.
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Operation Liquiline System CA80PH Modbus Menu/Setup/General settings/Extended setup/Modbus Function Options Info Enable Selection You can switch off communication at this point. • Off The software can then only be accessed via local • On operation. Factory setting Termination Read only If the device is the last in the bus, you can terminate via the hardware.
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Liquiline System CA80PH Operation Menu/Setup/General settings/Extended setup/Webserver Function Options Info User administration List of users already View/edit You can change user names or passwords or created delete users. A user is already created at the factory: "admin" with password "admin".
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Operation Liquiline System CA80PH Menu/Setup/General settings/Extended setup/Ethernet Function Options Info Netmask xxx.xxx.xxx.xxx On the basis of the IP address of a device, the netmask specifies which IP addresses this device searches for in its own network and which addresses it could access in other networks via a router.
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Liquiline System CA80PH Operation Saving the setup Saving a setup offers the following advantages, among others : • Copying settings for other devices • Quick and easy switching between various setups, e. g. for different user groups or for recurring sensor type changes •...
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Operation Liquiline System CA80PH 5. Use OK to confirm or cancel and assign a new file name. Your setup is saved on the SD card in the "Device" folder. You cannot upload the exported setup to the device again. You must use the Save setup .
Liquiline System CA80PH Operation 3. Enter the new password again. The password has been changed successfully. Press the navigator for longer to return to the measuring mode. 10.3 Analyzer Menu/Setup/Analyzer Function Options Info Mode Read only Manual, automatic or fieldbus ‣...
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Operation Liquiline System CA80PH 10.3.1 Extended setup Measured value Menu/Setup/Analyzer/Extended setup/Measuring value Function Options Info Main value Selection If another main value is selected, this affects • PO4 other display screens. However, if another main • PO4-P value is selected, these display screens only •...
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Liquiline System CA80PH Operation Signals Menu/Setup/Analyzer/Extended setup Function Options Info Signal for sample request Lead time SPX Selection In the automatic mode, each measurement only 0.00 to 30.00 (mm:ss) starts once the lead time has elapsed. The request sample signal is active from the start of...
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Operation Liquiline System CA80PH 2. Enter the starting volume for every bottle. 3. Specify alarm and warning limits for the residual volumes. 4. Specify alarm and warning limits for the remaining time until the bottle refills are consumed. Menu/Setup/Analyzer/Extended setup/Diagnostics settings/Bottles...
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Liquiline System CA80PH Operation Menu/Setup/Analyzer/Extended setup/Diagnostics settings/Bottles Function Options Info Alarm limits Diag. code 727 Reagent RK 1 to 7 d Factory setting Standard S1 1 to 7 d Factory setting Absorption curve recording Menu/Setup/Analyzer/Extended setup/Diagnostics settings/Absorption curve recording Function...
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Operation Liquiline System CA80PH Menu/Setup/Analyzer/Measurement Function Options Info Measuring interval 0:10 to 24:00 (hh:mm) Function only available for: Start condition = Immediate or Date/time Factory setting 0:10 For configuring the time interval of the measurement Sequence of measurements Selection Defines the sequence of channels in automatic •...
Liquiline System CA80PH Operation 10.4 Sample preparation The menu displayed depends on the connected sample preparation system. The menu item does not appear if a Liquiline System CA80 analyzer without a collecting vessel is connected. The Liquiline System CAT860 can only be operated with a Liquiline System CA80 single-channel device.
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Operation Liquiline System CA80PH Menu/Setup/Sample preparation/Installation type = Others/Sample preparation 1 ... 2 Function Options Info Operating mode Selection • Controlled • Independent Sample preparation that is controlled by the • Controlled analyzer, e.g. Liquiline System CAT820 / CAT860 Factory setting •...
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Liquiline System CA80PH Operation Menu/Setup/Sample preparation/Installation type = Others/Sample preparation 1 ... 2 Function Options Info Pump pause Selection 20 to 50 s Factory setting 30 s CAT820 and CAT860 Pressurized air cleaning CAT820 only Selection Settings for sample preparation with or without Compressed air •...
