Buick 2004 Rainier Owner's Manual page 297

While refueling, hang the fuel cap by the tether using
the hook located on the inside of the filler door.
To remove the fuel cap, turn it slowly to the left
(counterclockwise).
CAUTION:
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If you spill fuel and then something ignites it,
you could be badly burned. Fuel can spray out
on you if you open the fuel cap too quickly. This
spray can happen if your tank is nearly full, and
is more likely in hot weather. Open the fuel cap
slowly and wait for any "hiss" noise to stop.
Then unscrew the cap all the way.
Be careful not to spill fuel. Don't top off or overfill your
tank, and wait a few seconds after you've finished
pumping before you remove the nozzle. Clean fuel from
painted surfaces as soon as possible. See Cleaning
the Outside of Your Vehicle on page 5-96.
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