Synology DS-101j User Manual page 79

By connecting a USB printer to DS-101j Disk Station, you will be able to share
the USB printer through the network. Click Refresh button and USB printer status
will become active as shown in the page below.
Refresh the USB printer status
Click Refresh for updated status of the USB printer.
Eject the USB printer
Please remember to always click Eject button, before you remove the printer.
Clean up the printer spool space
Click the Clean button when you want to clean up the printer spool space.
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Synology DS-101j