Operation Liquiline System CA80PH Menu/Setup/Sample preparation/Installation type = Others/Sample preparation 1 ... 2 Function Options Info Limit change hose Function Selection • On • Off Factory setting Warning limit Selection Diag. code 337 01‐00 to 99‐00 (DD‐HH) Factory setting 60-00 Reset settings Resets all settings specific to sample preparation.
Liquiline System CA80PH Operation Menu/Setup/Sample preparation/Installation type = Inlet pipe sampling/Sample preparation 1 ... 2 Function Options Info Filter backflush Selection • On • Off Factory setting Cleaning duration Selection Cleaning duration of the automatic water or compressed 10 to 60 s...
Operation Liquiline System CA80PH Menu/Setup/Inputs/Current input x:y Function Options Info ‣ Lower range value -20.0 ... Upper range Enter the measuring range. The lower and value <unit of measure> upper range values are assigned to the 0 or Input variable = Parameter...
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Liquiline System CA80PH Operation 10.6.1 Application examples Chlorine regulation with feedforward control CA80 CCA250 Dig.in CA80 CCA250 Dig.out: PFM CA80 – CA80: DIO Dig.in: PFM Flow, e.g. Promag53 A0029239 65 Example of chlorine control with feedforward control Connection of the inductive proximity switch INS of CCA250 to the digital input of the DIO module...
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Operation Liquiline System CA80PH 7. Disturbance variable: in the controller menu, select the binary input to which you have connected the flow measured value. (Menu/Additional functions/Controllers/ Controller 1/Disturbance variable/Source of data = Binary input 6:2 and Measured value = PFM value) 8.
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Liquiline System CA80PH Operation The following information is processed at the binary inputs or output at the binary outputs: • Binary inputs: Signal for process access: The analyzer can only perform activities that require sample (measurement, calibration, cleaning) when the signal is active. The time and the sequence of activities correspond to the settings in the setup.
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Operation Liquiline System CA80PH The following information is processed at the binary inputs or output at the binary outputs: • Binary inputs: Signal for process access: The analyzer can only perform activities that require sample (measurement, calibration, cleaning) when the signal is active. The time and the sequence of activities correspond to the settings in the setup.
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Liquiline System CA80PH Operation Menu/Setup/Outputs/Binary output x:y Function Options Info Binary output Selection Signal type Selection Static signal Function Selection Analyzer Assignments Selection Here select which binary outputs output the Measurement active SP1 system status for a measurement currently Function = Analyzer running.
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Operation Liquiline System CA80PH 5. The output signal level High indicates that sample is required. 10.6.2 Binary input configuration Menu/Setup/Inputs/Binary input x:y Function Options Info Binary input Selection Switches the input on/off • Off • On Factory setting ‣...
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Liquiline System CA80PH Operation Menu/Setup/Inputs/Binary input x:y Function Options Info Input variable Selection Frequency • Frequency Display in Hz in the measuring menu • Parameter Parameter • Flow rate You subsequently determine the parameter Factory setting name and unit. These are then displayed in the Frequency measuring menu.
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Operation Liquiline System CA80PH Menu/Setup/Outputs/Binary output x:y Function Options Info Signal type = Static signal Function Selection Source for the outputted switching state • None The following functions depend on the option • Limit switches selected. • Diagnostics message Function = None switches off the function.
Liquiline System CA80PH Operation Menu/Setup/Outputs/Binary output x:y Function Options Info Source of data Selection Source whose value should be read out as a • None frequency via the binary output. • Sensor inputs • Binary inputs • Controller • Fieldbus signals •...
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Operation Liquiline System CA80PH Menu/Setup/Outputs/Current output x:y Function Options Info Current output Selection Use this function to activate or deactivate a • Off variable being output at the current output • On Factory setting Source of data Selection The sources of data on offer depend on your •...
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Liquiline System CA80PH Operation Source of data Measured value Oxygen (amp.) Selection • Temperature Oxygen (opt.) • Partial pressure • Concentration liquid • Saturation • Raw value nA (only Oxygen (amp.)) • Raw value μs (only Oxygen (opt.)) Cond i Selection •...
