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Operating manual Multi 9310 Multi 9310P Multi 9310P Multi 9310 Digital pH / ORP / D.O. / conductivity meter for digital IDS sensors ba75937e03 12/2011...
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Contents Multi 9310 4.5.4 Example 1 on navigation: Setting the language ..24 4.5.5 Example 2 on navigation: Setting the date and time . . . 26 pH value......... . 28 Measuring .
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Multi 9310 Contents 8.3.4 Calibration data ....... 60 Settings ......... . 62 pH measurement settings .
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16 Firmware update ........94 16.1 Firmware update for the meter Multi 9310 ....94 16.2 Firmware-Update for IDS Sensors.
Overview Multi 9310 meter The compact, digital precision meter Multi 9310 enables you to carry out pH measurements, ORP measurements, conductivity measurements and dis- solved oxygen (D.O.) measurements quickly and reliably. The Multi 9310 provides the maximum degree of operating comfort, reliability and measuring certainty for all applications.
4 Printer 5 Control panel of the printer Sensors A measuring system ready to measure consists of the Multi 9310 meter and a suitable sensor. Suitable sensors are IDS pH sensors, IDS ORP sensors, IDS conductivity sensors and IDS D.O. sensors.
Multi 9310 Overview 1.3.1 IDS sensors IDS sensors support the automatic sensor recognition show only the settings relevant to the specific sensor in the setting menu process signals in the sensor digitally so that precise and interference-free measurements are enabled even with long cables...
1.3.2 IDS adapter for analog sensors With the aid of an IDS adapter, you can also operate analog sensors on the Multi 9310. The combination of the IDS adapter and analog sensor behaves like an IDS sensor. The measuring electronics with the stored adapter data are in the adapter head.
Multi 9310 Safety Safety Safety information 2.1.1 Safety information in the operating manual This operating manual provides important information on the safe operation of the meter. Read this operating manual thoroughly and make yourself familiar with the meter before putting it into operation or working with it. The operating manual must be kept in the vicinity of the meter so you can always find the infor- mation you need.
Safety Multi 9310 Safe operation 2.2.1 Authorized use The authorized use of the meter consists exclusively of the measurement of the pH, ORP, conductivity and dissolved oxygen in a laboratory environment. Only the operation and running of the meter according to the instructions and...
– software MultiLab User – software MultiLab Importer Power supply The Multi 9310 is supplied with power in the following ways: Mains operation with the supplied power pack Battery operation (4 batteries, 1.5 V Mignon type AA) USB operation via a connected USB-B cable...
Commissioning Multi 9310 3.3.1 Inserting the batteries You can operate the meter either with normal batteries or with rechargeable batteries (Ni-MH). In order to charge the batteries, an external charging device is required. Open the battery compartment (1) on the underside of the meter.
ENERAL DATA page 92). Connect the plug of the power pack to the socket for the power pack on the Multi 9310. Connect the original power pack to an easily accessible power outlet. 3.3.3 Mounting the stand The stand base can be mounted at the right side of the meter.
Operation Multi 9310 Operation General operating principles 4.1.1 Keypad In this operating manual, keys are indicated by brackets <..>. The key symbol (e.g. <ENTER>) generally indicates a short keystroke (under 2 sec) in this operating manual. A long keystroke (approx. 2 sec) is indicated by the underscore behind the key symbol (e.g.
Multi 9310 Operation 4.1.2 Display Example (pH): AutoCal TEC HOLD AR 01.07.2011 USB output Info 08:00 1 Status information (sensor) 2 Measured value 3 Measured parameter 4 Continuous measurement control (CMC function) 5 Sensor symbol (calibration evaluation, calibration interval) 6 Measured temperature (with unit)
(> SELV and > current circuit with current limiting). WTW IDS sensors and IDS adapters meet these requirements. 4.1.5 Sensor info You can display the current sensor data and sensor settings of a connected sensor at any time.
Multi 9310 Operation SenTix 940 B09250001 01.07.2011 More 08:00 Display further sensor data (settings) with <F1>/[More]. SenTix 940 B092500013 pH resolution 0.001 mV resolution Buffer Calibration interval Unit for slope mV/pH QSC: Software-Version V 1.00 01.07.2011 Back 08:00 Switching on the meter Switch the meter on with <On/Off>.
