Chevrolet 2000 Tahoe Owner's Manual page 282

1. You can remove the coolant surge tank pressure
cap when the cooling system, including the coolant
surge tank pressure cap and upper radiator hose,
is no longer hot. Turn the pressure cap slowly
counterclockwise (left) about one full turn. If you
hear a hiss, wait for that to stop. A hiss means there
is still some pressure left.
2. Then keep turning the pressure cap slowly, and
remove it.
5-16
3. Then fill the coolant surge tank with the proper
mixture, to the FILL COLD mark.