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Operation Liquiline System CA80PH Outputting the controller manipulated variable via the current output Unipolar+ Assign to the output to which an actuator that can increase the measured value is connected. Unipolar- Assign to the output to which an actuator that can decrease the measured value is connected.
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Liquiline System CA80PH Operation Outputting the status of a limit switch Function = Limit switch Function Options Info Source of data Selection Select the limit switch via which the status of the Limit switch 1 ... 8 relay is to be output.
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Operation Liquiline System CA80PH 1. PWM (pulse width modulation): The duty cycle is varied within a period T (T=t ). The cycle duration remains constant. y = t / T 10 % 50 % 100 % 1 "High" 0 "Low"...
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Liquiline System CA80PH Operation Function = Controller Function Options Info Maximum frequency 1 to 180 min Maximum number of pulses per minute The controller calculates the pulse duration Operating mode = PFM Factory setting based on this setting. 60 min ‐1...
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Operation Liquiline System CA80PH Outputting the status of a cleaning function Function = Cleaning(for sensors) Function Options Info Assignments Selection Here you can specify how a cleaning function • None should be displayed for the relay. • Depends on the type of...
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Liquiline System CA80PH Operation Please note that if you select Hold behavior= Freeze , the system not only flags the status but also actually "freezes" the measured value. In addition, you can define 8 binary variables (DI Blocks): 1. Define the data source.
Operation Liquiline System CA80PH In addition you can define 8 digital device variables (DI): ‣ Define the data source. You can choose from relays, binary inputs and limit switches. For further information on "EtherNet/IP", see the Guideline for Communication via EtherNet/IP, SD01293C 10.8...
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Liquiline System CA80PH Operation Source of data Measured value Cond i Selection • Temperature Cond c • Conductivity • Resistance (only Cond c) • Concentration (only Cond i and Cond c 4-pol) Disinfection Selection • Temperature • Sensor current • Concentration Selection •...
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Operation Liquiline System CA80PH Menu/Setup/Additional functions/Limit switches/Limit switch 1 ... 8 Function Options Info Cleaning program Selection Use this function to choose which cleaning • None instance should start when the limit switch is • Cleaning 1 ... 4 active.
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Liquiline System CA80PH Operation Menu/Setup/Additional functions/Limit switches/Limit switch 1 ... 8 Function Options Info Range lower value Settings depend on the Operating mode = Out of range check or In measured value range check Range upper value A0028524 70...
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Operation Liquiline System CA80PH Menu/Setup/Additional functions/Limit switches/Limit switch 1 ... 8 Function Options Info Delta value Settings depend on the Operating mode = Change rate measured value The slope of the measured value (MV) is monitored in this mode. Delta time 00:00:01 ...
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Liquiline System CA80PH Operation Menu/Setup/Additional functions/Time switches/ Time switch 1 ... 8 Function Options Info Function Selection Switches the function on or off • On • Off Factory setting ‣ Start date 01.01.2000 to 31.12.2099 Enter start date Format DD.MM.YYYY ‣...
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Operation Liquiline System CA80PH • Start date = 01.01.2020 • Start time = 12:00:00 • Signal duration = 05:00:00 • Period = 24:00:00 3. Create Formula mathematical function. Menu/Setup/Additional functions/Mathematical functions • MF1: Formula • Tracking = On • Source A = Time switch 1 •...
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Liquiline System CA80PH Operation 10.8.3 Controller Controller structure in Laplace representation A0015007 75 Block diagram of the controller structure Neutral zone Integral value Output limiting Derivative value Gain (P ‐ value) αT Damping time constant with α = 0 to 1 Integral action time (I ‐...
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Operation Liquiline System CA80PH • (5) Specify the parameters for the controller: • Set point, → Setpoint • Neutral zone, → Xn • Proportional band, → Xp • Integral action time (I-value), → Tn • Derivative action time (D-value), → Tv •...
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Liquiline System CA80PH Operation Menu/Setup/Additional functions/Controller 1 ... 2 Function Options Info ‣ Process type Selection Decide what type of process best describes • Inline your particular process. • Batch Factory setting Inline Batch process The medium is in a closed system.
