Samsung SSG-5100GB User Manual page 204

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You need to change the wireless router's security settings to AES. WEP
security settings don't support WPS Connection.
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If HIGH PURE THROUGHPUT (Greenfield) 802.11n mode is selected and
the Encryption type is set to WEP for your wireless router, Samsung TVs
will not support a connection in compliance with new Wi-Fi certification
specifications.
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If your wireless router supports WPS (Wi-Fi Protected Setup), you can
connect to the network via PBC (Push Button Configuration) or PIN
(Personal Identification Number). WPS will automatically configure the
SSID and WPA key in either mode.
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