Operation Multi 9310 If the user administration function is activated, the Login dialog appears after the meter is switched on (see section 4.4 L OGIN WITH , page 20). A USER NAME The user administration function is not active in the delivery condi- tion.
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Multi 9310 Operation The login is done immediately if no password is required. If a sensor is connected the measured value display appears. If a password is required: Using < >< >, select the menu item, Password and confirm with <ENTER>.
Operation Multi 9310 Navigation 4.5.1 Operating modes Operating Description mode Measuring The measurement data of the connected sensor are shown in the measured value display Calibration The course of a calibration with calibration information, functions and settings is displayed Storing in...
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Multi 9310 Operation System General Interface Clock function Service information Reset 01.07.2011 Back 08:00 Settings Settings are indicated by a colon. The current setting is displayed on the right-hand side. The setting mode is opened with <ENTER>. Subsequently, the setting can be changed with < >< > and <ENTER>. Example:...
Operation Multi 9310 Calibration record Calibration data storage Buffer: Single-point calibration: Calibration interval: Unit for slope: mV/pH ] 2.00 4.01 7.00 10.01 01.07.2011 Back 08:00 4.5.4 Example 1 on navigation: Setting the language Press the <On/Off> key. The measured value display appears.
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Multi 9310 Operation System General Interface Clock function Service information Reset 01.07.2011 Back 08:00 Select the General submenu with < >< >. The current selection is displayed with a frame. Open the General submenu with <ENTER>. General Language: Deutsch Acoustic signal:...
Operation Multi 9310 4.5.5 Example 2 on navigation: Setting the date and time The meter has a clock with a date function. The date and time are indicated in the status line of the measured value display. When storing measured values and calibrating, the current date and time are automatically stored as well.
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Multi 9310 Operation Change and confirm the setting with < >< > and <ENTER>. The time is set. If necessary, set the Date and Date format. The setting is made similarly to that of the time. To make further settings, switch to the next higher menu level with <F1>/ [Back].
Multi 9310 pH value Measuring 5.1.1 Measuring the pH value NOTE When connecting a grounded PC/printer, measurements cannot be performed in grounded media as the values would be incorrect. The USB interface is not galvanically isolated. Connect the IDS pH sensor to the meter.
Multi 9310 pH value You can terminate the Stability control function and the HOLD func- tion with <AR> or <M> at any time. Using <ENTER>, activate the Stability control function manually. The [AR] status indicator appears while the measured value is assessed as not stable.
Multi 9310 mode: Temperature Resolution of the Temp. measurement sensor temp. display 0.1 °C Automatic with temperature sensor 1 °C Manual pH calibration 5.2.1 Why calibrate? pH electrodes age. This changes the zero point (asymmetry) and slope of the pH electrode.
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Multi 9310 pH value 01.07.2011 08:00 Thoroughly rinse the sensor with deionized water. Immerse the sensor in the first buffer solution. For measurements without temperature sensor (e.g. when using an IDS adapter Measure the temperature of the buffer manually and enter it with <...
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Multi 9310 Immerse the pH sensor in buffer solution 2. When measuring without temperature sensor: Measure the temperature of the buffer manually and enter it with < >< >. Start the measurement with <ENTER>. The measured value is checked for stability (stability control).
Multi 9310 pH value 01.07.2011 08:00 Wait for the measurement with stability control to be completed or ter- minate the stability control and take over the calibration value with <ENTER>. The calibration display for the next buffer appears (voltage display).
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Multi 9310 01.07.2011 08:00 Thoroughly rinse the sensor with deionized water. Immerse the pH sensor in buffer solution 1. For measurements without temperature sensor (e.g. when using an IDS adapter Measure the temperature of the buffer manually and enter it with <...
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Multi 9310 pH value 01.07.2011 08:00 Set the nominal buffer value for the measured temperature with < >< >. Accept the calibration value with <ENTER>. The calibration display for the next buffer appears (voltage display). If necessary, finish the calibration procedure as a single-point calibra- tion with <M>.