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Operation Liquiline System CA80PH Menu/Setup/Additional functions/Controller 1 ... 2 Function Options Info Effective direction Selection In what direction should the controller influence • Direct the measured value? Controller type = PID 1-sided • Reverse • The measured value should increase as a result of dosing (e. g.
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Liquiline System CA80PH Operation Menu/Setup/Additional functions/Controller 1 ... 2 Function Options Info In the case of "flowing medium" (in-line) controls, the flow rate may not be constant. In some circumstances, strong fluctuations are possible. In the case of a settled control system in which the flow rate is suddenly halved, it is desirable that the dosed quantity from the controller is also directly halved.
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Operation Liquiline System CA80PH Menu/Setup/Additional functions/Controller 1 ... 2 Function Options Info ‣ Measured value Selection Specify the measured value that should be Depends on Source of data your disturbance variable. Factory setting You can use different measured values None depending on the data source.
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Liquiline System CA80PH Operation Menu/Setup/Additional functions/Controller 1 ... 2 Function Options Info 0.1 to 999.9 s Time constant for anti‐windup feedback The lower the value the greater the integrator Factory setting inhibition. Exercise extreme caution when 20.0 s making changes.
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Operation Liquiline System CA80PH Menu/Setup/Additional functions/Controller 1 ... 2 Function Options Info XHyst 0.0 to 99.9 % Width of the hysteresis range of the neutral zone, relative component of x Factory setting 0.0 % hyst e = w-x The graphic illustrates the manipulated variable (with a pure P‐controller) over the control deviation e (set point minus controlled variable).
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Liquiline System CA80PH Operation Types of cleaning The user can choose from the following cleaning types: • Standard clean • Chemoclean • Chemoclean Plus State of cleaning: Indicates whether the cleaning program is active or not. This is for information purposes only.
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Operation Liquiline System CA80PH Chemoclean Plus An example is the use of the CYR10 injector unit to clean pH glass sensors. (CYR10 connection → 37) Menu/Setup/Additional functions/Cleaning/Cleaning 1 ... 4/Chemoclean Plus/ChemoCleanPlus setup Function Options Info Cleaning steps setup Table to create a time...
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Liquiline System CA80PH Operation Defining the cleaning cycle Menu/Setup/Additional functions/Cleaning/Cleaning 1 ... 4 Function Options Info ‣ Cleaning cycle Selection Choose from a cleaning routine that is • Off restarted at set intervals and a user- • Interval definable weekly program.
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Operation Liquiline System CA80PH The "virtual" process values can be: • Output via a current output or a fieldbus • Used as a controlled variable • Assigned as a measured variable to a limit switch • Used as a measured variable to trigger cleaning •...
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Liquiline System CA80PH Operation Menu/Setup/Additional functions/Mathematical functions/MF1 to 8/Mode = Redundancy Function Options Info Deviation control Selection You can monitor the redundancy. Specify an • Off absolute limit value that must not be exceeded. • On Factory setting Deviation limit...
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Operation Liquiline System CA80PH Menu/Setup/Additional functions/Mathematical functions/MF1 to 8/Mode = Degassed conductivity Function Options Info Calculation Selection On/off switch for the function • Off • On Factory setting Cation conductivity Connected conductivity Cation conductivity represents the sensor sensor downstream from the cation exchanger and upstream from the "degassing module",...
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Liquiline System CA80PH Operation Calculated pH value The pH value can be calculated from the measured values of two conductivity sensors under certain conditions. Areas of application include power stations, steam generators and boiler feedwater. Menu/Setup/Additional functions/Mathematical functions/MF1 to 8/Mode = pH calculation from...
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Operation Liquiline System CA80PH Symbol Operation Type of operands Type of result Example Sine Numerical Numerical SIN(A) Cosine Numerical Numerical COS(B) Exponential function e Numerical Numerical EXP(A) Natural logarithm Numerical Numerical LN(B) Decadic logarithm Numerical Numerical LOG(A) Maximum of two values...
