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ABB GLA231 Series User Manual

ABB GLA231 Series User Manual

Performance rackmount gas analyzer
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GLA231 Series
Performance Rackmount Gas Analyzer
User Manual
ABB Inc. Measurement & Analytics
3400, rue Pierre-Ardouin
Quebec, (Quebec) G1P 0B2 Canada
Tel: 1 800 858 3847 (North America)
Tel: +1 418 877 2944 (Worldwide)
Fax: +1 418 877 2834
abb.com/analytical
ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_AC_09_2016

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  • Page 1 User Manual ABB Inc. Measurement & Analytics 3400, rue Pierre-Ardouin Quebec, (Quebec) G1P 0B2 Canada Tel: 1 800 858 3847 (North America) Tel: +1 418 877 2944 (Worldwide) Fax: +1 418 877 2834 abb.com/analytical ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_AC_09_2016...

  • Page 2: Table Of Contents

    User Interface Operation ....................29 Main Display Screen ..........................30 HMI Dashboard ............................31 Spectra Chart Display .......................... 32 GLA231-HFHC Performance Rackmount Hydrogen Fluoride / Hydrogen Chloride Analyzer ..32 GLA231-EAA Performance Rackmount Ammonia Analyzer ..............33 ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 3 PC104 Stack ............................63 Laser(s) and Astigmatic Mirrors ......................63 Self Correction ............................64 Output Data ............................64 Preventative Maintenance ........................66 Main Features ............................67 Theory of Operation ..........................67 LGR Off-Axis ICOS ..........................68 ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 4: Patent

    ABB product catalogs, the latter takes precedence. ABB reserves the right to make changes to the specifications of all equipment and software, and to the contents of this document, without obligation to notify any person or organization of such changes.

  • Page 5: Customer Support

    Customer Support ABB provides product support services worldwide. To receive product support, either in or out of warranty, contact the ABB office that serves your geographical area, or the office indicated below: ABB Inc. Measurement & Analytics 3400, rue Pierre-Ardouin...

  • Page 6: Introduction

    Introduction This document describes usage, installation, operational safety, maintenance, and troubleshooting details for the GLA231 series gas analyzer. Details of this manual include: • Menus and data screens • Calibration instructions • Data sampling rate adjustments • Data file transfer instructions Only authorized persons may open the analyzer cover or perform internal maintenance.

  • Page 7: Safety

    Title 21 Code of Federal Regulations, chapter 1, sub-chapter J WEEE Directive The GLA231 series gas analyzer product is not subject to WEEE Directive 2002/96/EC (Waste Electrical and Electronic Equipment) or relevant national laws (e.g. ElektroG in Germany). The product must be disposed of at a specialized recycling facility. Do not use municipal garbage collection points.

  • Page 8: Symbols

    The following labels are placed on the analyzer to identify hazardous locations: Heavy Object Label This label is affixed to the outer covers of the analyzer. Total weight = 29kg. (Figure 1) Figure 1: Heavy Object Label ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 9: Pinch Point Label

    Figure 3: High Voltage Label Laser Radiation Label These labels are located on the top cover. The fiber laser is visible only when the top cover is removed. (Figure 4) Figure 4: Laser Radiation Label ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 10: Operator Safety

    Operating the analyzer in any other condition can damage the equipment or injure personnel. Follow these general safety guidelines at all times. The GLA231 Series analyzer is a Category II (Overvoltage Category) installation. Do not operate the analyzer when the top enclosure panel is removed.

  • Page 11: Heavy Objects

    The rack-mount analyzer weighs approximately 29kg, and qualifies as a heavy object. Figure 5 Heavy Object label shows the The analyzer should not be hand-carried. ABB recommends the unit be rolled to its’ final mounting site on a wheeled table. Use a minimum of two people when lifting.

  • Page 12: Pinch Point Hazards

    Location of Hazardous Voltages Electrical hazard warning labels are applied wherever the removal of the panel can create an opportunity for contact with hazardous voltages. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 13: Electrical Safety Task Types

    20 joules, or radio frequency (RF) is present • Equipment is energized Type • Measurements and adjustments require physical entry into the equipment, or equipment configuration will not allow the use of clamp- on probes ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 14: Electrical Hazards During Normal Operation

    Occurs when validating AC power from the facility at the power entry module to the AC/DC power supply converter. • Type 5 electrical hazard There are no Type 5 tasks required for the analyzer. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 15: Laser Hazards

    Laser Hazards The GLA231 Series analyzer will contain 1 or 2 lasers, depending on the gases to be measured. The gas types determine the laser wavelength. Under normal operation, with the enclosure top panel Class 1 Laser Product Title 21 Code of Federal...

