Teledyne 4700 Installation And Operation Manual page 129

Refrigerated samplers
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Gas
Chemical
Common
Formula
Properties
Carbon
CO
Asphyxiant, Colorless,
2
Dioxide
odorless. When breathed
in large quantities, may
cause acid taste.
Non-flammable. Not gen-
erally present in danger-
ous amounts unless an
oxygen deficiency exists.
Carbon
CO
Chemical asphyxiant. Col-
Monoxide
orless, odorless, tasteless.
Flammable.
Poisonous.
Carbon
CCl
Heavy, ethereal odor.
4
Tetra-
Chloride
Chlorine
Cl
Irritant. Yellow-green color.
2
Choking odor detectable in
very low concentrations.
Non-flammable.
Formal-
CH
O
Colorless, pungent suffo-
2
dehyde
cating odor.
Gasoline
C
H
Volatile solvent.
5
12
to
Colorless. Odor notice-
C
H
able at 0.03%. Flammable.
9
20
Hydrogen
H
Simple asphyxiant. Color-
2
less, odorless, tasteless.
Flammable
Hydrogen
HCN
Faint odor of bitter
Cyanide
almonds.
Colorless gas
Hydrogen
H
S
Irritant and poisonous vol-
2
Sulfide
atile compound. Rotten
egg odor in small concen-
trations. Exposure for 2 to
15 min. at 0.01% impairs
sense of smell. Odor not
evident at high concentra-
tions. Colorless. Flamma-
ble.
Methane
CH
Simple asphyxiant.
4
Colorless, odorless, taste-
less, flammable.
Nitrogen
N
Simple asphyxiant. Color-
2
less, tasteless. Non-flam-
mable. Principal
constituent of air. (about
79%).
Table B-1 Hazardous Gases (Continued)
Specific
Physiological
Gravity or
Effect*
Vapor
Density
Air = 1
1.53
Cannot be endured at 10%
more than a few minutes,
even if subject is at rest and
oxygen content is normal.
Acts on respiratory nerves.
0.97
Combines with hemoglobin
of blood. Unconsciousness
in 30 min. at 0.2% to 0.25%.
Fatal in 4 hours at 0.1%.
Headache in few hours at
0.02%.
5.3
Intestinal upset, loss of con-
sciousness, possible renal
damage, respiratory failure.
2.49
Irritates respiratory tract.
Kills most animals in a very
short time at 0.1%.
1.07
Irritating to the nose.
3.0
Anesthetic effects when
to
inhaled. Rapidly fatal at
4.0
2.4%. Dangerous for short
exposure at 1.1 to 2.2%.
0.07
Acts mechanically to deprive
tissues of oxygen. Does not
support life.
0.93
Slight symptoms appear
upon exposure to 0.002% to
0.004%. 0.3% rapidly fatal.
1.19
Impairs sense of smell, rap-
idly as concentration
increases. Death in few min-
utes at 0.2%. Exposure to
0.07 to 0.1% rapidly causes
acute poisoning. Paralyzes
respiratory center.
0.55
Acts mechanically to deprive
tissues of oxygen. Does not
support life.
vided oxygen
0.97
Physiologically inert.
Isco 4700 Refrigerated Sampler
Appendix B General Safety Procedures
Max
Max.
Explosive
Safe
Safe
Range
Location
60 Min.
8 Hour
(% by vol.
Exposure
Exposure
in air.)
Highest
ppm
ppm
Limits
Concentration
lower/upper
40,000
5,000
At bottom;
to
when heated
60,000
may stratify
at points
above bottom.
400
50
12.5
Near top,
74.0
especially if
present with
illuminating
gas.
1,000
100
At bottom.
to
1,500
4
1
At bottom.
10
7.0
Near bottom
73.0
4,000
1,000
1.3
At bottom
to
6.0
7,000
4.0
At top
74.0
10
6.0
Near top
40.0
200
20
4.3
Near bottom,
to
45.0
but may be
300
above bottom
if air is heated
and highly
humid.
Probably no
5.0
At top, increas-
limit, pro-
15.0
ing to certain
depth.
percent-age
is sufficient
for life.
Near top, but
may be found
near bottom.
Likely
Most
Simplest and
Common
Cheapest
of
Sources
Safe Method
of Testing
Products of combus-
Oxygen
tion, sewer gas,
deficiency
sludge. Also issues
indicator
from carbonaceous
strata.
Manufactured gas,
CO ampoules
flue gas, products of
combustion, motor
exhausts. Fires of
almost any kind.
Industrial wastes,
Detectable odor
solvent, cleaning
at low concentrations
Chlorine cylinder and
Detectable odor at
feed line leaks
low concentrations
Incomplete combus-
Detectable odor
tion of organics.
Common air pollut-
ant, fungicide.
Service stations,
1. Combustible
garages, storage
gas indicator.
tanks, houses.
2. Oxygen
deficiency
indicator.**
Manufactured gas,
Combustible gas
sludge digestion tank
indicator
gas, electrolysis of
water. Rarely from
rock strata.
Insecticide and
Detector tube
rodenticide
Coal gas, petro-
1. H
S Ampoule.
2
leum, sewer gas.
Fumes from blasting
2. 5% by weight
under some condi-
lead acetate
tions.
solution.
Sludge gas.
Natural gas, sludge
1. Combustible
gas, manufactured
gas indicator
gas, sewer gas.
Strata of sedimen-
2. Oxygen defi-
tary origin. In
ciency indicator.
swamps or marshes.
Sewer gas. sludge
Oxygen
gas. Also issues
deficiency
from some rock
indicator
strata.
B-7

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