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Liquiline System CA80PH Operation Menu/Setup/Additional functions/Mathematical functions/MF1 to 8/Mode = Formula Function Options Info Formula User-defined text Table → 117 Make sure the exact notation is used (upper case). Blank spaces before and after mathematical characters are irrelevant.
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Operation Liquiline System CA80PH 3. Configure the Formula mathematical function: Source A = input signal phosphate and Source B = input signal volume flow. Formula: A*B*x (where x is an application-specific proportionality factor) 4. Select this formula as the source e.g. of the current output or of a modulated binary output.
Liquiline System CA80PH Diagnostics and troubleshooting Diagnostics and troubleshooting 11.1 General troubleshooting The analyzer continuously monitors its functions itself. If a diagnostic message occurs, the display alternates between the diagnostic message and the measured value in the measuring mode. The color of the display background changes to red if a diagnostic message for error category "F"...
Diagnostics and troubleshooting Liquiline System CA80PH Problem Possible cause Tests and/or remedial measures No reagents/sample Check levels Check the hoses of the reagents Check sample (only if self-priming) Check all connectors and tighten if necessary. Cuvette dirty Perform calibration with zero standard...
Liquiline System CA80PH Diagnostics and troubleshooting 11.5 Adapting the diagnostic information 11.5.1 Classification of diagnostic messages In the DIAG/Diagnostics list menu you can find more detailed information on the current diagnostic messages displayed. In accordance with Namur specification NE 107, the diagnostic messages are characterized •...
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Diagnostics and troubleshooting Liquiline System CA80PH Menu/Setup/Run the ../Extended setup/Diagnostics settings/Diag. behavior Function Options Info ‣ List of diagnostic messages Select the message to be changed. Only then can you make the settings for this message. Diag. code Read only...
Liquiline System CA80PH Diagnostics and troubleshooting 11.6 Overview of diagnostic information 11.6.1 Device-specific, general diagnostic messages Message Factory settings Tests or remedial action Selftest active Wait for self-test to be finished Hold active Output values and status of the channel are on...
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Diagnostics and troubleshooting Liquiline System CA80PH Message Factory settings Tests or remedial action Pump hose warning End of pump hose service life will be reached shortly Display under Menu/Diagnostics/Operating time information/Pump tube life Schedule replacement. After replacing, reset the operating time under Menu/Diagnostics/Operating time information.
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Liquiline System CA80PH Diagnostics and troubleshooting Message Factory settings Tests or remedial action Temperature sensor Temperature sensor defective in reactor, cuvette or sample pre-heating system ‣ Contact the Service Department and quote the number displayed. Valve defective Indicated valve is defective ‣...
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Diagnostics and troubleshooting Liquiline System CA80PH Message Factory settings Tests or remedial action Language change Language change failed ‣ Contact the Service Department. ‣ Diag. setup active Wait for maintenance to be finished. Logbook at 80% Save the logbook to the SD card and then delete the logbook in the device.
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Liquiline System CA80PH Diagnostics and troubleshooting Message Factory settings Tests or remedial action Cuvette covering Photometer check High degree of contamination - reliable measurement will not be possible soon Clean analyzer manually. Contact the Service Department. Cuvette covering Photometer check buildup, high degree of contamination - measurement no longer possible Start cleaning.
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Diagnostics and troubleshooting Liquiline System CA80PH Message Factory settings Tests or remedial action Wear parts warning One or more wear parts has almost reached the end of its service life. ‣ Replace the wear parts in question and reset the counter in Diagnostics/Operating time information.
Liquiline System CA80PH Diagnostics and troubleshooting Message Factory settings Tests or remedial action Modbus Watchdog The device did not receive a Modbus telegram from the master within the specified time. The status of Modbus process values received is set to invalid Curr.
Diagnostics and troubleshooting Liquiline System CA80PH The following messages are directly displayed every time you enter the menu: • Most important message Diagnostic message recorded with the highest criticality level • Past message Diagnostic message whose cause is no longer present.
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Liquiline System CA80PH Diagnostics and troubleshooting 11.9.2 Menu Logbooks DIAG/Logbooks Function Options Info All events Chronological list of all the logbook entries, with information on the type of event Show Events are displayed Select a particular event to display more detailed information.