  • Page 16: Internal Laser Interlock Switch

    Make sure all handling equipment is electrically grounded. Mop or wipe up, and then place all chemical-soaked items in containers approved by the US Department of Transportation (DOT), or the appropriate local regulatory agency. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 17: Facilities Interface Requirements

    0.08 kVA Wire Provided with the instrument Dedicated ground, not neutral. Must be earth Grounding grounded. Supplied by the customer at the Supply Point Main Disconnect Interconnect. Circuit breaker able to support 10A. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 18 0.375” (9.525 mm) Tube Swagelok Fitting Do not use liquid products for leak detection. Liquid can travel into the line at the point of the leak and contaminate the measurement source and impact measurement performance. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 19: Power Service

    Grounding The GLA231 Series analyzer is grounded through the AC power plug to the customer AC power source. This ground must be tied into one main grounding conductor. This ground wire is a dedicated ground (not a neutral) and must be carried back to a service ground that is earth grounded.

  • Page 20: Equipment Facility Drawings

    Equipment Facility Drawings This section provides drawings for the GLA231 series analyzer. This is a rack-mount analyzer. The front (Figure 10) and back (Figure 11) views show the required facilities and their specifications for: • Exhaust gas • Inlet gas •...
  • Page 21 Figure 10 shows the front of the analyzer. Figure 10: Front Panel Figure 11 shows the back of the analyzer. Figure 11: Back Panel ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 22 Figure 12 shows the right side panel of the analyzer. Figure 12 : Right Side Panel Figure 13 shows the left side panel of the analyzer. Figure 13 : Left Side Panel ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 23 Figure 14 shows the bottom panel of the analyzer. Figure 14 : Bottom Panel All drawings in this manual are for reference only. All critical dimensions or criteria must be confirmed on the latest revision of controlled drawings. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 24: Data Interface Connection Ports

    USB ports – Used for transferring data to a USB memory device, or to connect a USB keyboard and mouse. • Modbus – Used for customer-configured analog gas concentration output data. Figure 15: Data Interface Connection Ports ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 25: Environmental Controls For Storage

    Environmental Controls for Storage The analyzer requires specific transportation to maintain tool integrity. The requirements for tool transportation from the ABB site to the customer’s location are as follows: • Humidity control range from 10% to 80% with no condensation.

  • Page 26: Installation

    Ethernet and Modbus cables, it is recommended to use double- shielded Category 6 S/FTP or SF/UTP type cable. Shielding of communication cable is required to suppress possible radiated and conductive interference affecting the electronics function. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 27: System Power Up & Communication Checks

    Pressure value recorded in the data package. Figure 17 shows an example of the Gas Pressure reading. Figure 17:Gas Pressure reading on the HMI Dashboard 11. Connect the facility exhaust gas line to the Internal Pump Exhaust port. The exhaust line should draw a minimum of 3.0 SLPM. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 28 Figure 18 shows the 4-20mA Passive Circuit Connection Diagram. Figure 18: 4-20mA Passive Circuit Connection Diagram 15. Reboot the analyzer to take gas measurements. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 29: User Interface Operation

    -- shows the operational status of the analyzer. (Figure 27) • Alarm Status • Setup Tools – access additional configuration and service menus. • Exit – exits the application and shuts down the analyzer. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 30: Main Display Screen

    Main Display After the program loads, the From this screen you can: • Measure data in several different formats • View system alarms • Configure the external communication interface Figure 19: Main Display Screen ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 31: Hmi Dashboard

    Laser B τ – Laser B ring-down time (micro-seconds - µs) • Figure 21: HMI Dashboard HMI Dashboard Tapping the Home icon on the left side of the will return the software application to the Main Display screen. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 32: Spectra Chart Display

    The measured HF and HCl concentrations are shown in parts per billion (ppb) and H O in parts per Spectrum Display million (ppm) on the bottom of the Figure 22: Spectra Chart Display for Laser 1 (GLA231-HFHC) ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 33: Gla231-Eaa Performance Rackmount Ammonia Analyzer

    Figure 24 shows the Spectra Display for the GLA231-EAA. The measured NH concentration is Spectrum shown in parts per billion (ppb) and H O in parts per million (ppm) on the bottom of the Display Figure 24: Spectra Chart Display for Laser 1 (GLA231-EAA) ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 34: Time Series Display

