Material Safety Data Sheet - Sharp AR-156 Operation Manual

MATERIAL SAFETY DATA SHEET

Section 1. Product Identification
Product:
AR-152NT/T/FT/ST (Black Toner)
Section 2. Supplier's Name and Address
Sharp Corporation
22-22 Nagaike-cho, Abeno-ku, Osaka, Japan
Local suppliers are listed below. Please contact the nearest supplier for additional information.
(Country)
U.S.A.
Canada
United Kingdom
Section 3. Ingredients
Ingredients
Styrene-Acrylate copolymer
Carbon black
Iron oxide
Metal Complex dye
Section 4. Hazardous Identification (Emergency Overview)
Toner is a fine, black powder possessing no immediate hazard. There are no anticipated carcinogenic
effects from exposure based on animal tests performed using toner. When used as intended according
to instructions, studies do not indicate any symptoms of fibrosis will occur.
Section 5. Health Hazard Data
Route(s) of Entry:
Health Hazards: Acute oral toxicity ------------- LDL
Mutagenicity -------------------- The result of Ames test is negative.
Carcinogenicity: In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible
human carcinogen). This classification is given to chemicals for which there is
inadequate human evidence, but sufficient animal evidence on which to base an
opinion of carcinogenicity. The classification is based upon the development of lung
tumors in rats receiving chronic inhalation exposures to free carbon black at levels
that induce particle overload of the lung. Studies performed in animal models other
than rats did not show any association between carbon black and lung tumors.
Moreover, a two-year cancer bioassay using a typical toner preparation containing
carbon black demonstrated no association between toner exposure and tumor
development in rats.
Chronic Effect: In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate
degree of lung fibrosis was observed in 92% of the rats in the high concentration
(16mg/m
22% of the animals in the middle (4mg/m
was reported in the lowest (1mg/m
potential human exposures.
Signs and Symptoms of Exposure: Minimal irritation to respiratory tract may occur as with exposure
Medical Conditions Generally Aggravated by Exposure: None
Emergency and First Aid Procedures:
Inhalation; Remove to fresh air. If effects occur, consult medical personnel.
Eye;
(Name and Telephone Number)
Sharp Electronics Corporation
Telephone number for information: 1-800-237-4277
Emergency telephone number:
Sharp Electronics of Canada Ltd.
Telephone number for information: 905-890-2100
Emergency telephone number:
Sharp Electronics (U.K.) Ltd.
Telephone number for information: 01923-474013
CAS No. Proportion OSHA PEL ACGIH TLV Other Limits
29497-14-1 > 88 %
1333-86-4 < 6.0%
1309-38-2 < 4.5%
{
109125-51-1 < 1.5%
109125-50-0
84179-66-8
Inhalation? Skin?
Yes No
of this toner is over 2,000mg/kg.
0
3
) exposure group, and a minimal to mild degree of fibrosis was noted in
3
to any non-toxic dust.
In case of contact, immediately flush eyes with water for 15 minutes.
Date Issued:Nov. 1, 2000
MSDS No. F-01001
1-800-255-3924
1-800-255-3924
Not listed Not listed
3
3.5mg/m 3.5mg/m
Not listed Not listed
0.5mg/m 3 0.5mg/m
Ingestion?
Possible but very unusual.
3
) exposure group, but no pulmonary change
) exposure group, the most relevant level to
None
3
None
None
3 None