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Diagnostics and troubleshooting Liquiline System CA80PH You can also adapt the display to suit your individual requirements: • Press the navigator button in the graphic display: you are given additional options such as the zoom function and x/y movement of the graph.
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Liquiline System CA80PH Diagnostics and troubleshooting DIAG/Logbooks Function Options Info Analyzer data logbooks Data logbooks for the data of the wet-chemical analyzers Data logbook SP1 In the case of two-channel devices, data logbook SP2 is also displayed Source of data...
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Diagnostics and troubleshooting Liquiline System CA80PH DIAG/Logbooks Function Options Info Set plotting window Here you can specify the start and end times of range the logbook entries to be displayed graphically. Plotter begin Selection • First entry: Defines the first entry saved in •...
Liquiline System CA80PH Diagnostics and troubleshooting DIAG/Logbooks Function Options Info All data logbooks Action, Use this function to save the logbook to an SD Data logbook SP1 commences as soon as the card. Absorption data logbook option is selected ‣...
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Diagnostics and troubleshooting Liquiline System CA80PH DIAG/System information Function Options Info Sample preparation 1 ... 2 Read only Depends on the type and number of • SP type sample preparations • Order code • Serial number • Hardware version • Software version •...
Liquiline System CA80PH Diagnostics and troubleshooting DIAG/System information Function Options Info Save system information Save to SD card File name assigned The information is saved on the SD automatically (includes a card in a "sysinfo" subfolder. time stamp) The csv file can be read and edited in MS Excel, for example.
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Diagnostics and troubleshooting Liquiline System CA80PH DIAG/Simulation Function Options Info Alarm relay Simulation of a relay state Relay x:y This menu appears once for each relay. Simulation Selection If you simulate the relay state, this is indicated • Off on the display by a simulation icon in front of •...
Liquiline System CA80PH Diagnostics and troubleshooting 11.13 Device test 11.13.1 Analyzer DIAG/System testAnalyzer/Sample collector Function Options Info Empty sample collector The sample collecting vessel can be automatically emptied in this menu. Start Stop Is only displayed if a collecting vessel is provided.
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Diagnostics and troubleshooting Liquiline System CA80PH DIAG/System testAnalyzer/Photometer Function Options Info Cleaning factor Read only Raw value Read only Temperature Read only DIAG/System testAnalyzer/Sample collector valve Function Options Info Towards sample collector If CAT860 sample preparation is connected, this menu item is also displayed.
Liquiline System CA80PH Diagnostics and troubleshooting 11.14 Resetting DIAG/Reset Function Options Info Device restart Selection Restart and keep all the settings • OK • ESC Factory default Selection Restart with factory settings • OK Settings that have not been saved are lost.
Liquiline System CA80PH Maintenance Maintenance Effects on process and process control ‣ Take all the necessary precautions in time to ensure the operational safety and reliability of the entire measuring point. WARNING Process pressure and temperature, contamination, electrical voltage Risk of serious or fatal injury ‣...
Maintenance Liquiline System CA80PH Interval Maintenance work 12 months • (If necessary) replace hoses: • Norprene, black • C-Flex, white ID 1.6 mm • Replace filter mats • Replace the O-ring in the cover of the sample collecting vessel 2 to 3 years (If necessary) replace hoses: •...
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Liquiline System CA80PH Maintenance Cleaning the housing ‣ Clean the front of the housing using commercially available cleaning agents only. The front of the housing is resistant to the following in accordance with DIN 42 115: • Ethanol (for a short time) •...
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Maintenance Liquiline System CA80PH Cleaning the (optional) sample collecting vessel Cleaning the collecting vessel Trigger the rinsing and draining of the collecting vessel before rinsing the analyzer → 147. 1. Remove all the hoses from the sample collecting vessel and the cable of the level monitoring system and take the sample collecting vessel out of the holder unit.