    Click on the drop-down box in the lower-right corner of either window to change displays of gas concentrations and to adjust the number of significant figures. Figure 25 shows and example of the Time Chart for the GLA231-HFHC with a flow of H Figure 25: Time Series Display ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 35: Numeric Display

    Sample gases are measured in parts per million (ppm) and parts per billion (ppb). Concentrations vary depending on the type of analyzer. Figure 26 shows an example of the Numeric Display measuring three gas samples. Figure 26: Numeric Display Screen ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 36: Alarm Status Display

    Red: The analyzer requires maintenance to correct an identified fault. A description of the cause of the alarm is displayed by selecting the relevant alarm button. Figure 27 shows the Alarm Status Display with all parameters functioning properly. Figure 27: Alarm Status Display ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 37 Acceptable Range No warning/alarm No warning/alarm Table 7 describes fault criteria for the Analyzer Alarms ‘A’ refers to Laser 1 and ‘B’ refers to Laser 2. Not all analyzers are equipped with 2 lasers. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 38 Occurs when linelock control voltage is Linelock (A/B) Peak is drifting approaching control range limit. Signal Power Signal power is Occurs when laser signal power has degraded by (A/B) degrading > 10% of the factory value. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 39: Setup Tools Display

    About -- Lists analyzer specific information. (Figure 37) Measure Rate -- Changes the rate at which data is written to the log file. (Figure 38) • File Transfer -- Transferring measurement data saved by the analyzer. (Figure 39) • ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 40 Figure 28: Setup Tools Screen ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 41: Time & Files

    Format mm/dd/yyyy, Absolute Local American hh:mm:ss.sss dd/mm/yyyy, Absolute Local European hh:mm:ss.sss mm/dd/yyyy, Absolute GMT American hh:mm:ss.sss dd/mm/yyyy, Absolute GMT European hh:mm:ss.sss Relative Seconds After Power On ssssss.sss Relative Seconds in Hours, Minutes, hh:mm:ss.sss Seconds ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 42: Laser Adjust

    To achieve this, the voltage driving the laser temperature is modified to move the laser to the operating wavelength. If the analyzer has two lasers, each laser can be fine-tuned to have the measured absorption in line with the theoretical target. Figure 30: Laser Adjust for Optimizing Measurement Calibration ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 43 Down Arrow: Peaks adjust to the left 4. Deselect the Disable Laser Frequency Lock check box. The software resumes automatic tracking and control of the laser wavelength. Figure 31: Laser Frequency Offset Adjust ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 44: Calibration

    Calibration ABB recommends periodic referencing rather than calibration to ensure measurement accuracy and consistency. When calibration is necessary, follow the procedure detailed below. Before performing calibration, the operator needs to have the following information available: • Traceable regulated gas type •...

  • Page 45: Serial Communication

    • Baud rate • Parity • Stop bits For proper serial communication, the analyzer settings must match the settings of the device that it is connected to. (Figure 33) Figure 33: Serial Screen ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 46: Analog Outputs

    Gas Concentration #2 +V Pin 7 Gas Concentration #2 RETURN Pin 3 Gas Concentration #3 +V Pin 8 Gas Concentration #3 RETURN Pin 4 Gas Concentration #4 +V Pin 9 Gas Concentration #4 RETURN ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 47: Service

    Service menu (Figure 35) is only to be modified by ABB-trained field service engineers for Service updating changes made to the analyzer. • These settings determine the level of change that could affect measurement performance. • The alarm threshold levels are set based upon the last fixed setting.

  • Page 48: Miu Application

    (depending on the ordered configuration). These ports are directed to the inlet port of the analyzer for sampling unknown gasses and reference gasses. menu can be configured to control the duration of each gas being sampled. (Figure 36) Figure 36: MIU Setup Screen ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 49: About

    (Figure 37) By selecting the About About section displays the: • Build Date of the current software • Serial Number of the analyzer • IP Address • Version of the code Figure 37: About Screen ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 50: Measure Rate

    Data is acquired at a rate of 1 Hz and averaged for a selected interval (1 to 100 seconds) before being written into the data file and plotted on the time chart. Longer averaging periods (or equivalently, slower data acquisition rates) yield better measurement precision than shorter averaging periods. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 51: File Transfer

