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Free Chlorine
OPERATING INSTRUCTIONS

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  • Page 1 Free Chlorine OPERATING INSTRUCTIONS...
  • Page 3: Table Of Contents

    TABLE OF CONTENTS Table of Contents 1 General Information 6 Malfunction and Maintenance 1.1 Introduction 6.1 Cleaning and Upkeep 1.2 Health and safety information 6.2 Maintenance and inspection 1.3 Warnings 6.2.1 Electrolyte Replacement 1.4 Users and Operating Requirements 6.2.2 Membrane cap replacement 1.5 Intended use 6.2.3 Sensor Check 1.6 Disposal Information...
  • Page 4: General Information

    The chlorine sensor from the eCHEM sensors product range is an electrochemical sensor for measuring the chlorine concent- ration in water. This sensor detects free chlorine from inorganic chlorine products (chlorine gas, hypochlorite, etc.). The measu- ring method has a reduced pH dependency, so that pH fluctuations only have a limited impact on the measurement signal. pH value increases only lead to an approximately 10% reduction of the measuring signal per pH unit.
  • Page 5: Health And Safety Information

    Devices that radiate strong electromagnetic waves can influence the measurement data or result in a malfunction of the sen- sor. Avoid using the following devices in the same room as the TriOS sensor: mobile phones, cordless phones, transmitters/ receivers and other electrical devices that produce electromagnetic waves.
  • Page 6: Warnings

    Stop operation of the sensor in the event of excessive heat development (i.e. if it is hot to the touch). Switch off the sensor immediately and unplug the cable from the power supply. Please contact your dealer or the TriOS customer service.
  • Page 7: Intended Use

    Other uses do not comply with the intended use. This device has been developed for use in research and industry. It may only be used for the measurement of free chlorine in aqueous fluids such as drinking water, swimming pool water or sea water. The use of other media can damage the sensor. For the use of the chlorine sensor in other media than those specified in this manual, please contact the customer service of TriOS Mess- und Datentechnik GmbH (support@trios.
  • Page 8: Introduction

    Product type Power supply Interface In addition to the product bar code, the rating plate includes the TriOS Mess- und Datentechnik GmbH logo and the quality label. Please note that the specifications given here are for illustration purposes only and may be different depending on the version of the product.
  • Page 9: Scope Of Delivery

    This electrical signal is proportional to the chlorine concentration and is amplified by the sensor electronics. Due to an integrated temperature compensati- on, the measuring signal is independent of the temperature of the sample water. D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 10: Commissioning

    To do this, place the special sandpaper on a paper towel, hold it at one corner and run the electrode tip of the vertically held sensor two to three times over the sandpaper. Cleaning with special sandpaper D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 11 Important: When unscrewing the filled membrane cap, be sure to push the hose ring to the side at the NOTICE marked valve opening so that air can flow into the electrolyte chamber, otherwise the membrane will be destroyed! D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 12: Electrical Installation

    8. Power (9...30 VDC) Insert the connector into one of the supplied TriOS cables (2 m). Additional cable lengths of 0.3 m, 2 m, 5 m, 10 m, 25 m are offered. Connect the male end of the cable into the connector on the sensor by making the pins align with the slots of the cable.
  • Page 13: Interfaces

    The sensor must be used for measurements in the flow cell type FLC (see chapter 4). The use of the sensor in other flow cells must be approved by TriOS GmbH. Otherwise, no warranty will be given for the proper functioning of the sensor or for resulting damage to property or personal injury.
  • Page 14: Use

    Free Chlorine 4 Use The chlorine sensor can be operated with all TriOS controllers. Instructions for correct installation can be found in the relevant controller manual. A bypass installation of the sensor is essential for correct results. Therefore we strongly recommend to use the sensor in the flow cell type FLC for permanent use.
  • Page 15 Free Chlorine Approx. 122 80.00 18.00 44.00 Screw connection 1 1/4” 6/8 mm hose Sampling Flow control 6/8 mm hose Dimensions in mm D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 16: Installation With Retaining Ring

    FLC-3 8.0 bar (80 mH2O) 70 °C 45 (15) NOTICE The table shows the properties of the FlowCell. The sensor itself must not be operated at more than 3 bar. Higher pressure will damage the sensor. D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 17: Installation Without Retaining Ring

    Observe and adhere to the max. permitted operating pressure / operating temperature of the IMPORTANT sensor! FLC-1 45 °C 15 (45) Sensor operation wit- 0.5 bar (5 mH2O) hout retaining ring FLC-3 70 °C 45 (15) D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 18: Calibration

    (concentration, pH, inflow velocity etc.) in an endurance test. 5.2 Customer calibration A customer calibration using the DPD-1 method ("free chlorine") must be carried out in the application. The installation and other conditions must match the final application.
  • Page 19: Measurement Properties

    Gas bubbles in front of the membrane prevent the free chlorine from entering the electrolyte, which falsifies the measuring signal.
  • Page 20: Malfunction And Maintenance

    The use of warm water is recommended for rinsing off the gel electrolyte residues on the electrode finger and in the membrane cap. D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 21: Electrolyte Replacement