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Multi 9310 01.07.2011 08:00 Set the nominal buffer value for the measured temperature with < >< >. Accept the calibration value with <ENTER>. The calibration display for the next buffer appears (voltage display). If necessary, finish the calibration procedure as a two-point calibration with <M>.
Multi 9310 pH value Set the nominal buffer value for the measured temperature with < >< >. Accept the calibration value with <ENTER>. The calibration display for the next buffer appears (voltage display). If necessary, use <M> to finish the calibration.
Multi 9310 5.2.6 Calibration data The calibration record is automatically transmitted to the interface after calibrating. Displaying the The calibration record of the last calibration is to be found under the menu item, calibration data Calibration / Calibration record. To open it in the measured value display, press the <CAL__>...
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Multi 9310 pH value Calibration After calibrating, the meter automatically evaluates the calibration. The zero evaluation point and slope are evaluated separately. The worse evaluation of both is taken into account. The evaluation appears on the display and in the calibration record.
Multi 9310 5.2.7 Continuous measurement control (CMC function) The Continuous Measurement Control (CMC function) facilitates to evaluate the current measured value instantly and definitely. After each successful calibration the scale of the pH measuring range is dis- played in the measured value display. Here you can very clearly see whether or not the current measured value is in the calibrated part of the measuring range.
Multi 9310 pH value 5.2.8 QSC function (sensor quality control) General information The QSC function (Quality Sensor Control) is a new sensor evaluation for on the QSC function digital IDS sensors. It evaluates the condition of an IDS pH sensor individually and with a very fine grading.
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Multi 9310 Carry out the normal calibrations for your special measuring range with your usual standard solutions as previously done. As soon as the QSC function was enabled for an IDS sensor, it is not possible to return to the sensor evaluation with the sensor symbol for this sensor.
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Multi 9310 pH value sor evaluation. 01.07.2011 USB output Info 08:00 1 QSC scale The double arrow on the QSC scale indicates the current sensor evaluation Carrying out a QSC A QSC control calibration can, e.g. be useful if the sensor evaluation noticeably control calibration changed (after some normal calibrations).
Multi 9310 Measuring 6.1.1 Measuring the ORP NOTE When connecting a grounded PC/printer, measurements cannot be performed in grounded media as the values would be incorrect. The USB interface is not galvanically isolated. IDS ORP sensors are not calibrated. However, you can check IDS ORP sensors using a test solution.
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Multi 9310 You can terminate the Stability control function and the HOLD func- tion with <AR> or <M> at any time. Using <ENTER>, activate the Stability control function manually. The [AR] status indicator appears while the measured value is assessed as not stable. A progress bar is displayed and the display of the measured parameter flashes.
Multi 9310 6.1.2 Measuring the temperature For reproducible ORP measurements, it is essential to measure the tempera- ture of the test sample. When operating a sensor without integrated temperature sensor, you first have to measure and enter the temperature of the sample.
Multi 9310 Dissolved oxygen Dissolved oxygen Measuring 7.1.1 Measuring D.O. NOTE When connecting a grounded PC/printer, measurements cannot be performed in grounded media as the values would be incorrect. The USB interface is not galvanically isolated. Connect the D.O. sensor to the meter.
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Dissolved oxygen Multi 9310 You can switch the salinity correction on or off and enter the salinity in the menu for calibration and measurement settings (see section 9.3.1 S D.O. ETTINGS FOR SENSORS MENU FOR MEASUREMENT AND ), page 66).
Multi 9310 Dissolved oxygen Criteria for a stable The Stability control function checks whether the measured values are stable measured value within the monitored time interval. Measured parame- Time interval Stability in the time interval D.O. concentration 20 seconds ∆ : better than 0.03 mg/l D.O.
Dissolved oxygen Multi 9310 ® check procedure 7.2.1 Why should you check the sensor? ® With the FDO Check procedure, you can find out in a simple manner ® whether the FDO 925 D.O. sensor should be cleaned or calibrated.
Multi 9310 Dissolved oxygen [t90= 30 s] 01.07.2011 08:00 Start the measurement with <ENTER>. The measured value is checked for stability (stability control). The [AR] status indicator is displayed. The measured parameter flashes. Wait for the end of the AutoRead measurement ([HOLD][AR]) status indicator or take over the measured value with <ENTER>.