    Data files are written in text (ASCII) format and contain labeled columns displaying: • The time stamp of each recorded measurement • Gas concentration • Cell pressure (Torr) • Cell temperature (Celsius) • Ambient Temperature (Celsius) • Ring-Down Time (microseconds) ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 52: Transferring Files

    When the hard drive is showing > 75% full, it is recommended to perform data clean up. To perform this clean up: Use the touchscreen to highlight the files to be deleted. Display Screen 2. Select Delete on the ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 53: Communications - Data And Alarms

    A crossover Ethernet cable will NOT allow an external computer to access the shared data directory, as the analyzer will not obtain a DHCP address on initialization and will shut down its Ethernet interface. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 54: Modbus

    Modbus, using the Ethernet port located at the rear panel. Moxa ioSearch 3. Execute the application file 4. Upon executing ioSearch, the Auto Search for I/O Servers menu will be displayed. (Figure 5. Select the Start Search tab to locate the Modbus. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 55 (Figure 41) Figure 41: Remote I/O Menu Screen 7. Select E1240 on the left side tree. The web console appears with the preset parameters currently loaded into the ioLogik Modbus device. (Figure 42) ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 56 Figure 42: Analog Input Configuration Screen ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 57 AI Channel Setting c. When making any changes on the menu screen, the user must select Submit at the bottom of the menu screen to lock the changes made when exiting. Figure 43: AI Channel Settings ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 58: Changing The Modbus Ip Address

    If a change is made to the IP address of the ioLogik Modbus, select the Submit tab to save changes before exiting the menu screen; otherwise, the new IP address will not be saved. ioLogik Quit the application. 2. Disconnect the Ethernet cable from the Modbus port at the rear panel. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 59: Modbus Tcp Information For Customize Configuration

    300009 Floating, LSBF Temperature Warning/Alarm 300011 Floating, LSBF Analyzer Warning/Alarm 300013 Floating, LSBF Gas 1 Concentration 300015 Floating, LSBF Gas 2 Concentration 300017 Floating, LSBF Gas 3 Concentration 300019 Floating, LSBF Gas 4 Concentration ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 60: Local Data Access

    CH3, and CH4 on the rear panel. Figure 45 displays the connection points used to sample gas concentrations. The information output is in real time. Figure 45 : Gas Concentration 5.08mm Terminal Block Connection Point ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 61: Alarms

    Mirror health is degrading, clean mirrors soon Warning (A)/(B) Warning Linelock (A)/(B) Laser A and/or B peak position is moving very fast Signal Power Laser A and/or B is degrading. Contact ABB Warning (A)/(B) support. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 62: Analyzer Shutdown

    Do NOT turn off the analyzer during this time. Figure 47: Archiving Spectra Files 4. Once the archiving process is complete, press the power switch to shut down the analyzer. Powering down without going through this process can corrupt the operating software. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 63: Maintenance

    Maintenance PC104 Stack The GLA231 series analyzer operates with a single board computer (PC104 Stack), equipped with an Intel Atom microprocessor. This single board computer is integrated with a digital signal processor (DSP) board along with a multiple I/O (MIO) board that collects signals from the ICOS detector for both processing the light signal and controlling the light source to maintain the level of sensitivity of the ICOS module.

  • Page 64: Self Correction

    Pin 7 (-) Gas Concentration #3 analog + Pin 3 (+) Gas Concentration #3 analog - Pin 8 (-) Gas Concentration #4 analog + Pin 4 (+) Gas Concentration #4 analog - Pin 9 (-) ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 65 Analog In 1- Gas Concentration #3 analog + Analog In 2+ Gas Concentration #3 analog - Analog In 2- Gas Concentration #4 analog + Analog In 3+ Gas Concentration #4 analog - Analog In 3- ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 66: Preventative Maintenance

    Preventative Maintenance The GLA231 series analyzer requires every six months to yearly preventative maintenance (PM) to maintain its measurement performance. Parts requiring maintenance every year are: a. Astigmatic mirrors 2. Parts to check and possibly replace every six months are: a.