    (see figure right). Take a new membrane cap and fill it with electrolyte bubble-free (see section 3.1). If the sensor then still indicates too low or unstable values, it must be checked by the manufacturer. Shifted hose ring Cleaning with special sandpaper D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 22: Sensor Check

    Malfunction and Maintenance Free Chlorine 6.2.3 Sensor Check An adjustment or a check of the sensor according to the DPD-1 method ("free chlorine") should be carried out regularly at specific intervals, depending on the requirements. Recommendation: Weekly control, if necessary more frequently.
  • Page 23: General Troubleshooting

    Check installation type and change if medium necessary Reference electrode exhausted and/or Send in sensor to be overhauled contaminated Missing galvanic isolation Establish galvanic isolation. Send in sensor to the supplier to be checked / overhauled. D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 24 The measuring line is interrupted. Replace the measuring line. The sensor is not supplied with power. Establish correct power supply. The sensor is defective. Send in sensor to the supplier to be checked / overhauled. D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 25: Special Troubleshooting On The Sensor

    The formation of a small meniscus can be tolerated since the membrane is hydrophilic. -> Check whether the reference electrode has been damaged by the exchange between measuring medium and electrolyte. If it is no longer in perfect condition, send in the sensor for inspection. D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 26 For sensors with very small measuring ranges or high sensitivity, the zero NOTICE points are in principle somewhat higher than for sensors with large measu- ring ranges or low sensitivity. D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 27: Returns

    Please make sure that the sensor is cleaned and disinfected before shipping. In order to prevent damage to the goods during shipping, use the original packaging. If this is not available, make sure that safe transport is guaranteed and that the sensor is safely packed with enough packing material. D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 28: Technical Data

    7.1 Technical Specifications Measurement technology Membrane-covered, amperometric potentiostatic 3-electrode system Measurement principle Amperometry Parameters Free chlorine with reduced pH dependency Measurement range 0...2 mg/L, 0...20 mg/L Measuring range 2 mg/L: at 0.4 mg/L & 1.6 mg/L < 1% Accuracy Measuring range 20 mg/L: at 4 mg/L <...
  • Page 29: Accessories

    Free Chlorine 8 Accessories 8.1 Controller The sensor can be connected to all TriOS controllers. Below you will find an overview of the available TriOS devices: 8.1.1 TriBox3 Digital, 4-channel display and control unit with integrated solenoid valve for compressed-air control TriBox3 is a measurement and control system for all TriOS sensors.
  • Page 30: Warranty

    Damage resulting from modification or unprofessional attachment of accessories by the customer is not covered by the warranty. • If the serial number is not legible, the warranty expires. NOTICE Opening the electrode body voids the warranty! D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 31: Customer Service

    Free Chlorine 10 Customer service If you are having a problem with the sensor, please contact TriOS customer service. We recommend sending the sensor in for maintenance and calibration every 2 years. To do this, please request an RMA number from customer service.
  • Page 32: Contact

    If you have found an error or bug in one of the devices or programs, please let us know: Customer service: support@trios.de General questions / sales: sales@trios.de Website: www.trios.de TriOS Mess- und Datentechnik GmbH Bürgermeister-Brötje-Str. 25 D-26180 Rastede Germany Telephone +49 (0) 4402 69670 - 0 +49 (0) 4402 69670 - 20 D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 33 Contact Free Chlorine D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 34: Keyword Index

    Intended use Interfaces Care CE certification Cleaning Contact Copyright Label Customer calibration Customer service Manufacturer Calibration Measurement Declaration of conformity Measurement principle Disposal Measurement properties Membrane cap replacement Mounting Electrical installation Electrolyte Electromagnetic waves Operating requirements D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 35 Keyword Index Free Chlorine Product Identification Technical Specifications Troubleshooting User requirements Rating plate Reagents Retaining ring Returns Warnings RMA number Warranty Waste Safety instructions Scope of Delivery Specifications Storage Structure of the sensor D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 36: Annex

    Bürgermeister-Brötje-Str. 25 D- 26180 Rastede Konformitätserklärung Declaration of Conformity Déclaration de Conformité Die TriOS GmbH bescheinigt die Konformität für das Produkt The TriOS GmbH herewith declares conformity of the product TriOS GmbH déclare la conformité du produit Bezeichnung eCHEM Freies Chlor...
  • Page 37 Write Multiple Registers Device data Address Access Data type Parameters Example 0x03 R / O char [16] Sensor type CL4. 1-M1 0x04 R / O Hardware 1120 (1.120) 0x06 R / O Firmware 1202 (1.202) D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 38 X_Span [2] 0x0220 R / O unsigned longint DateTime [2] yymmddhhmm 0x0222 R / O float X_Null [3] 0x0224 R / O float X_Span [3] 0x0226 R / O unsigned longint DateTime [3] yymmddhhmm D01-905en201912 Manual eCHEM Free Chlorine...
  • Page 39 • Data type: unsigned long • = 4294967296 Date / Time stamp • Year: (20)42, Month: [94], Day: [96], Hour: [72], Min: [96] • Last possible date: 31.12.2042, 23:59 (Subject to technical changes!) D01-905en201912 Manual eCHEM Free Chlorine...

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