When the calibration interval has expired When your accuracy requirements are especially high Routinely within the framework of the company quality assurance 7.3.3 Calibration procedures The Multi 9310 provides 2 calibration procedures: Calibration in water vapor-saturated air. ® Use an OxiCal air calibration vessel for calibration.
Multi 9310 Dissolved oxygen 01.07.2011 08:00 Start the measurement with <ENTER>. The measured value is checked for stability (stability control). The [AR] status indicator is displayed. The measured parameter flashes. Wait for the end of the AutoRead measurement ([HOLD][AR]) status indi- cator.
Dissolved oxygen Multi 9310 Start the measurement with <ENTER>. The measured value is checked for stability (stability control). The [AR] status indicator is displayed. The measured parameter flashes. Wait for the end of the AutoRead measurement or accept the calibration value with <ENTER>.
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Multi 9310 Dissolved oxygen Menu item Setting/ Description function Calibration / Displays the calibration records. Calibration data stor- age /Display Further options: Scroll through the calibration records with < >< >. Output the displayed calibra- tion record to the interface with <F2>/[USB output].
Conductivity Multi 9310 Conductivity Measuring 8.1.1 Measuring the conductivity NOTE When connecting a grounded PC/printer, measurements cannot be performed in grounded media as the values would be incorrect. The USB interface is not galvanically isolated. Connect the conductivity sensor to the meter.
Multi 9310 Conductivity ting for automatic Stability control (see section 9.5.3 A UTOMATIC TABILITY CON , page 71) in the System menu. TROL Freeze the measured value with <AR>. The [HOLD] status indicator is displayed. The HOLD function is active.
Conductivity Multi 9310 temperature of the test sample. IDS sensors measure the temperature with a temperature sensor integrated in the IDS sensor. Temperature compensation The calculation of the temperature compensation is based on the preset refer- ence temperature, 20 °C or 25 °C. It appears on the display as Tr20 or Tr25.
Multi 9310 Conductivity Calibration 8.3.1 Why calibrate? Aging slightly changes the cell constant, e. g. due to coatings. As a result, an inexact measured value is displayed. The original characteristics of the cell can often be restored by cleaning the cell. Calibration determines the current value of the cell constant and stores this value in the meter.
Conductivity Multi 9310 01.07.2011 08:00 Immerse the conductivity sensor in the control standard solution, 0.01 mol/l KCI. Start the measurement with <ENTER>. The measured value is checked for stability (stability control). The [AR] status indicator is displayed. The measured parameter flashes.
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Multi 9310 Conductivity Menu item Setting/ Description function Calibration / Displays the calibration records. Calibration data storage / Display Further options: Scroll through the calibration records with < >< >. Output the displayed calibration record to the interface with <F2>/ [USB output].
Settings Multi 9310 Settings pH measurement settings 9.1.1 Settings for pH measurements Settings The settings are made in the menu for calibration and measurement settings of the pH/ORP measurement. To open the settings, display the required mea- sured parameter in the measured value display and press the <ENTER> key.
Multi 9310 Settings Menu item Possible Description setting pH resolution 0.001 Resolution of the pH display 0.01 mV resolution Resolution of the mV display Reset Resets all sensor settings to the delivery condition (see sec- tion 9.6.1 R , page 72).
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Settings Multi 9310 Buffer set * pH values DIN 19267 1.090 25 °C 4.650 6.790 9.230 Mettler Toledo USA * 1.679 25 °C 4.003 7.002 10.013 Mettler Toledo EU * 1.995 25 °C 4.005 7.002 9.208 Fisher * 2.007 25 °C 4.002...
Settings Multi 9310 Confirm the setting with <ENTER>. Quit the menu with <M>. ORP measurement settings 9.2.1 Settings for ORP measurements The settings are made in the menu for measuring settings of the ORP measure- ment. To open the settings, display the required measured parameter in the measured value display and press the <ENTER>...
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Multi 9310 Settings Menu item Possible Description setting Calibration /Cali- 1 ... 180 ... Calibration interval for the D.O. sensor bration interval 999 d (in days). The meter reminds you to calibrate regularly by the flashing sensor sym- bol in the measuring screen.