  • Page 67: Appendix A: Features And Measurement Theory

    Integration of the measured spectra with the measured values of: • Gas temperature • Gas pressure • Path length • Line strength of the probed transition allows one to determine the mole fraction directly from the relation: ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 68: Lgr Off-Axis Icos

    The measured absorption spectra is recorded and used to determine a quantitative measurement of mixing ratio directly and without external calibration when combined with the recorded: Measured gas temperature and pressure in the cell Effective path length Known line strength ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 69: Appendix B: Material Safety Data Sheets

    Appendix B: Material Safety Data Sheets This chapter provides material safety data sheets for the chemicals typically used in GLA231 series analyzers. Each chemical has an MSDS, which lists the product name, supplier contacts (including emergency numbers), chemical and safety information, and other information as determined by the chemical manufacturer.
  • Page 70 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/ container to an approved waste disposal plant. 2.3 Hazards not otherwise classified (HNOC) or not covered by GHS – none ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 71: Composition/Information On Ingredients

    4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 72: Firefighting Measures

    Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 73: Exposure Controls/Personal Protection

    Biological occupational exposure limits Component CAS-No. Parameters Value Biological specimen Basis Methanol 67-56-1 Methanol 15.0000 mg/l Urine ACGIH – Biological Exposure Indices (BEI) Remarks End of shift (As soon as possible after exposure ceases) ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 74 Wash and dry hands. Full contact Material: butyl-rubber Minimum layer thickness: 0.3 mm Break through time: 480 min Material tested: Butoject® (KCL 897 / Aldrich Z677647, Size M) ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 75: Physical And Chemical Properties

    No data available e) Melting point/freezing point Melting point/range: -98°C (-144°F) - lit. f) Initial boiling point and boiling range 64.7°C (148.5°F) g) Flash point 9.7°C (49.5°F) - closed cup h) Evaporation rate No data available ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 76: Stability And Reactivity

    < 1 μS/cm Relative vapor density 1.11 10. STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions Vapors may form explosive mixture with air. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 77: Toxicological Information

    Germ cell mutagenicity Ames test S. typhimurium Result: negative in vitro assay fibroblast Result: negative Mutation in mammalian somatic cells. Mutagenicity (in vivo mammalian bone-marrow cytogenetic test, chromosomal analysis) Mouse - male and female Result: negative ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 78: Ecological Information

    EC50 - Daphnia magna (Water flea) - > 10,000.00 mg/l - 48 h Toxicity to algae Growth inhibition EC50 - Scenedesmus capricornutum (fresh water algae) - 22,000.0 mg/l - 96 h ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 79: Disposal Considerations

    Contact a licensed professional waste disposal service to dispose of this material. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION DOT (US) UN number: 1230 Class: 3 Packing group: II ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

  • Page 80: Regulatory Information

    State of California to cause birth defects or other reproductive harm. Methanol CAS-No. Revision Date 67-56-1 2012-03-16 16. OTHER INFORMATION Full text of H-Statements referred to under sections 2 and 3. Acute Tox. Acute toxicity Flam. Liq. Flammable liquids ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 81 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Company: Sigma-Aldrich 3050 Spruce Street ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 82 P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 83 In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 84 Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet- brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 85 Substances for which there is a Biological Exposure Index or Indices (see BEI® section) Not classifiable as a human carcinogen STEL 750.000000 USA. ACGIH Threshold Limit Values (TLV) Central Nervous System impairment Hematologic effects ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 86 Long-term systemic effects 186mg/kg BW/d Consumers Ingestion Long-term systemic effects 62mg/kg BW/d Consumers Skin contact Long-term systemic effects 62mg/kg BW/d Workers Inhalation Acute systemic effects 2420 mg/m3 Workers Inhalation Long-term systemic effects 1210 mg/m3 ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 87 Body Protection impervious clothing, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 88 No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Surface tension 23.2 mN/m at 20.0 °C (68.0 °F) ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 89 Result: Mild skin irritation - 24 h Serious eye damage/eye irritation Eyes - Rabbit Result: Eye irritation - 24 h Respiratory or skin sensitization - Guinea pig Result: Does not cause skin sensitization. Germ cell mutagenicity No data available ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 90 LC50 - Daphnia magna (Water flea) - 8,800 mg/l - 48 Toxicity to algae Remarks: No data available 12.2 Persistence and degradability Biodegradability Result: 91 % - Readily biodegradable (OECD Test Guideline 301B) 12.3 Bio-accumulative potential Does not bio-accumulate. ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 91 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De-Minimis) reporting levels established by SARA Title III, Section 313. Massachusetts Right To Know Components Acetone CAS-No. Revision Date 67-64-1 2007-03-01 ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...
  • Page 92 See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. Preparation Information Sigma-Aldrich Corporation Product Safety – Americas Region 1-800-521-8956 ABB GLA231 Series_Rackmount User Manual_ 3KXG162001R4601_09_2016...

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