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Liquiline System CA80PH Maintenance Replacing bottles 1. Replace the removed bottles with fresh reagent or standard solution. Reagents must be prepared according to the instructions for mixing a reagent. 2. Reconnect the hoses to the Liquid Manager. 3. Select Menu/Operation /Maintenance/Bottle change mode/Bottle insertion/ Bottle selection.
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Maintenance Liquiline System CA80PH 5. Select Confirm bottles inserted. Recommendation: Afterwards, perform a manual calibration with the standard solution (Determine calibration factor). Alternatively, the zero point and calibration factor can be determined in one step (Determine zero point and calibr. factor).
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Liquiline System CA80PH Maintenance A0045364 80 Fan screen on the bottom 1. Open both fan screens and remove them. The filter mats are located under the screens. 2. Remove the used filter mats and replace them with new ones from the maintenance kit.
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Maintenance Liquiline System CA80PH 2. Slide the dispenser holder over the snap-fit hooks. Ensure that the holder snaps into place. Make sure that the drain hose D6 is routed behind dispenser 7. 3. Secure the cover and place the bottle tray back into the housing.
Liquiline System CA80PH Maintenance 2. Slide the dispenser holder over the snap-fit hooks. Ensure that the holder snaps into place. Make sure that the drain hose D6 is routed behind dispenser 7. Reinserting the bottles and starting the analyzer again 1.
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Maintenance Liquiline System CA80PH 4. Alternatively: Stop actions currently running under: Menu/Operation/Manual operation. 12.3.2 Emptying the sample collecting vessel 1. Menu/Operation /Maintenance/Decommissioning/Sample collector/Empty sample collector/Start must be selected. The system is automatically rinsed with sample and emptied. This process takes approx.
The product must be returned if repairs or a factory calibration are required, or if the wrong product was ordered or delivered. As an ISO-certified company and also due to legal regulations, Endress+Hauser is obliged to follow certain procedures when handling any returned products that have been in contact with medium.
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Repair Liquiline System CA80PH Disposing of chemicals ‣ CAUTION Risk of injury if used reagents and reagent waste are disposed of incorrectly! ‣ When disposing, follow the instructions of the safety data sheets for the chemicals used. ‣ Observe the local regulations regarding waste disposal.
Liquiline System CA80PH Accessories Accessories The following are the most important accessories available at the time this documentation was issued. ‣ For accessories not listed here, please contact your Service or Sales Center. 14.1 Device-specific accessories 14.1.1 Sample preparation Liquiline System CAT810 •...
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Accessories Liquiline System CA80PH 14.1.4 Maintenance kit CAV800 Order according to product structure (https://www.endress.com/device-viewer) Standard • Dispensers, 4 x 10 ml, including mounted adapter Blue method: additionally 4 x 2.5 ml Yellow method: additionally 2 x 2.5 ml • Hoses for reagents and standard solution •...
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Liquiline System CA80PH Accessories 14.1.6 Sensors pH glass electrodes Memosens CPS11E • pH sensor for standard applications in process and environmental engineering • Digital with Memosens 2.0 technology • Product Configurator on the product page: www.endress.com/cps11e Technical Information TI01493C Memosens CPS41E •...
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Accessories Liquiline System CA80PH Ceramax CPS341D • pH electrode with pH-sensitive enamel • Meets highest demands of measuring accuracy, pressure, temperature, sterility and durability • Product Configurator on the product page: www.endress.com/cps341d Technical Information TI00468C Orbipac CPF81D • Compact pH sensor for installation or immersion operation •...
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Liquiline System CA80PH Accessories Conductivity sensors with conductive measurement of conductivity Memosens CLS21E • Digital conductivity sensor for media with medium or high conductivity • Conductive measurement • With Memosens 2.0 • Product Configurator on the product page: www.endress.com/cls21e Technical Information TI01528C...
Accessories Liquiline System CA80PH Turbidity sensors Turbimax CUS51D • For nephelometric measurements of turbidity and solids in wastewater • 4-beam scattered light method • With Memosens technology • Product Configurator on the product page: www.endress.com/cus51d Technical Information TI00461C Turbimax CUS52D •...