Settings Multi 9310 Cond measurement settings 9.4.1 Settings for IDS conductivity sensors Settings The settings are made in the menu for the measured parameter, conductivity. To open the settings, display the required measured parameter in the mea- sured value display and press the <ENTER> key. After completing the settings, switch to the measured value display with <M>.
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Multi 9310 Settings Menu item Possible Description setting Temp. comp. (TC) / 0.000 ... Coefficient of the linear temperature Linear coeff. 2.000 ... compensation. 3.000 %/K This menu item is only available when the linear temperature compensation is set. Temp. comp. (TC) / 20 °C...
Comma (xx,x) System / Interface / Output of a header for Output format: Output header System / Printer Settings for the integrated printer of the Multi 9310 P. For details, see section 12 P RINTER 9310P), page 83 ONLY ULTI...
THE SYSTEM SETTINGS 9.5.2 Data storage This menu contains all functions to display, edit and erase stored measured values. Detailed information on the memory functions of the Multi 9310 are given in section 10 D , page 75. ATA STORAGE 9.5.3 Automatic Stability control...
Settings Multi 9310 9.5.5 Display illumination The meter automatically switches off the display illumination if no key is pressed for 20 seconds. The illumination is switched on with the next keystroke again. You can also generally switch on the display illumination (see section 9.5.1 , page 70).
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Multi 9310 Settings The following settings for ORP measurements are reset to the default settings with the Reset function: Setting Default settings mV resolution Man. temperature 25 °C The sensor settings are reset under the Reset menu item in the menu for cali- bration and measurement settings.
Settings Multi 9310 The sensor settings are reset under the Reset menu item in the menu for cali- bration and measurement settings. To open the settings, display the required measured parameter in the measured value display and press the <ENTER>...
Multi 9310 Data storage Data storage You can transmit measured values (datasets) to the data storage: Manual data storage (see section 10.1 M , page 75) ANUAL DATA STORAGE Automatic data storage at intervals (see section 10.2 A UTOMATIC DATA STOR...
Data storage Multi 9310 10.2 Automatic data storage at intervals The data storage interval (Interval) determines the time interval between auto- matic data storage processes. Each data storage process transmits the current dataset to the interface at the same time.
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Multi 9310 Data storage Starting the To start the automatic data storage function, select continue with < >< > and automatic data confirm with <ENTER>. The meter switches to the measured value display. storage function 0d03h00min 01.07.2011 08:00 1 Remaining storage duration...
Data storage Multi 9310 10.3 Measured value data storage 10.3.1 Editing the measured value data storage The contents of the manual or automatic measurement data storage can be shown on the display. Each of the measurement data storages has a function to erase the entire contents.
24.8 °C AR Sensor: +++ 01.07.2011 USB output Back 08:00 Representation of a 01.07.2011 07:43:33 dataset inoLab Multi 9310 (USB output) Ser. no. 09250023 ID number 2 SenTix 940 Ser. no. B092500013 6.012 24.8 °C, AR, S: +++ ________________________________________ 01.07.2011 07:43:53 inoLab Multi 9310 Ser.
- 4 levels (+++, ++, +, -, or no evaluation) or - QSC (percentage) 10.3.4 Storage locations The Multi 9310 meter has two measurement data storages. The measured values recorded either manually or automatic are stored separately in indi- vidual measurement data storages.
Via the USB-B interface (USB Device) you can transmit data to a PC or printer and update the meter software. 11.3 Connecting the PC / USB-B interface (USB Device) Connect the Multi 9310 to the PC via the USB-B interface. Installation of the System requirements of the PC for installation of the USB driver:...
Transmitting data (USB interfaces) Multi 9310 11.4 Options for data transmission to a PC Via the USB-B interface you can transmit data to a PC. The following table shows which data are transmitted to the interface in which way: Data...
4 Lid of the paper compartment 12.1 Commissioning / switching the printer on or off Switching on the Connect the power pack to the Multi 9310 P. printer The LED lights up green. The printer is ready for operation. If the printer was switched off (LED flashing): Switch on the printer with <OFF>.
