Agilent Technologies 5975C TAD VL MSD Troubleshooting And Maintenance Manual page 78

3
CI Troubleshooting
Reagent gas ion ratio is difficult to adjust or unstable
The interface tip seal is incorrectly placed, damaged, or missing.
Inspect the interface tip seal. If necessary, remove and reinstall it to ensure a
good seal with the CI ion source. Replace it if it is damaged. Install it if it is
missing.
Residual air and water in the MSD or in the reagent gas supply lines
Run the methane pretune. Air will appear as a peak at m/z 32 and excessive
water as a peak at m/z 19 > m/z 17. If either of these conditions is present,
purge the reagent gas supply lines and bake out the MSD. See
Continued presence of a large peak at m/z 32 may indicate an air leak. After
correcting the problems, you may need to clean the ion source.
Air leak
Run Methane Pretune (in PCI). Large peak at m/z 32 indicates air in the
system. Check for and correct any leaks. See
The reagent gas supply is at the wrong pressure.
Check the regulator on the reagent gas supply. It should be adjusted to 20 psi
(140 kPa).
A leak in the reagent gas delivery path. This is especially likely if you have set
the methane flow much higher than normal and the ratio is still too low.
Check the reagent gas path. Tighten fittings.
The CI ion source is dirty.
Clean the ion source. See
information.
78
"To Clean the CI Ion Source"
5975 Series MSD Troubleshooting and Maintenance Manual
page
"Air Leaks" on page 60.
on page 164 for more
168.