Liquiline System CA80PH Accessories Communication; software 71449901 Upgrade code for PROFINET+web server for BASE2 71249548 Kit CA80: activation code for 1st digital sensor input 71249555 Kit CA80: activation code for 2nd digital sensor input Retrofit kits 71136999 Kit CSF48/CA80: retrofit service interface (CDI flange connector, counter nut)
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Accessories Liquiline System CA80PH Measuring cable CYK81 • Unterminated cable for extending sensor cables (e.g. Memosens, CUS31/CUS41) • 2 x 2 cores, twisted with shielding and PVC sheath (2 x 2 x 0.5 mm + shielding) • Sold by meter, Order No.: 51502543 14.3.2...
Liquiline System CA80PH Technical data Technical data 15.1 Input Measured variables , PO -P, P [mg/l, ppm] Measuring range CA80PH-**E3: 0.5 to 20 mg/l PO CA80PH-**E4: 0.5 to 50 mg/l PO Types of input • 1 or 2 measuring channels (analyzer main parameter) •...
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Technical data Liquiline System CA80PH PROFIBUS DP/RS485 Signal encoding EIA/TIA-485, PROFIBUS DP-compliant acc. to IEC 61158 Data transmission rate 9.6 kBd, 19.2 kBd, 45.45kBd, 93.75 kBd, 187.5 kBd, 500 kBd, 1.5 MBd, 6 MBd, 12 MBd Galvanic isolation Connectors Spring terminal (max. 1.5 mm), bridged internally (T‐function),...
Liquiline System CA80PH Technical data Signal on alarm Adjustable, as per NAMUR Recommendation NE 43 • In measuring range 0 to 20 mA: Failure current from 0 to 23 mA • In measuring range 4 to 20 mA: Failure current from 2.4 to 23 mA •...
Technical data Liquiline System CA80PH Extension module Switching voltage Load (max.) Switching cycles (min.) 230 V AC, cosΦ = 0.8 to 1 0.1 A 700,000 0.5 A 450,000 120,000 115 V AC, cosΦ = 0.8 to 1 0.1 A 1,000,000 0.5 A...
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Liquiline System CA80PH Technical data Modbus TCP TCP port TCP connections Protocol Function codes 03, 04, 06, 08, 16, 23 Broadcast support for function codes 06, 16, 23 Output data 16 measured values (value, unit, status), 8 digital values (value,...
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Technical data Liquiline System CA80PH PROFINET Protocol "Application layer protocol for decentral device periphery and distributed automation", PNIO Version 2.34 Communication type 100 MBit/s Conformance Class Conformance Class B Netload Class Netload Class II Baud rate Automatic 100 Mbps with full-duplex detection...
Liquiline System CA80PH Technical data Web server The Web server enables full access to the device configuration, measured values, diagnostic messages, logbooks and service data via standard WiFi/WLAN/LAN/GSM or 3G routers with a user-defined IP address. TCP port Supported features •...
Technical data Liquiline System CA80PH Sensor connection Sensors with Memosens protocol (optional) Sensor types Sensor cable Sensors Digital sensors without With plug-in • pH sensors additional internal power connection and • ORP sensors supply inductive signal • Combined sensors transmission •...
Liquiline System CA80PH Technical data With dilution module • Sample: 11 to 15 ml (0.37 to 0.51 fl oz)/measurement (depends on dilution factor) • Dilution water: 17 to 21 ml (0.57 to 0.71)/measurement (depends on dilution factor) Reagent requirement approx. 115 µl per measurement Standard requirement Given a calibration interval of 48 h approx.
Technical data Liquiline System CA80PH Consistency of the sample Low solids content (turbidity < 50 NTU), aqueous, homogenized Sample supply Unpressurized 15.10 Mechanical construction Dimensions → 16 Weight Order version Weight with cooling module Weight without cooling module Cabinet version 42 kg (92.6 lbs)
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Liquiline System CA80PH Technical data Hose entries 4 x bores for M32 for sample inflow and outflow Hose specification (self- • Clearance: max. 1.0 m (3.3 ft) priming analyzer) • Height: max. 0.5 m (1.6 ft) • Hose ID: 1.6 mm (¹/...