Printer (only Multi 9310P) Multi 9310 12.2 Operation / printing Data are only output to the printer if the following conditions are met Data are transmitted manually or automatically (see section 11.4 O PTIONS PC, page 82) FOR DATA TRANSMISSION TO A the printer is switched on (LED illuminated) there is no USB connection.
Multi 9310 Printer (only Multi 9310P) Use original WTW rolls of paper only. You will find information on this in the WTW catalog L ABORATORY or on the Internet. IELD NFORMATION The thermal paper will remain legible for at least 7 years if stored appropriately.
Maintenance, cleaning, disposal Multi 9310 Maintenance, cleaning, disposal 13.1 Maintenance 13.1.1 General maintenance activities The only maintenance activity required is replacing the batteries. See the relevant operating manuals of the IDS sensors for instruc- tions on maintenance. 13.1.2 Replacing the batteries You can operate the meter either with normal batteries or with rechargeable batteries (Ni-MH).
Multi 9310 Maintenance, cleaning, disposal Dispose of used batteries according to the local regulations of your country. End users within the European Union are obligated to return used batteries (even ecologically compatible ones) to a collection point set up for recycling purposes.
What to do if... Multi 9310 What to do if... 14.1 pH More information and instructions on cleaning and exchange of sensors are given in the documentation of your sensor. Error message Cause Remedy OFL, UFL IDS pH sensor: – Measured value outside the –...
Multi 9310 What to do if... No stable measured Cause Remedy value IDS pH sensor: – Junction contaminated – Clean junction – Membrane contaminated – Clean membrane Test sample: – pH value not stable – Measure with air excluded if neces- sary –...
What to do if... Multi 9310 Cause Remedy – Measured value outside the – Use a suitable IDS D.O. sensor measuring range Error message, Cause Remedy Error – Sensor contaminated – Clean the sensor – Measured temperature value – Keep to the temperature range for...
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Multi 9310 What to do if... Cause Remedy – Batteries almost empty – Replace the batteries (see section 13.1 M , page 86) AINTENANCE Display Instrument does not Cause Remedy react to keystroke – Operating condition undefined – Processor reset: or EMC load unallowed Press the <ENTER>...
Further data are given in the documentation of your sensor. 15.2 General data Dimensions Multi 9310: Approx. 240 x 190 x 80 mm Multi 9310 P: Approx. 290 x 190 x 80 mm Weight Multi 9310: Approx. 0.8 kg Multi 9310 P: Approx.
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Multi 9310 Technical data USB interface (device) Type USB 1.1 USB-B (Device), PC Baud rate Adjustable: 1200, 2400, 4800, 9600, 19200 Baud Data bits Stop bits Parity None Handshake RTS/CTS Cable length Max. 3 m Applicable directives EC directive 2004/108/EC...
USB interface (virtual COM port) on the PC the driver for the USB interface (on the enclosed CD-ROM) the USB cable (included in the scope of delivery of the Multi 9310). Install the downloaded firmware update on a PC.
IDS sensor to the newest version. You can find available firmware update files for your IDS sensor on the Internet. For updating, connect the IDS sensor to the Multi 9310, and the Multi 9310 to a PC. For the update via the USB-B interface, the following is required:...
Glossary Multi 9310 Glossary pH/ORP Asymmetry see zero point Electromotive force of The electromotive force U of the combination electrode is the measur- an electrode able electromotive force of an electrode in a solution. It equals the sum of all the galvanic voltages of the combination electrode. Its dependency on the pH results in the electrode function, which is char- acterized by the parameters, slope and zero point.
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Pressure caused by the oxygen in a gas mixture or liquid. D.O. saturation Short name for the "relative D.O. saturation". ® OxiCal WTW name for a procedure to calibrate D.O. measuring systems in water vapor saturated air. Salinity The absolute salinity S of seawater corresponds to the relationship of the mass of dissolved salts to the mass of the solution (in g/kg).
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Glossary Multi 9310 Calibration Comparing the value from a measuring system (e. g. the displayed value) to the correct value or a value that is regarded as correct. Often, this expression is also used when the measuring system is adjusted at the same time (see adjusting).
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