BAS 100B/W Instruction Manual page 118

Electrochemical workstation
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A.
RPM
Figure 10-28. Typical rotation rate (A) and potential wave form (B) for RDE.
Figure 10-29. Typical current response for RDE.
Hydrodynamic Modulation (HDM) is a related technique in which the frequency is
varied sinusoidally with time. More specifically, ω
to ω
1/2
. The A.C. current is handled using conventional data handling techniques; that
is, filtering followed by rectification or phase selective detection.
Consider the following example. According to the Levich equation, i
ω
=
ω
+ ∆
ω
1 2
/
1 2
/
1 2
/
sin
0
waveform of frequency
output is shown in Figure 10-31, and the processed I is shown in Figure 10-32. ∆i is
given by the equation
1 2
/
ω
∆i
=
i
ω
ω
0
0
E
B.
FINAL
t
QUIET TIME
INIT
σ
t (ω
is the base rotation rate that is modulated with a sine
o
= 2πf) and amplitude ∆ω
σ
σ
(
10-50
1/2
is varied, since i
is proportional
l
= Kω
l
1/2
(Figure 10-30)). The A.C.
t
1/2
, where

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